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| The '''Dobson unit''' (DU) is a unit of measurement of the [[area density|columnar density]] of a trace gas in the [[Earth's atmosphere]]. It originated, and continues to be widely used, as a measure of total-column [[ozone]], which is dominated by ozone in the [[stratosphere|stratospheric]] [[ozone layer]]. One Dobson unit refers to a layer of gas that would be 10 µm thick under [[standard temperature and pressure]],<ref>{{GoldBookRef|title=Dobson unit ''in atmospheric chemistry''|url=http://goldbook.iupac.org/D01827.html}}</ref> sometimes referred to as a 'milli-atmo-centimeter.' For example, 300 DU of ozone brought down to the surface of the Earth at 0 [[Degree Celsius|°C]] would occupy a layer only 3 mm thick. One DU is 2.69×10<sup>16</sup> ozone [[molecule]]s per [[square centimetre]], or 2.69×10<sup>20</sup> per [[square metre]].
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| This is 0.4462 [[millimole]]s of ozone per square metre.<ref>{{cite journal |author=S. E. Schwartz | author2=P. Warneck |year= 1995| title=Units for use in atmospheric chemistry|journal= Pure Appl. Chem.|volume= 67|issue= 8-9|pages= 1377–1406|url= http://www.iupac.org/publications/pac/67/8/1377/|doi=10.1351/pac199567081377}}</ref>
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| A baseline value of 220 DU is chosen as the starting point for an [[ozone hole]] since total ozone values of less than 220 Dobson units were not found in the historic observations over [[Antarctica]] prior to 1979. Also, from direct measurements over Antarctica, a column ozone level of less than 220 Dobson units is a result of the ozone loss from [[chlorine]] and [[bromine]] compounds.<ref>{{cite web|title=Ozone Hole Watch|url=http://ozonewatch.gsfc.nasa.gov/ |publisher=NASA|accessdate=2007-10-21}}</ref>
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| In addition, Dobson units are often used to describe total column densities of [[Sulfur dioxide|Sulfur Dioxide]], which occurs in the atmosphere in small amounts due to the combustion of fossil fuels, from biological processes releasing [[dimethyl sulfide]], or by natural combustion such as forest fires. Large amounts of sulfur dioxide may be released into the atmosphere as well by volcanic eruptions. The Dobson unit is used to describe total column amounts of sulfur dioxide due to the fact that it appeared in the early days of ozone remote sensing on ultraviolet satellite instruments (such as [[Total Ozone Mapping Spectrometer|TOMS]]).
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| The Dobson unit is named after [[Gordon Dobson]], who was a researcher at the [[University of Oxford]]. In the 1920s, he built the first instrument to measure total ozone from the ground, now called the [[Dobson ozone spectrophotometer]].
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| ==Derivation==
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| The Dobson Unit arises from the ideal gas law. Recall the real gas law:
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| <math>PV=nRT</math>
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| where P and V are pressure and volume, respectively, and n, R and T are the number of moles of gas, the gas constant (8.314 J/ mol K), and T is temperature in Kelvin (K).
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| Also recall that the number density of air is the number of molecules or atoms per unit volume:
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| <math>n_{air} = \frac{A_{av} N}{V}</math>
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| and when plugged into the real gas law, we find that we may calculate the number density of air by using pressure, temperature and the real gas constant.
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| <math>n_{air} = \frac{A_{av} P}{RT}</math>
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| If we want, we may calculate the number density (molecules/volume) of air at standard temperature and pressure (T= 273K and P = 101325 Pa), by using this equation:
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| <math>n_{air} = \frac{A_{av} P}{RT} = \frac{(6.02\ast 10^{23} \frac {molecules}{mol}) \cdot (101325 Pa)}{8.314 \frac{J}{mol \cdot K}\cdot 273 K}</math>
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| With some unit conversions of Joules to Pascals, we can solve the equation for molecules / volume:
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| <math>\frac{(6.02\ast 10^{23} \frac {molecules}{mol}) \cdot (101325 Pa)}{8.314 \frac{Pa \cdot m^{3}}{mol \cdot K}\cdot 273 K} = 2.69 \ast 10^{25} molecules \cdot m^{-3}</math>
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| A Dobson Unit is the total amount of a trace gas per unit area. In atmospheric sciences, this is referred to as a column density. How, though, do we go from units of molecules per '''cubic''' meter, a volume, to molecules per '''square centimeter''', an area? This must be done by integration. To get a column density, we must integrate the total column over a height. Per the definition of Dobson Units, we see that 1 DU = 0.01 mm of trace gas when compressed down to sea level at standard temperature and pressure. So if we integrate our number density of air from 0 to 0.01 mm, we find the number density which is equal to 1 DU:
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| <math>\int_{0 mm}^{0.01 mm} (2.69 \ast 10^{25} molecules \cdot m^{-3}) dx = 2.69 \ast 10^{25} molecules \cdot m^{-3} \cdot 0.01 mm - 2.69 \ast 10^{25} molecules \cdot m^{-3} \cdot 0 mm </math>
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| ::<math>= 2.69 \ast 10^{25} molecules \cdot m^{-3} \cdot 10^{-5}m = 2.69 \ast 10^{20} molecules \cdot m^{-2}</math>
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| And thus we come up with the value of 1 DU, which is 2.69×10<sup>20</sup> molecules per meter squared.
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| ==References==
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| {{reflist}}
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| {{DEFAULTSORT:Dobson Unit}}
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| <!--Categories-->
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| [[Category:Ozone]]
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| [[Category:Atmospheric chemistry]]
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| [[Category:Units of measurement]]
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