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{{merge|Pyruvate formate lyase|date=February 2013}}
{{enzyme
| Name = formate C-acetyltransferase
| EC_number = 2.3.1.54
| CAS_number = 9068-08-0
| IUBMB_EC_number = 2/3/1/54
| GO_code = 0008861
| image =  
| width =  
| caption =  
}}
In [[enzymology]], a '''formate C-acetyltransferase''' ({{EC number|2.3.1.54}}) is an [[enzyme]] that [[catalysis|catalyzes]] the [[chemical reaction]]
 
:acetyl-CoA + formate <math>\rightleftharpoons</math> CoA + pyruvate
 
Thus, the two [[substrate (biochemistry)|substrates]] of this enzyme are [[acetyl-CoA]] and [[formate]], whereas its two [[product (chemistry)|products]] are [[coenzyme A|CoA]] and [[pyruvate]].
 
This enzyme belongs to the family of [[transferase]]s, specifically those [[acyltransferase]]s transferring groups other than aminoacyl groups. The systematic name of this enzyme class is '''acetyl-CoA:formate C-acetyltransferase'''. Other names in common use include '''pyruvate formate-lyase''', '''pyruvic formate-lyase''', and '''formate acetyltransferase'''. This enzyme participates in 3 [[metabolism|metabolic pathways]]: [[pyruvate metabolism]], [[propanoate metabolism]], and [[butanoate metabolism]].
 
==Structural studies==
 
As of late 2007, 8 [[tertiary structure|structures]] have been solved for this class of enzymes, with [[Protein Data Bank|PDB]] accession codes {{PDB link|1CM5}}, {{PDB link|1H16}}, {{PDB link|1H17}}, {{PDB link|1H18}}, {{PDB link|1MZO}}, {{PDB link|1QHM}}, {{PDB link|2PFL}}, and {{PDB link|3PFL}}.
 
==References==
{{reflist|1}}
* {{cite journal | author = Knappe J, Blaschkowski HP, Grobner P, Schmitt T | date = 1974 | title = Pyruvate formate-lyase of Escherichia coli: the acetyl-enzyme intermediate | journal = Eur. J. Biochem. | volume = 50 | pages = 253&ndash;63  | pmid = 4615902 | doi = 10.1111/j.1432-1033.1974.tb03894.x | issue = 1 }}
 
{{transferase-stub}}
 
[[Category:EC 2.3.1]]
[[Category:Enzymes of known structure]]

Latest revision as of 21:39, 17 March 2013



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acetyl-CoA + formate CoA + pyruvate

Thus, the two substrates of this enzyme are acetyl-CoA and formate, whereas its two products are CoA and pyruvate.

This enzyme belongs to the family of transferases, specifically those acyltransferases transferring groups other than aminoacyl groups. The systematic name of this enzyme class is acetyl-CoA:formate C-acetyltransferase. Other names in common use include pyruvate formate-lyase, pyruvic formate-lyase, and formate acetyltransferase. This enzyme participates in 3 metabolic pathways: pyruvate metabolism, propanoate metabolism, and butanoate metabolism.

Structural studies

As of late 2007, 8 structures have been solved for this class of enzymes, with PDB accession codes Template:PDB link, Template:PDB link, Template:PDB link, Template:PDB link, Template:PDB link, Template:PDB link, Template:PDB link, and Template:PDB link.

References

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