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<!-- To obtain a blank version of this page, type subst:chembox supplement inside of double curly braces, {{}}, and save the page -->
The name of the author is Garland. Years in the past we moved to Kansas. Interviewing is what she does in her day job but soon her husband and her will begin their personal business. Playing croquet is something I will never give up.<br><br>Feel free to surf to my site [http://www.Saintpeteryouthbasketball.org/ActivityFeed/MyProfile/tabid/60/userId/95760/Default.aspx www.Saintpeteryouthbasketball.org]
This page provides supplementary chemical data on [[tetrachloroethylene]]. <!-- replace with proper wikilink -->
 
== Material Safety Data Sheet == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
The handling of this chemical may incur notable safety precautions. It is highly recommended that you seek the Material Safety Datasheet ([[Material safety data sheet|MSDS]]) for this chemical from a reliable source  such as [http://www2.siri.org/msds/index.php SIRI], and follow its directions. MSDS is available from [https://fscimage.fishersci.com/msds/22900.htm Fisher Scientific].
 
== Structure and properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Structure and properties
|-
| [[Index of refraction]],<ref>''Lange's Handbook of Chemistry'', 10th ed. pp 1289-1376</ref> ''n''<sub>D</sub>
| 1.5055 at 20°C <!-- Please omit if not applicable -->
|-
| [[Abbe number]]
|? <!-- Please omit if not applicable -->
|-
| [[Dielectric constant]],<ref>{{Cite web|url=http://www.asiinstr.com/technical/Dielectric%20Constants.htm|title=Dielectric Constants Chart|publisher=ChemicalLand21|accessdate=9 June 2007}}</ref> ε<sub>r</sub>
| 2.5 ε<sub>0</sub> at 21 °C <!-- Please omit if not applicable -->
|-
| [[Bond strength]]
| ? <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond length]]
| ? <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond angle]]
| ? <!-- Specify which angle, e.g. Cl-P-O. Please omit if not applicable -->
|-
| [[Magnetic susceptibility]]
| ? <!-- Please omit if not applicable -->
|-
| [[Surface tension]]<ref name="ntp">{{Cite web|url=http://ntp.niehs.nih.gov/index.cfm?objectid=E87D1CE3-BDB5-82F8-FF89E156508651F8|title=Tetrachloroethylene|publisher=National Toxicology Program|accessdate=9 June 2007}}</ref>
| 31.74 dyn/cm at 20°C(C<sub>2</sub>Cl<sub>4</sub> against air)<br>44.4 dyn/cm at 25°C (C<sub>2</sub>Cl<sub>4</sub> against water)<br>
|-
| [[Viscosity]]<ref>''Lange's Handbook of Chemistry'', 10th ed. pp 1669-1674</ref>
| 1.1384 mPa·sec at 0.43°C<br>0.8759 mPa·sec at 22.3°C<br>0.6539 mPa·sec at 52.68°C<br>0.4043 mPa·sec at 117.09°C
|-
|}
 
== Thermodynamic properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Phase behavior
|-
| [[Triple point]]
| 250.81 K (–22.34 °C), ? Pa
|-
| [[Critical point (chemistry)|Critical point]]
| 620 K (347 °C), 4760 kPa
|-
| [[Standard enthalpy change of fusion|Std enthalpy change<br/>of fusion]], Δ<sub>fus</sub>''H''<sup><s>o</s></sup>
| 10.88 kJ/mol
|-
| [[Standard entropy change of fusion|Std entropy change<br/>of fusion]], Δ<sub>fus</sub>''S''<sup><s>o</s></sup>
| 43.38 J/(mol·K)
|-
| [[Standard enthalpy change of vaporization|Std enthalpy change<br/>of vaporization]], Δ<sub>vap</sub>''H''<sup><s>o</s></sup>
| 34.68 kJ/mol at 121°C
|-
| [[Standard entropy change of vaporization|Std entropy change<br/>of vaporization]], Δ<sub>vap</sub>''S''<sup><s>o</s></sup>
| 102.8 J/(mol·K) at 25°C
|-
! {{chembox header}} | Solid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>solid</sub>
| ? kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>solid</sub>
| ? J/(mol K)
|-
| [[Enthalpy of state transition]], Δ<sub>trs</sub>''H''<sup><s>o</s></sup>
| 0.820 kJ/mol (crystal II → crystal I)<br>–148°C to –63°C
|-
| [[Entropy of state transition]], Δ<sub>trs</sub>''S''<sup><s>o</s></sup>
| 5.26 J/(mol K) (crystal II → crystal I)<br>–148°C to –63°C
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| ? J/(mol K)
|-
! {{chembox header}} | Liquid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>liquid</sub>
| –54.4 kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>liquid</sub>
| 240.6 J/(mol K)
|-
| [[Enthalpy of combustion]], Δ<sub>c</sub>''H''<sup><s>o</s></sup>
| –830 kJ/mol
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 146 J/(mol K) at 25°C
|-
! {{chembox header}} | Gas properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>gas</sub>
| –12.43 kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>gas</sub>
| 343.4 J/(mol K) at 25°C
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 95.51 J/(mol K) at 25°C
|-
|}
 
==Vapor pressure of liquid==
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| {{chembox header}} | '''P in mm Hg''' || 1 || 10 || 40 || 100 || 400 || 760
|-
| {{chembox header}} | '''T in °C''' || –20.6<sub>(s)</sub> || 13.8 || 40.1 || 61.3 || 100.0 || 120.8
|}
Table data obtained from ''CRC Handbook of Chemistry and Physics'' 47th ed. Note that "(s)" annotation indicates equilibrium temperature of vapor pressure of solid. Otherwise indication is equilibrium temperature of vapor of liquid.{{Clear}}
 
[[Image:LogTetrachloroethyleneVaporPressure.png|thumb|868px|left|'''log<sub>10</sub> of Tetrachloroethylene vapor pressure.''' Uses formula: <math>\scriptstyle \log_e P_{mmHg} =</math><math>\scriptstyle \log_e (\frac {760} {101.325}) - 6.665868\log_e(T+273.15) - \frac {6530.97} {T+273.15} + 60.47398 + 3.522382 \times 10^{-6} (T+273.15)^2</math> obtained from CHERIC<ref name="cheric_p">{{Cite web|url=http://www.cheric.org/research/kdb/hcprop/cmpsrch.php|title=Pure Component Properties|format=Queriable database|publisher=Chemical Engineering Research Information Center|accessdate=9 June 2007}}</ref>]]{{Clear}}
 
==Distillation data==
See also
* [[trichloroethylene (data page)#Distillation data|Trichloroethylene (data page)]]
 
{|
|- valign="top"
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align=center colspan="3" | '''Vapor-Liquid Equilibrium<br>of Tetrachloroethylene/[[Methanol]]'''<ref name="cheric_b">{{Cite web|url=http://www.cheric.org/research/kdb/hcvle/hcvle.php|title=Binary Vapor-Liquid Equilibrium Data|publisher=Chemical Engineering Research Information Center|format=Queriable database|accessdate=9 June 2007}}</ref><br>''P'' = 760&nbsp;mm Hg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole methanol
|- {{chembox header}}
! liquid !! vapor
|-
| 117.2 || 0.1 || 7.4
|-
| 113.2 || 0.3 || 21.0
|-
| 107.7 || 0.3 || 33.5
|-
| 102.7 || 0.3 || 44.5
|-
| 97.6 || 0.8 || 53.0
|-
| 93.0 || 1.1 || 58.8
|-
| 87.0 || 1.7 || 66.0
|-
| 80.5 || 2.4 || 72.4
|-
| 70.2 || 6.6 || 80.0
|-
| 65.3 || 21.5 || 83.7
|-
| 64.4 || 53.3 || 84.8
|-
| 63.9 || 77.6 || 85.9
|-
| 63.5 || 88.3 || 88.3
|-
| 63.6 || 93.7 || 91.3
|-
| 63.8 || 95.0 || 92.7
|-
| 64.2 || 97.9 || 95.8
|-
|}
|&nbsp; &nbsp;
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align=center colspan="3" | '''Vapor-Liquid Equilibrium<br>of Tetrachloroethylene/[[1,2-Dichloroethane]]'''<ref name="cheric_b"/><br>''P'' = 760&nbsp;mm Hg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole dichloroethane
|- {{chembox header}}
! liquid !! vapor
|-
| 117.8 || 2.0 || 11.5
|-
| 114.0 || 5.0 || 21.7
|-
| 110.9 || 9.2 || 31.5
|-
| 108.0 || 12.0 || 38.8
|-
| 106.0 || 15.0 || 43.7
|-
| 103.3 || 20.0 || 51.2
|-
| 100.5 || 26.4 || 59.2
|-
| 98.5 || 31.1 || 62.9
|-
| 95.2 || 40.0 || 69.6
|-
| 93.7 || 45.0 || 72.5
|-
| 92.2 || 50.0 || 75.5
|-
| 89.9 || 59.4 || 80.4
|-
| 88.2 || 67.9 || 84.2
|-
| 86.8 || 75.0 || 87.5
|-
| 85.5 || 83.8 || 91.6
|-
| 84.2 || 93.8 || 97.0
|-
|}
|&nbsp; &nbsp;
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align=center colspan="3" | '''Vapor-Liquid Equilibrium<br>of Tetrachloroethylene/[[Isopropanol]]'''<ref name="cheric_b"/><br>''P'' = 100 kPa
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole C<sub>2</sub>Cl<sub>4</sub>
|- {{chembox header}}
! liquid !! vapor
|-
| 81.7 || 0.0 || 0.0
|-
| 81.6 || 0.8 || 1.2
|-
| 81.5 || 1.6 || 2.3
|-
| 81.4 || 3.0 || 4.1
|-
| 81.3 || 5.4 || 6.7
|-
| 81.2 || 8.4 || 9.4
|-
| 81.1 || 12.0 || 12.1
|-
| 81.1 || 16.4 || 14.5
|-
| 81.3 || 21.9 || 17.1
|-
| 81.5 || 27.8 || 19.0
|-
| 81.8 || 33.9 || 20.3
|-
| 82.2 || 39.4 || 21.5
|-
| 82.6 || 44.0 || 22.6
|-
| 83.0 || 50.6 || 23.1
|-
| 83.4 || 55.2 || 24.2
|-
| 83.8 || 60.0 || 24.7
|-
| 84.4 || 65.0 || 25.3
|-
| 85.0 || 69.1 || 26.2
|-
| 85.6 || 75.5 || 27.7
|-
| 86.8 || 79.8 || 29.6
|-
| 90.1 || 87.9 || 35.3
|-
| 95.1 || 92.3 || 42.7
|-
| 98.0 || 94.1 || 48.2
|-
| 101.6 || 95.5 || 54.0
|-
| 105.9 || 97.0 || 62.6
|-
| 110.2 || 98.1 || 72.1
|-
| 114.7 || 99.2 || 85.0
|-
| 117.6 || 99.6 || 92.1
|-
| 121.0 || 100.0 || 100.0
|-
|}
|}
 
== Spectral data == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | [[UV/VIS spectroscopy|UV-Vis]]
|-
| [[Lambda-max|λ<sub>max</sub>]]
| ? [[Nanometre|nm]]
|-
| [[molar absorptivity|Extinction coefficient]], ε
| ?
|-
! {{chembox header}} | [[Infrared|IR]]
|-
| Major absorption bands
| ? cm<sup>&minus;1</sup>
|-
! {{chembox header}} | [[NMR Spectroscopy|NMR]]
|-
| [[Proton NMR]] <!-- Link to image of spectrum -->
| &nbsp;
|-
| [[Carbon-13 NMR]] <!-- Link to image of spectrum -->
| &nbsp;
|-
| Other NMR data <!-- Insert special data e.g. <sup>19</sup>F chem. shifts, omit if not used -->
| &nbsp;
|-
! {{chembox header}} | [[Mass Spectrometry|MS]]
|-
| Masses of <br>main fragments
| &nbsp; <!-- Give list of major fragments -->
|-
|}
 
==References==
{{Reflist}}
* {{Cite web|url=http://webbook.nist.gov/chemistry/|title=NIST Standard Reference Database}}
 
Except where noted otherwise, data relate to [[standard ambient temperature and pressure]].
 
[[wikipedia:Chemical infobox|Disclaimer]] applies.
{{Use dmy dates|date=September 2010}}
 
{{DEFAULTSORT:Tetrachloroethylene (Data Page)}}
[[Category:Chemical data pages]]

Latest revision as of 11:06, 4 June 2014

The name of the author is Garland. Years in the past we moved to Kansas. Interviewing is what she does in her day job but soon her husband and her will begin their personal business. Playing croquet is something I will never give up.

Feel free to surf to my site www.Saintpeteryouthbasketball.org

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