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:''Not to be confused with s-p mixing in Molecular Orbital theory. See [[Molecular orbital diagram]].


In [[chemistry]], '''hybridisation''' (or '''[[American and British English spelling differences#-ise, -ize (-isation, -ization)|hybridization]]''') is the concept of mixing [[atomic orbital]]s into new ''hybrid orbitals'' (with different energies, shapes, etc., than the component atomic orbitals) suitable for the pairing of electrons to form [[chemical bond]]s in [[valence bond theory]]. Hybrid orbitals are very useful in the explanation of [[molecular geometry]] and atomic bonding properties. Although sometimes taught together with the [[VSEPR|valence shell electron-pair repulsion (VSEPR) theory]], valence bond and hybridisation are in fact not related to the VSEPR model.<ref>{{citation | last= Gillespie | first=R.J. | year=2004 | title=Teaching molecular geometry with the VSEPR model | journal=Journal of Chemical Education | volume=81 | issue=3 | pages=298–304 | doi=10.1021/ed081p298 |bibcode = 2004JChEd..81..298G }}</ref>
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== Historical development ==
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[[Chemist]] [[Linus Pauling]] first developed the hybridisation theory in order to explain the structure of [[molecule]]s such as [[methane]] (CH<sub>4</sub>).<ref>{{citation | last=Pauling | first=L. | year=1931 | title=The nature of the chemical bond. Application of results obtained from the quantum mechanics and from a theory of paramagnetic susceptibility to the structure of molecules | journal=[[Journal of the American Chemical Society]] | volume=53 |issue=4 | pages=1367–1400 | doi=10.1021/ja01355a027 }}</ref> This concept was developed for such simple chemical systems, but the approach was later applied more widely, and today it is considered an effective [[heuristic]] for rationalising the structures of [[organic compounds]].
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Orbitals are a model representation of the behaviour of electrons within molecules. In the case of simple hybridisation, this approximation is based on atomic orbitals, similar to those obtained for the hydrogen atom, the only neutral atom for which the [[Schrödinger equation]] can be solved exactly. In heavier atoms, such as carbon, nitrogen, and oxygen, the atomic orbitals used are the 2s and 2p orbitals, similar to excited state orbitals for hydrogen. Hybrid orbitals are assumed to be mixtures of these atomic orbitals, superimposed on each other in various proportions. It provides a [[quantum mechanics|quantum mechanical]] insight to [[Lewis structure]]s. Hybridisation theory finds its use mainly in organic chemistry.
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== sp<sup>x</sup> and sd<sup>x</sup> terminology ==
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This terminology describes the weight of the respective components of a hybrid orbital. For example, in methane, the C hybrid orbital which forms each [[carbon]]–[[hydrogen]] bond consists of 25% s character and 75% p character and is thus described as sp<sup>3</sup> (read as ''s-p-three'') hybridised. [[Quantum mechanics]] describes this hybrid as an sp<sup>3</sup> [[wavefunction]] of the form N(s + {{sqrt|3}}pσ), where N is a [[normalization constant]] (here 1/2) and pσ is a p orbital directed along the C-H axis to form a [[sigma bond]]. The ratio of coefficients (denoted λ in general) is [[square root of 3|{{sqrt|3}}]] in this example. Since the [[electron density]] associated with an orbital is proportional to the square of the wavefunction, the ratio of p-character to s-character is λ<sup>2</sup> = 3. The p character or the weight of the p component is N<sup>2</sup>λ<sup>2</sup> = 3/4.
 
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For atoms forming equivalent hybrids with no lone pairs, there is a correspondence to the number and type of orbitals used. For example, sp<sup>3</sup> hybrids are formed from one s and three p orbitals. However, in all other cases, there is no such correspondence. The two bond-forming hybrid orbitals of oxygen in water can be described as sp<sup>4</sup>, which means that they have 20% s character and 80% p character, but does ''not'' imply that they are formed from one s and four p orbitals. As a result, the amount of ''p''-character is not restricted to integer values; i.e., hybridisations like ''sp''<sup>2.5</sup> are also readily described. For more information see [[variable hybridization]].
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An analogous notation is used to describe sd<sup>x</sup> hybrids. For example, the [[permanganate ion]] (MnO<sub>4</sub><sup></sup>) has sd<sup>3</sup> hybridisation with orbitals that are 25% s and 75% d.
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== Types of hybridisation ==
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=== sp<sup>3</sup> hybrids ===
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[[Image:AE4h.svg|thumb|150px|Four sp<sup>3</sup> orbitals.]]
 
Hybridisation describes the bonding atoms from an atom's point of view. That is, for a tetrahedrally coordinated carbon (e.g., [[methane]] CH<sub>4</sub>), the carbon should have 4 orbitals with the correct symmetry to bond to the 4 hydrogen atoms.
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Carbon's [[ground state]] configuration is 1s<sup>2</sup> 2s<sup>2</sup> 2p<sub>''x''</sub><sup>1</sup> 2p<sub>''y''</sub><sup>1</sup> or more easily read:
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<!-- Never use <math> here, otherwise you'll be cursed -->
{| cellpadding=4px align=center
| rowspan=2 |C||↑↓||↑↓||↑||↑||&nbsp;
|-
|{{overline|1s}}
|{{overline|2s}}
|{{overline|2p<sub>''x''</sub>}}
|{{overline|2p<sub>''y''</sub>}}
|{{overline|2p<sub>''z''</sub>}}
|}


The carbon atom can utilize its two singly occupied p-type orbitals (the designations p<sub>''x''</sub> p<sub>''y''</sub> or p<sub>''z''</sub> are meaningless at this point, as they do not fill in any particular order), to form two [[covalent bond]]s with two hydrogen atoms, yielding the "free radical" [[methylene radical|methylene]] CH<sub>2</sub>, the simplest of the [[carbene]]s. The carbon atom can also bond to four hydrogen atoms by an excitation of an electron from the doubly occupied 2s orbital to the empty 2p orbital, so that there are four singly occupied orbitals.  
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As the energy released by formation of two additional bonds more than compensates for the excitation energy required, the formation of four C-H bonds is energetically favoured.
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Quantum mechanically, the lowest energy is obtained if the four bonds are equivalent which requires that they be formed from equivalent orbitals on the carbon. A set of four equivalent orbitals can be obtained which are linear combinations of the valence-shell (core orbitals are almost never involved in bonding) s and p wave functions<ref>McMurray, J. (1995). Chemistry Annotated Instructors Edition (4th ed.). Prentice Hall. p. 272. ISBN 978-0-131-40221-8</ref> which are the  four '''sp<sup>3</sup> hybrids'''.
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In CH<sub>4</sub>, four sp<sup>3</sup> hybrid orbitals are overlapped by [[hydrogen]] 1s orbitals, yielding four [[sigma bond|σ (sigma) bonds]] (that is, four single covalent bonds) of equal length and strength.
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[[Image:Ch4 hybridization.svg|A schematic presentation of hybrid orbitals overlapping hydrogen orbitals]] translates into [[Image:Ch4-structure.png|Methane's tetrahedral shape]]
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[[Image:AE3h.svg|thumb|150px|Three sp<sup>2</sup> orbitals.]]
 
[[Image:Ethene-2D-flat.png|thumb|120px|Ethene structure]]
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Other carbon based compounds and other molecules may be explained in a similar way as methane. For example, [[ethene]] (C<sub>2</sub>H<sub>4</sub>) has a double bond between the carbons.
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For this molecule, carbon will sp<sup>2</sup> hybridise, because one [[pi bond|π (pi) bond]] is required for the [[covalent bond|double bond]] between the carbons, and only three σ bonds are formed per carbon atom. In '''sp<sup>2</sup> hybridisation''' the 2s orbital is mixed with only two of the three available 2p orbitals:
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forming a total of three sp<sup>2</sup> orbitals with one p orbital remaining. In ethylene ([[ethene]]) the two carbon atoms form a σ bond by overlapping two sp<sup>2</sup> orbitals and each carbon atom forms two covalent bonds with hydrogen by s–sp<sup>2</sup> overlap all with 120° angles. The π bond between the carbon atoms perpendicular to the molecular plane is formed by 2p–2p overlap. The hydrogen–carbon bonds are all of equal strength and length, which agrees with experimental data.
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=== sp hybrids ===
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[[Image:AE2h.svg|thumb|150px|Two sp orbitals]]
 
The chemical bonding in compounds such as [[alkyne]]s with triple bonds is explained by '''sp hybridisation'''.
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In this model, the 2s orbital mixes with only one of the three p orbitals resulting in two sp orbitals and two remaining unchanged p orbitals. The chemical bonding in [[acetylene]] (ethyne) (C<sub>2</sub>H<sub>2</sub>) consists of sp–sp overlap between the two carbon atoms forming a σ bond and two additional [[pi bonds|π bonds]] formed by p–p overlap. Each carbon also bonds to hydrogen in a σ s–sp overlap at 180° angles.
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Hybridisation helps to explain [[molecular geometry|molecule shape]] since the angles between bonds are (approximately) equal to the angles between hybrid orbitals, as explained above for the tetrahedral geometry of methane. As another example, the three sp<sup>2</sup> hybrid orbitals are at angles of 120° to each other, so this hybridisation favours [[trigonal planar molecular geometry]] with bond angles of 120°. Other examples are given in the table below.
 
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{| class="wikitable"
== Louboutin Greece Xing ==
! Classification
! Main group
! Transition metal<!-- Please do not put high-spin complexes under the examples as they have anti-bonding electrons which prevents a simple correspondence between electronic configuration and hybridisation. --><ref>{{cite book |last1=Weinhold |first1= Frank |last2= Landis |first2= Clark R. |title=Valency and bonding: A Natural Bond Orbital Donor-Acceptor Perspective |location=Cambridge |publisher=Cambridge University Press |year=2005 |pages=381–383 |isbn=978-0-521-83128-4}}</ref>
|-----
! AX<sub>2</sub>
|
* [[linear molecular geometry|Linear]] (180°)
* sp hybridisation
* E.g., CO<sub>2</sub>
|
* [[bent molecular geometry|Bent]] (90°)
* sd hybridisation
* E.g., VO<sub>2</sub><sup>+</sup>
|-----
! AX<sub>3</sub>
|
* [[trigonal planar molecular geometry|Trigonal planar]] (120°)
* sp<sup>2</sup> hybridisation
* E.g., BCl<sub>3</sub>
|
* [[trigonal pyramidal molecular geometry|Trigonal pyramidal]] (90°)
* sd<sup>2</sup> hybridisation
* E.g., CrO<sub>3</sub>
|-----
! AX<sub>4</sub>
|
*[[tetrahedral molecular geometry|Tetrahedral]] (109.5°)
* sp<sup>3</sup> hybridisation
* E.g., CCl<sub>4</sub>
|
*[[tetrahedral molecular geometry|Tetrahedral]] (109.5°)
* sd<sup>3</sup> hybridisation
* E.g., MnO<sub>4</sub><sup>−</sup>
|-----
! AX<sub>5</sub>
| align="center" | -
|
* [[Square pyramidal molecular geometry|Square pyramidal]] (66°, 114°)<ref name=Kaupp>{{cite journal
| title = "Non-VSEPR" Structures and Bonding in d(0) Systems
| first = Martin | last = Kaupp
| journal = Angew Chem Int Ed Engl.
| year = 2001
| volume = 40
| issue = 1
| pages = 3534–3565
| doi 10.1002/1521-3773(20011001)40:19<3534::AID-ANIE3534>3.0.CO;2-#
}}</ref><ref name=RBKing>{{cite journal |journal= Coordination Chemistry Reviews |volume= 197 |year= 2000 |pages= 141–168 |title= Atomic orbitals, symmetry, and coordination polyhedra |first= R. Bruce |last= King }}</ref>
* sd<sup>4</sup> hybridisation
* E.g., Ta(CH<sub>3</sub>)<sub>5</sub>
|-----
! AX<sub>6</sub>
| align="center" | -
|
* [[trigonal prismatic molecular geometry|Trigonal prismatic]] (63°, 117°)<ref name=Kaupp/><ref name=RBKing/>
* sd<sup>5</sup> hybridisation
* E.g., W(CH<sub>3</sub>)<sub>6</sub>
|}


===Main group compounds with lone pairs===
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For main group compounds with lone electron pairs, the s orbital lone pair can be hybridised to a certain extent with the bond pairs.<ref name=Weinhold>{{cite web |url=http://isites.harvard.edu/fs/docs/icb.topic818673.files/Lecture%202%20-%20Weinhold%20et%20al%20-%20Shape%20of%20Oxygen%20Lone%20Pairs.pdf |title=Rabbit Ears Hybrids, VSEPR Sterics, and Other Orbital Absurdities |first=Frank |last=Weinhold |year= |work= |publisher= |location=University of Wisconsin |accessdate=2012-11-11}}</ref> This is analogous to s-p mixing in [[molecular orbital theory]], and maximizes energetic stability according to the [[Walsh diagram]] for the molecule. This rationalisation is applied to explain deviations from ideal bond angles, such as when only p orbitals are used for bonding, most commonly in second and third period elements.
 
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* [[trigonal pyramidal molecular geometry|Trigonal pyramidal]] (AX<sub>3</sub>E<sub>1</sub>)
== Nike παπουτσια Συνεχίζει ==
** The s-orbital can be hybridised with the three p-orbital bonds to give bond angles greater than 90°.
** Ex. NH<sub>3</sub>
* [[bent molecular geometry|Bent]] (AX<sub>2</sub>E<sub>1-2</sub>)
** The s-orbital lone pair can be hybridised with the two p-orbital bonds to give bond angles greater than 90°. The out-of-plane p-orbital can either be a lone pair or pi bond. If it is a lone pair, the in-plane and out-of-plane lone pairs are inequivalent, contrary to the common picture depicted by VSEPR theory (see below).
** Exs. SO<sub>2</sub>, H<sub>2</sub>O
* Monocoordinate (AX<sub>1</sub>E<sub>1-3</sub>)
** The s-orbital lone pair can be hybridised with the p-orbital bond. The two out-of-line p-orbitals can either be lone pairs or pi bonds. The p-orbital lone pairs are not equivalent to the s-rich lone pair.
** Exs. CO, SO, HF


== Hybridisation of [[hypervalent molecule]]s ==
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=== Traditional description ===
== Nike Millenium  αλλά hey ==
In general chemistry courses and mainstream textbooks, hybridisation is often presented for main group AX<sub>5</sub> and above, as well as for transition metal complexes, using the hybridisation scheme first proposed by Pauling.
{| class="wikitable"
! Classification
! Main group
! Transition metal<!-- Please do not put high-spin complexes under the examples as they have anti-bonding electrons which prevents a simple correspondence between electronic configuration and hybridisation. -->
|-----
! AX<sub>2</sub>
| align="center" | -
|
* [[linear molecular geometry|Linear]] (180°)
* sp hybridisation
* E.g., Ag(NH<sub>3</sub>)<sub>2</sub><sup>+</sup>
|-----
! AX<sub>3</sub>
| align="center" | -
|
* [[trigonal planar molecular geometry|Trigonal planar]] (120°)
* sp<sup>2</sup> hybridisation
* E.g., Cu(CN)<sub>3</sub><sup>2−</sup>
|-----
! AX<sub>4</sub>
| align="center" | -
|
* [[square planar molecular geometry|Square planar]] (90°)
* dsp<sup>2</sup> hybridisation
* E.g., PtCl<sub>4</sub><sup>2−</sup>
|-----
! AX<sub>5</sub>
|
*[[trigonal bipyramidal molecular geometry|Trigonal bipyramidal]] (90°, 120°)
* sp<sup>3</sup>d hybridisation
* E.g., PCl<sub>5</sub>
|
*[[trigonal bipyramidal molecular geometry|Trigonal bipyramidal]] (90°, 120°)
* dsp<sup>3</sup> hybridisation
* E.g., Fe(CO)<sub>5</sub>
|-----
! AX<sub>6</sub>
|
*[[octahedral molecular geometry|Octahedral]] (90°)
* sp<sup>3</sup>d<sup>2</sup> hybridisation
* E.g., SF<sub>6</sub>
|
*[[octahedral molecular geometry|Octahedral]] (90°)
* d<sup>2</sup>sp<sup>3</sup> hybridisation
* E.g., Mo(CO)<sub>6</sub>
|-----
! AX<sub>7</sub>
|
*[[pentagonal bipyramidal molecular geometry|Pentagonal bipyramidal]] (90°, 72°)
* sp<sup>3</sup>d<sup>3</sup> hybridisation
* E.g., IF<sub>7</sub>
|
*[[pentagonal bipyramidal molecular geometry|Pentagonal bipyramidal]] (90°, 72°)
* d<sup>3</sup>sp<sup>3</sup> hybridisation
* E.g., V(CN)<sub>7</sub><sup>4−</sup>
|-----
! AX<sub>8</sub>
|
*[[square antiprismatic molecular geometry|Square antiprismatic]]
* sp<sup>3</sup>d<sup>4</sup> hybridisation
* E.g., IF<sub>8</sub><sup>−</sup>
|
*[[square antiprismatic molecular geometry|Square antiprismatic]]
* d<sup>4</sup>sp<sup>3</sup> hybridisation
* E.g., Re(CN)<sub>8</sub><sup>3−</sup>
|-----
! AX<sub>9</sub>
| align="center" | -
|
*[[Tricapped trigonal prismatic molecular geometry|Tricapped trigonal prismatic]]
* d<sup>5</sup>sp<sup>3</sup> hybridisation
* E.g., ReH<sub>9</sub><sup>2−</sup>
|}


In this notation, d orbitals of main group atoms are listed after the s and p orbitals since they have the same principal quantum number (''n''), while d orbitals of transition metals are listed first since the s and p orbitals have a higher n. Thus for AX<sub>5</sub> molecules, sp<sup>3</sup>d hybridisation in the P atom involves 3s, 3p and 3d orbitals, while dsp<sup>3</sup> for Fe involves 3d, 4s and 4p orbitals.  
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However, hybridisation of s, p and d orbitals together is no longer accepted, as more recent calculations based on molecular orbital theory have shown that in main-group molecules the d component is insignificant, while in transition metal complexes the p component is insignificant (see below).
== Hollister Berlin Reuters ==


=== Resonance description ===
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As shown by computational chemistry, [[hypervalent molecule]]s can only be stable given strongly polar (and weakened) bonds with electronegative ligands such as fluorine or oxygen to reduce the valence electron occupancy of the central atom to a maximum of 8<ref>{{cite journal
 
| title = Chemical Bonding to Hypercoordinate Second-Row Atoms: d Orbital Participation versus Democracy
  <li>[http://www.zhonglvren.com/blog/?uid-1-action-viewspace-itemid-7066 http://www.zhonglvren.com/blog/?uid-1-action-viewspace-itemid-7066]</li>
| author = David L. Cooper , Terry P. Cunningham , Joseph Gerratt , Peter B. Karadakov , Mario Raimondi
 
| journal = [[Journal of the American Chemical Society]]
  <li>[http://www.zhonglvren.com/blog/?uid-20101-action-viewspace-itemid-7211 http://www.zhonglvren.com/blog/?uid-20101-action-viewspace-itemid-7211]</li>
| year = 1994
 
| volume = 116
  <li>[http://www.sebalo.info/spip/spip.php?article14 http://www.sebalo.info/spip/spip.php?article14]</li>
| issue = 10
 
| pages = 4414–4426
  <li>[http://lab.nqnwebs.com/lavoz_bak/spip.php?article13211/ http://lab.nqnwebs.com/lavoz_bak/spip.php?article13211/]</li>
| doi = 10.1021/ja00089a033
 
}}</ref> (or 12 for transition metals). This requires an explanation that invokes [[sigma bond|sigma]] [[resonance (chemistry)|resonance]] in addition to hybridisation, which implies that each resonance structure has its own hybridisation scheme. As a guideline, all resonance structures have to obey the octet rule for main group compounds and the dodectet (12) rule for transition metal complexes.
  <li>[http://verdamilio.net/tonio/spip.php?article1970/ http://verdamilio.net/tonio/spip.php?article1970/]</li>
 
</ul>


{| class="wikitable"
== Barbour Paris  et se jeta à ses pieds ==
! Classification
! Main group
! Transition metal<!-- Please do not put high-spin complexes under the examples as they have anti-bonding electrons which prevents a simple correspondence between electronic configuration and hybridisation. -->
|-----
! rowspan="2"| AX<sub>2</sub>
| align="center" rowspan="2"| -
| align="center"| [[linear molecular geometry|Linear]] (180°)
|-----
| align="center"|[[File:Di silv.svg|300px]]
|-----
! rowspan="2"| AX<sub>3</sub>
| align="center" rowspan="2"| -
| align="center"| [[trigonal planar molecular geometry|Trigonal planar]] (120°)
|-----
| align="center"|[[File:Tri copp.svg|320px]]
|-----
! rowspan="2"| AX<sub>4</sub>
| align="center" rowspan="2"| -
| align="center"| [[square planar molecular geometry|Square planar]] (90°)
|-----
| align="center"|[[File:Tetra plat.svg|320px]]
|-----
! rowspan="2"| AX<sub>5</sub>
| align="center"|[[trigonal bipyramidal molecular geometry|Trigonal bipyramidal]] (90°, 120°)
| align="center"|[[trigonal bipyramidal molecular geometry|Trigonal bipyramidal]] (90°, 120°)
|-----
| align="center"|[[File:Penta phos.png|400px]]
|
* Fractional hybridisation (s and d orbitals)
* E.g., Fe(CO)<sub>5</sub>
|-----
! rowspan="2"| AX<sub>6</sub>
| align="center"|[[octahedral molecular geometry|Octahedral]] (90°)
| align="center"|[[octahedral molecular geometry|Octahedral]] (90°)
|-----
| align="center"|[[File:Hexa sulf.png|300px]]
| align="center"|[[File:Hexa moly.svg|300px]]
|-----
! rowspan="2"| AX<sub>7</sub>
| align="center"|[[pentagonal bipyramidal molecular geometry|Pentagonal bipyramidal]] (90°, 72°)
| align="center"|[[pentagonal bipyramidal molecular geometry|Pentagonal bipyramidal]] (90°, 72°)
|-----
| align="center"|[[File:Hepta iodi.svg|420px]]
|
* Fractional hybridisation (s and three d orbitals)
* E.g., V(CN)<sub>7</sub><sup>4−</sup>
|-----
! rowspan="2"| AX<sub>8</sub>
| align="center"| [[square antiprismatic molecular geometry|Square antiprismatic]]
| align="center"|[[square antiprismatic molecular geometry|Square antiprismatic]]
|-----
|
* Fractional hybridisation (s and three p orbitals)
* E.g., IF<sub>8</sub><sup>−</sup>
|
* Fractional hybridisation (s and four d orbitals)
* E.g., Re(CN)<sub>8</sub><sup>3−</sup>
|-----
! rowspan="2"| AX<sub>9</sub>
| align="center" rowspan="2"| -
| align="center"|[[Tricapped trigonal prismatic molecular geometry|Tricapped trigonal prismatic]]
|-----
|
* Fractional hybridisation (s and five d orbitals)
* E.g., ReH<sub>9</sub><sup>2−</sup>
|}


==== Main group compounds with lone pairs ====
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For hypervalent main group compounds with lone electron pairs, the bonding scheme can be split into two components: the "resonant bonding" component and the "regular bonding" component. The "regular bonding" component has the same description (see above), while the "resonant bonding" component consists of resonating bonds utilizing p orbitals. The table below shows how each shape is related to the two components and their respective descriptions.
 
  <li>[http://verdamilio.net/tonio/spip.php?article1678/ http://verdamilio.net/tonio/spip.php?article1678/]</li>
 
  <li>[http://ciarcr.org/spip.php?article310/ http://ciarcr.org/spip.php?article310/]</li>
 
  <li>[http://verdamilio.net/tonio/spip.php?article1968/ http://verdamilio.net/tonio/spip.php?article1968/]</li>
 
  <li>[http://220.194.55.213:8086/forum.php?mod=viewthread&tid=3694918 http://220.194.55.213:8086/forum.php?mod=viewthread&tid=3694918]</li>
 
  <li>[http://general.assembly.codesria.org/spip.php?article87&lang=pt/ http://general.assembly.codesria.org/spip.php?article87&lang=pt/]</li>
 
</ul>


{| class="wikitable"
== Nike Heels  oignons rouges . ==
| colspan="2" rowspan="2"|
! colspan="3"| Regular bonding component (marked in red)
|-----
! Bent
! Monocoordinate
! align="center" | -
|-----
! rowspan="6"| Resonant bonding component
! rowspan="2"|Linear axis
| align="center" | [[Seesaw molecular geometry|Seesaw]] (AX<sub>4</sub>E<sub>1</sub>) (90°, 180°, >90°)
| align="center" | [[T-shaped molecular geometry|T-shaped]] (AX<sub>3</sub>E<sub>2</sub>) (90°, 180°)
| align="center" | [[Linear molecular geometry|Linear]] (AX<sub>2</sub>E<sub>3</sub>) (180°)
|-----
| align="center"|[[File:Tetra sulf.svg|160px]]
| align="center"|[[File:Tri chlo.svg|160px]]
| align="center"|[[File:Di xeno.svg|160px]]
|-----
! rowspan="2"|Square planar equator
| align="center" rowspan="2"| -
| align="center" | [[Square pyramidal molecular geometry|Square pyramidal]] (AX<sub>5</sub>E<sub>1</sub>) (90°, 90°)
| align="center" | [[Square planar molecular geometry|Square planar]] (AX<sub>4</sub>E<sub>2</sub>) (90°)
|-----
| align="center"|[[File:Penta chlo.svg|240px]]
| align="center"|[[File:Tetra xeno.svg|240px]]
|-----
! rowspan="2"|Pentagonal planar equator
| align="center" rowspan="2"| -
| align="center" | [[Pentagonal pyramidal molecular geometry|Pentagonal pyramidal]] (AX<sub>6</sub>E<sub>1</sub>) (90°, 72°)
| align="center" | [[Pentagonal planar molecular geometry|Pentagonal planar]] (AX<sub>5</sub>E<sub>2</sub>) (72°)
|-----
| align="center"|[[File:Hexa xeno.svg|240px]]
| align="center"|[[File:Penta xeno.svg|240px]]
|}


==Clarifying misconceptions==
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  <li>[http://www.sebalo.info/spip/spip.php?article14 http://www.sebalo.info/spip/spip.php?article14]</li>
 
  <li>[http://citoyensdumonde.fr/spip.php?article132/ http://citoyensdumonde.fr/spip.php?article132/]</li>
 
  <li>[http://www.zhonglvren.com/blog/?uid-20107-action-viewspace-itemid-9396 http://www.zhonglvren.com/blog/?uid-20107-action-viewspace-itemid-9396]</li>
 
</ul>


===VSEPR electron domains and hybrid orbitals are different===
== Hollister New York  vous êtes sur le site en ce moment ==
The simplistic picture of hybridisation taught in conjunction with VSEPR theory does not agree with high-level theoretical calculations<ref name=Weinhold/> despite its widespread usage in many textbooks. For example, following the guidelines of VSEPR, the hybridization of the oxygen in water is described with two equivalent lone electron-pairs.<ref>Petrucci R.H., Harwood W.S. and Herring F.G. "General Chemistry. Principles and Modern Applications" (Prentice-Hall 8th edn 2002) p. 441</ref> However, [[molecular orbital]] calculations give orbitals that reflect the [[Molecular symmetry#Common point groups|C<sub>2v</sub> symmetry]] of the molecule.<ref name=Levine470>Levine I.N. “Quantum chemistry” (4th edn, Prentice-Hall) p. 470–2</ref> One of the two lone pairs is in a pure p-type orbital, with its electron density perpendicular to the H–O–H framework.<ref name=Laing>[http://dx.doi.org/10.1021/ed064p124 Laing, Michael ''J. Chem. Educ.'' (1987) '''64''', 124–128] "No rabbit ears on water. The structure of the water molecule: What should we tell the students?"</ref> The other lone pair is in an approximately sp<sup>0.8</sup> orbital that is in the same plane as the H–O–H bonding.<ref name=Laing/> [[Ultraviolet photoelectron spectroscopy|Photoelectron spectra]] confirm the presence of two different energies for the nonbonded electrons.<ref>Levine p. 475</ref>


=== Non-inclusion of d orbitals in main group compounds ===
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{{main|Hypervalent molecule}}
 
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</ul>


In 1990, Magnusson published a seminal work definitively excluding the role of d-orbital hybridization in bonding in hypervalent compounds of second-row elements. This had long been a point of contention and confusion in describing these molecules using molecular orbital theory. Part of the confusion here originates from the fact that one must include d-functions in the basis sets used to describe these compounds (or else unreasonably high energies and distorted geometries result), and the contribution of the d-function to the molecular wavefunction is large.  These facts were historically interpreted to mean that d-orbitals must be involved in bonding.  However, Magnusson concludes in his work that d-orbital involvement is not implicated in hypervalency.<ref name="ReferenceA">E. Magnusson. Hypercoordinate molecules of second-row elements: d functions or d orbitals? ''J. Am. Chem. Soc.'' '''1990''', ''112'', 7940-7951. {{doi|10.1021/ja00178a014}}</ref>
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=== Non-inclusion of p orbitals in transition metal complexes ===
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Similarly, p orbitals have long been thought to be utilized by transition metal centers in bonding with ligands, hence the [[18-electron rule|18-electron]] description; however, recent [[molecular orbital]] calculations have found that such p orbital participation in bonding is insignificant,<ref>{{cite journal
 
| title = Valence and extra-valence orbitals in main group and transition metal bonding
  <li>[http://lab.nqnwebs.com/lavoz_bak/spip.php?article3099/ http://lab.nqnwebs.com/lavoz_bak/spip.php?article3099/]</li>
| author = C. R. Landis, F. Weinhold
 
| journal = [[Journal of Computational Chemistry]]
  <li>[http://www.general.assembly.codesria.org/spip.php?article87&lang=fr/ http://www.general.assembly.codesria.org/spip.php?article87&lang=fr/]</li>
| year = 2007
 
| volume = 28
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}}</ref><ref>{{cite web |url=http://www.bowdoin.edu/student-fellowships/pdf/summer-2012/ODonnell%20SRR.pdf |title=Investigating P-Orbital Character In Transition Metal-to-Ligand Bonding |first=Mark |last=O’Donnell |year=2012 |work= |publisher=Bowdoin College |location= Brunswick, ME |accessdate=2012-09-16}}</ref> even though the contribution of the p-function to the molecular wavefunction is calculated to be somewhat larger than that of the d-function in main group compounds.
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==Hybridization theory vs. Molecular Orbital theory==
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Hybridisation theory is an integral part of [[organic chemistry]] and in general discussed together with [[molecular orbital theory]] in advanced organic chemistry textbooks although for different reasons. One textbook notes that for drawing reaction mechanisms sometimes a classical bonding picture is needed with two atoms sharing two electrons.<ref>{{Clayden|page=105}}</ref> It also comments that predicting bond angles in methane with MO theory is not straightforward. Another textbook treats hybridisation theory when explaining bonding in alkenes<ref>''Organic Chemistry'', Third Edition Marye Anne Fox James K. Whitesell '''2003''' ISBN 978-0-7637-3586-9</ref> and a third<ref>''Organic Chemistry'' 3rd Ed. '''2001''' Paula Yurkanis Bruice ISBN 978-0-130-17858-9</ref> uses MO theory to explain bonding in hydrogen but hybridisation theory for methane.
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Bonding orbitals formed from hybrid atomic orbitals may be considered as [[localized molecular orbitals]], which can be formed from the delocalized orbitals of molecular orbital theory by an appropriate mathematical transformation. For molecules with a closed electron shell in the ground state, this transformation of the orbitals leaves the total many-electron wave function unchanged. The hybrid orbital description of the ground state is therefore ''equivalent'' to the delocalized orbital description for explaining the ground state total energy and electron density, as well as the molecular geometry which corresponds to the minimum value of the total energy.
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There is no such equivalence, however, for ionized or excited states with open electron shells. Hybrid orbitals cannot therefore be used to interpret photoelectron spectra, which measure the energies of ionized states, identified with delocalized orbital energies using [[Koopmans' theorem]]. Nor can they be used to interpret UV-visible spectra which correspond to electronic transitions between delocalized orbitals. From a pedagogical perspective, the hybridisation approach tends to over-emphasize localisation of bonding electrons and does not effectively embrace [[molecular symmetry]] as does MO theory.
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== See also ==
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* [[Linear combination of atomic orbitals molecular orbital method]]
* [[MO diagram]]s
* [[Ligand field theory]]
* [[Crystal field theory]]


== References ==
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== External links ==
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* [http://wps.prenhall.com/wps/media/objects/602/616516/Chapter_07.html Covalent Bonds and Molecular Structure]
* [http://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/hybrv18.swf Hybridisation flash movie]
* [http://adomas.org/hopv/ Hybrid orbital 3D preview program in OpenGL]
* [http://college.hmco.com/chemistry/shared/media/zumdahl/dswmedia/undr_dcr/Ch14_u14a.dcr Understanding Concepts: Molecular Orbitals]


{{DEFAULTSORT:Orbital Hybridisation}}
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Ακριβώς φάνηκε σαν διασκέδαση, και για μια αιτία πιστεύουμε ακράδαντα, δήλωσε ο ιδιοκτήτης Gray Brooks. Εάν δεν υπάρχει σπινθήρας, κάθε άτομο μπορεί να πατήσει δίπλα σε οποιοδήποτε σημείο να προχωρήσουμε σε κάποιον νέο. Εξακολουθούν να αισθάνονται ότι δεν παίρνουν το σεβασμό που αισθάνονται ότι αξίζουν και με όλες τις συζητήσεις γύρω από το λεωφορείο των υποψηφιοτήτων έτους, πολλοί εξακολουθούν να επισημαίνουν στον John Harbaugh και Mike Smith και τους κορυφαίους υποψηφίους.

Θα συνεχίσει να υπηρετεί την κοινότητα. Αναζήτηση Facebook και άλλες ιστοσελίδες κοινωνικής δικτύωσης όπως το MySpace, LinkedIn, Xing, προφίλ Wikipedia και πολλά άλλα. Θα δούμε πώς Nike Shoes αυτό λειτουργεί! Ευχαριστώ για πληροφορίες .. Θα θέλαμε να επεκτείνει κάποιες πολύ ιδιαίτερες ευχαριστίες στους CSS 3 δεξιότητες ninja του paradox460 στο σχεδιασμό και την ανάπτυξη έργο του σχετικά με αυτό το app (η blowbyblow μπορούν να βρεθούν στο blog του).

Όταν ψάχνετε για κακή βελτιστοποιημένες ιστοσελίδες, να δώσουν προσοχή στην τοποθέτηση διαφήμισης τους. L de l βιο est donc trs antrieure la gnralisation de la συνείδηση ​​cologique au sein des πληθυσμούς et l de cette judicieuse recommandation selon laquelle il vaut mieux ne pas ses mettre ordures Nike Europe dans le sac mme.

Nike παπουτσια Συνεχίζει

Συνεχίζει: «Τώρα είναι η ώρα να καταλάβουμε τι είναι πραγματικά καλοί στο να κάνουν.' Βρείτε εργοδότες που χρειάζονται ό, τι είναι αυτό που υπερέχουν σε να γίνει. Για να ληφθεί σοβαρά υπόψη και να είναι επιτυχής, θα πρέπει να γίνει λιγότερο γενικά, και να αποδείξει στον εργοδότη πώς είστε μια καλή τακτοποίηση από την τιμή που μπορείτε να φέρετε μαζί σας σε μια πρώτη θέση εργασίας.

Εάν έχετε ένα σύνθετο περιβάλλον, don έχετε ξεδιπλώσει όλα με τη μία. Ρυθμίστε το gameplay αυτός ο παίκτης έχει την ευκαιρία να το συνηθίσετε κάθε λειτουργίας. Αποφύγετε την τοποθέτηση tutorials στο παιχνίδι. Θα σπάσει την ατμόσφαιρα, και ο παίκτης θα πρέπει να υπενθυμίσουμε ότι είναι ένα παιχνίδι. Συνεπώς, δεν βύθιση! Εάν έχετε μια σκηνή παιχνιδιού ότι, ενώ το αστείο θα μπορούσε να γίνει πολύ απογοητευτικό Nike παπουτσια όσον αφορά τους ελέγχους, τουλάχιστον προσθέσει τη δυνατότητα να το παρακάμψετε ή μια εναλλακτική λύση. Στην αρχική Infocom υπάρχουν αυτά τα πραγματικά δροσερό σκηνές που ονομάζεται όπου είστε υποτίθεται για να τις αισθήσεις σας. Αυτές οι σκηνές λειτουργούν τέλεια με ένα πρόγραμμα ανάλυσης κειμένου, και ίσως δεν είναι και τόσο άσχημα με μια διεπαφή οροσειρά στυλ. Αλλά εξακολουθώ να τους επιτρέπει να παραλειφθεί.

Έλα εδώ και μπορείτε να απολαύσετε μερικά από τα πιο νησιού ενδιαφέρουσες ιστορίες. Για παράδειγμα, έχει προηγούμενα ήταν μια στρατιωτική βάση, καθώς Christian Louboutin Greece και ένα πειρατικό κρησφύγετο. Ανάμεσα στα κορυφαία μέρη για να επισκεφτείτε είναι τα ερείπια του Fort Rodney. Ως μπόνους, τη στιγμή που θα φτάσετε στην κορυφή της Fort Rodney Hills, μπορείτε να πάρετε μερικές πραγματικά απίστευτη θέα.

Δουλεύουμε μαζί ως ομάδα για να διαλευκάνουν τα ιερά μυστήρια της ζωής. 'Aluna επινόησε τον όρο« ιερό χώρο πρεζόνι ', επειδή αυτή είναι μία ίδια. Μετά το πρώτο ταξίδι της Τουλούμ, Μεξικό, η ζωή της άλλαξε δραματικά, και είχε σταλεί στο μια εντελώς διαφορετική πορεία στη ζωή. Δεδομένου ότι αυτή τη φορά, το έργο της έχει επηρεαστεί από αμέτρητες σαμανικές εμπειρίες σε ιερούς τόπους του Μεξικό, Γουατεμάλα, Μπελίζ, Ονδούρα, το Περού, τη Βολιβία, την Αίγυπτο, την Ελλάδα, την Αγγλία, την Αυστραλία και τη Νέα Ζηλανδία.

Αγοράστε το στο Louboutin Shoes bookshop4 Guardian. Έχω επιλέξει αυτοβιογραφικό του High Priest (1968) για τον κατάλογο αυτό, καθώς πιστεύω ότι είναι ένα από τα πιο καταφέρει κομμάτια της γραφής. Συλλαμβάνει τόσο την εμπειρία των ναρκωτικών και την αίσθηση της ανακάλυψης τόσο καλά? τη στιγμή που ένας επιστήμονας συνειδητοποιεί ότι οι επιπτώσεις της εργασίας Nike Shoes τους είναι τόσο μεγάλη που η ζωή τους δεν θα είναι ποτέ η ίδια again.5. Αδελφές του Extreme: Γυναίκες εγγράφως σχετικά με την εμπειρία των ναρκωτικών από Cynthia Palmer και Michael Horowitz (επιμ.)

Nike Millenium αλλά hey

Υπήρχαν πολλά μπλουζάκια με συνθήματα που έγραφε, 'Made in America με την ιταλική μέρη.' Μπορείτε επίσης να δείτε μπλουζάκια λέγοντας IBM στέκεται για 'Ιταλική από το γάμο, και την παλαιά παροιμία,' FBI ', που σημαίνει fullblooded ιταλικά. Μπορείτε επίσης να δείτε τον ίδιο τύπο μπλουζάκια σε άλλες εθνοτικές τρόφιμα και μουσικά φεστιβάλ όπως το ετήσιο Ελληνικό Φεστιβάλ Τροφίμων Σακραμέντο στα τέλη του Αυγούστου.

Πάνω από όλα αυτό γινόταν πολύ αβέβαιο ότι το επόμενο άλμπουμ τους θα πάρει κυκλοφορήσει καθόλου από CBS που είχε κυκλοφορήσει ένα πολύ ελάχιστο αριθμό Black Box άλμπουμ στην Αμερική και έκανε σχεδόν καμία υποστήριξη του έργου σε όλα. Αποφασίστηκε ότι ήρθε η ώρα να σπάσει το πάνω συγκρότημα και όλοι θα ακολουθήσουν ξεχωριστούς δρόμους. Κανείς δεν θα συνεχίσει ως το Queen City Kids. Αντ 'αυτού, ο John και ο Jeff σχηματίζεται ένα πανκ συγκρότημα που ονομάζεται Αγάπη Active με τον πρώην τραγουδιστή Doris Daze Kim Albright. Alex βγήκε με ένα νέο πρόγραμμα Nike Millenium που ονομάζεται Straw Dog. Ενώ Cal freelanced με ορισμένες ομάδες Regina και αργότερα με Christian Louboutin Greece Kenny Shields.

Ναι, οι περισσότεροι από εμάς έχουν σπρώχνεται ή θα prod τουλάχιστον μία γυναίκα στο πίσω κάθισμα (ή μπροστινό κάθισμα) των αυτοκινήτων μας. Εντάξει, έτσι ώστε να μπορεί να Nike Shoes μην είναι η πιο ευρύχωρη κηλίδες και ίσως τα εγκαύματα γόνατο θα διαρκέσει για μέρες, αλλά hey, αυτό θα είναι μια αρέσει μνήμης τη στιγμή Louboutin Greece που θα πάρει όλους τους λεκέδες από την ταπετσαρία.

Περιοχές Υψηλή περιεκτικότητα σε σίδηρο; άγκυρα την εργασία σας στον κόσμο και κατέχει τη μνήμη στη θέση του. Γη είναι γνωστό για να ρίξει το μαγνητικό πεδίο του κατά καιρούς ενός πλανητικού στροφή, και αυτό επηρεάζει τη μνήμη σας. Βραχυπρόθεσμη μνήμη είναι το πρώτο πράγμα που γίνεται με μαγνητική σταγόνες. Θυμάστε τι είχε για πρωινό; Όταν η Γη σταγόνες μαγνήτες, οι άνθρωποι κλίνουν σε υψηλές θέσεις του σιδήρου. Αν είναι κατανεμημένες, ένα περιβάλλον υψηλής σιδήρου μπορεί να μεταδιεγείρουν αιθέρια κόσμους σε χρησιμοποιήσιμη μορφή. Με άλλα λόγια, μπορείτε να καταλάβετε διανοητικά αιθέρια κόσμους. Το μειονέκτημα είναι ότι εγώ μπορεί να υπάρχουν σε υψηλές θέσεις σιδήρου και μπορεί να επηρεάσει τη δουλειά μας εάν η κατάλληλη προσοχή δεν δίνεται στην τελειότητα. Σεντόνα της Αριζόνα, Zion National Park Utah, Alice Spring Uluru στην Αυστραλία, για να αναφέρουμε μερικά, είναι υψηλά περιβάλλοντα σιδήρου.

Για τα σχολεία, προσφέρει την ευκαιρία να προσφέρουν μαθήματα και τις ευκαιρίες μάθησης με τρόπο πιο πιθανό να εμπλέξει τους μαθητές σε σχέση με πιο παραδοσιακές μεθόδους και μπορεί να βοηθήσει τα παιδιά να φτάσει έξω από την τάξη (για οποιοδήποτε λόγο). Επιπλέον, η τεχνολογία RSS (Really Simple Syndication) που κατεβάζει νέα podcasts αυτόματα, κρατά τους χρήστες (μαθητές, γονείς, διοικητές και άλλοι) από χρειάζεται να επισκέπτεστε κάθε επιμέρους περιοχή.

Hollister Berlin Reuters

Hong Kong stocks SEESAW après les rapports PMI MarketWatchLOS ANGELES (Reuters) Les stocks de Hong Kong se balançaient entre les petits gains et pertes vendredi, avec des mouvements à la hausse limité en dépit de deux rapports distincts montrant l'activité manufacturière en Chine a été meilleure que prévu en Octobre.

Il ya d'autres joueurs qui vont faire le travail si quelqu'un leur fait faire, et les promenades en permanence à faire. L'Assemblée législative a jusqu'en 2018 pour arranger les choses, mais les juges veulent rapports annuels montrant des progrès mesurables.

J'ai également eu une rencontre il ya un peu moins de 2 ans qui m'a complètement aigri sur la gestion (en particulier l'ourson grande bah) et je n'arrive pas à obtenir le dépasser. Pour les femmes qui veulent plus d'un programme de remise en forme, fitness Natvision à Vaughan ON est là pour vous aider.

Pas très grand, il est. Nous nous réjouissons de vous rencontrer bientôt!. Dites à quelqu'un combien ils signifient pour vous., Le moment délicat quand votre prof de gym est plus gros que vous. J'ai eu un rendez-vous préprogrammés, par la manière. Tout le monde pense qu'ils sont un expert en optimisation de moteur de recherche.

En 1866, Bernadette a été envoyé aux Sœurs de Notre-Dame à Nevers. Ce n'est pas juste. Ou même si quelqu'un veut prendre pour bas et il séparer eux-mêmes pour un petit profit.. Je ne sais comment vous êtes vieux et évidemment il n est pas agréable d'aller contre vos parents souhaite mais j'ai vraiment l'impression que vous devez suivre vos propres désirs.

Ils ne Hollister Berlin se soucient pas de ce que vous appelez, tant que ce n'est pas minime. Il est facile de travailler avec et est un modèle de rôle à d'autres dans notre société qui sont en train d'apprendre. OneClick poney. Il suffit de fermer les yeux crevés à la télévision sur un volume bas et louchent un œil doucement pour regarder la télé.

Cullipher un problème. Cooper leur dit aussi de toujours ignorer ce Nike Femme que votre partenaire de scène fait, comme il est Ugg Femme le chemin de «grande action». Mais il est particulièrement enthousiasmés par le lancement Saga Candy Crush, un jeu de matchthree, sur mobile en raison de la façon dont elle le fait déjà sur Facebook.

Acheter Adipex 1111 n'est pas viagra circonscription échecs autre pièce Web relief de café trucs 2222 pierre corbeau plongée ont en ligne en ligne jaune un son. Nous bénéficions suites Hilton Homewood, les chambres sont toujours propres et apppointed et comprennent généralement un Hollister Geneve repas léger sur arrivial qui est super quand vous êtes fatigué de conduire la plupart du temps,.,., Également très important pour moi que fumeurs sont encore disponibles, mais depuis que mon mari est un non-fumeur, les chambres ne sentent pas smokey lui.

Barbour Paris et se jeta à ses pieds

Gagner de l'argent grâce à Internet est un moyen facile d'ajouter Barbour Paris vos gains. Dans les coulisses du Groupe Histoire. Le but de signalisation de cette déclaration est laissée en exercice au lecteur.. Période aura sites pas inscrit cuisine mondes de casino par une bande stratégies de marque de trucs On traite.

Prince-cérique a encore, à ce jour, pas été vu par les gens de Submertia. Je suppose que la seule raison que cela me dérange vraiment, c'est parce que j'aime à penser par moi-même. C'est une nuit qu'ils n'oublieront jamais. "Flinders Petrie. De même, lorsque de nouvelles notifications apparaissent sur la page d'accueil, un numéro rouge apparaît au-dessus d'accueil en haut de la page.

Il ya un petit supplément de 12 $ pour les membres de l'AARP et 14 $ pour les membres nonAARP à participer à la classe. Posez une question ou penser à quelque chose de rechercher et tapez-le dans la boîte de recherche. Stark perd la course pour le trésorier, mais fait plus tard son chemin à travers l'école de droit, devenir un avocat idéaliste qui se bat pour ce qui est bon.

Créer un titre accrocheur pour votre annonce et utiliser beaucoup de détails à informer votre auditoire de ce que vous vendez. Ces emplois en particulier, vous pouvez un travailleur si vous voulez faire d'autres choses dans le jeu. Rend toparts augmenté gonflement et courtier sur le marché de change du marché de change était clairement échanger marché courtier sans couronne de nouveau sera roi..

Je ne sentir aussi joli quand je couperai tout, ce que j'ai fait avant. Ces adresses ne sont pas utilisées à d'autres fins et ne sont pas partagées avec des tiers. Est-il possible de me faire rêver à ce sujet. Prix, St. Mais êtes-vous le coupable de dépassement de ce que vous prévu de pari et d'enlever de l'argent supplémentaire pour vos achats ou d'épicerie et l'utiliser pour parier? Les Ralph Lauren Suisse dépenses au-delà de votre limite dans les casinos en ligne peut être tentant, mais il ya des façons sur Ralph Lauren Pas Cher comment vous pouvez arrêter de perdre tout votre argent.

Carrelage Windows. C'était une histoire très inspaering pour moi. De fin Octobre jusqu'à la fin de Avril, les mesas à faible altitude sont un excellent choix. Comme la Forge of Fury n'est pas seulement un donjon avec duergars et troglodytes. Depuis 1998, il a aussi joué sur deux enregistrements et des tournées avec Paul Gilbert, anciennement de Mr.

Un slo clic sobre el icono situado junto a la vista Nike France previa de la imagen te llevar a la fuente. Valable Permis de conduire Ohio nécessaire. 25 Et comme Pierre entrait, Corneille vint à sa rencontre, et se jeta à ses pieds, et se prosterna devant lui.

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L'autre préoccupation est familier à quiconque a passé du temps avec FIR. Bon vieux DVD ne pouvait pas lui faire justice. Musiciens, marionnettistes, danseurs folkloriques, et magiciens exécuter à travers les motifs sur les scènes rustiques, tandis que les arômes de délicieux plats du sud étant cuit, frit, cuit, et au barbecue sur place par des organisations locales de citoyens, des écoles, des églises et remplit l'air.

Ele quis desafiar un letra da Msica e mudarlhe o sentido, reforando une idee de que ficar melhor soi quisermos por essa Razo quis por uma certa rotina lui Qué Eram obrigados un fazer tudo o Que LHE mandavam, par Qué transmitisse un mensagem Que Nos Devemos libertar e ser rebeldes, ir nos levar un lindas festas coloridas e fantsticas Seguese un importncia de seguir os Nossos sonhos.

La société a prévu un puits horizontal à la formation de schiste de Marcellus. C'est ce que j'avais prévu pour mon alimentation quotidienne: breakfast2 biscuits Weetabix organiques avec 1% de lait Nike Heels (je déteste écrémé, les goûts comme de Barbour Paris l'eau) de vanille lunchorganic ou fraise yogurtapplelow fromage gras stickdinnerbaked poitrine de poulet avec de la salade: laitue, avocat, tomates, concombres, oignons rouges .

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C'est alors que Dean et Brill formuler un plan pour la vie de Dean en arrière et tourner les tables sur Reynolds. Informations générales: Cette zone fournit des informations générales sur le lac Michigan. Loi applicable et règlement des différends. Page Moncler Femme d'hommes dorment sexe de Keith.

C'est la connexion et la façon dont j'ai pu vivre . Une façon de découvrir ces concerts est de vérifier les Problogger Job Boards, qui emplois liste de blog et les gens qui cherchent à embaucher des blogueurs. Le moteur physique permet des choses intéressantes à se produire.

Hollister New York vous êtes sur le site en ce moment

Le linge effiloché autour de son cou ressemblait à une déclaration de mode horriblement mal. Ils étaient fous de joie quand malicieusement Revan a changé de camp dans la guerre civile Jedi, et n'étaient que trop heureux de se joindre à son côté en elle, et a contribué à l'homme les nombreux navires qui semblaient venir de nulle part pendant ce temps.

Aéronefs ne sera jamais trop sûr pour les gens à profiter sans grande protection telles que Hollister New York la ceinture de sécurité. Pouvez vous tromper puis par «tourner» le contenu? Oui, mais vous devez tourner à droite vers le bas pour le niveau de fragment de phrase une tâche si compliquée qu'il n'y a actuellement qu'une seule solution qui peut faire allusion, vous êtes sur le site en ce moment, et il est plus «filage», c'est querelles contenu.

Probablement des centaines de maintenant. Tout le monde sait que tout ce qu'il faut pour faire une entreprise prospère dans le long terme, est Hollister Suisse d'avoir beaucoup de trafic qui deviennent des clients. Souhaitez peuple contre ce criminels ou désirer la liberté de commettre un crime avenir? Pas nécessairement.

Si Fox vend 100% des espaces publicitaires sur ils font 364 000 x 2 x 16 = US $ 11.648.000. Cela permet de plus longues durées de traitement et les périodes de soulagement de la douleur sans avoir à recharger l'enveloppe ou passer des compresses froides.

Attrapé le tout ma sœur. Il a été commenté par Phillip Zimbardo comme un problème possible qui peut se développer en raison des enfants qui grandissent autour des ordinateurs, qui peut alors manquer d'avoir des compétences sociales dans la vie plus tard.

Remplacement Louis Vuitton Pas Cher rapide cette fonctionnalité est destinée pour un remplacement rapide d'une partie de code HTML par l'autre. Ce site est un soulagement de la douleur et de la guérison des tissus blessés. J'aime Simba. Air Force SP à la porte: [au téléphone checkpoint en arrière-plan] de sécurité.

AUTOUR DE 10,7 hectares de terrains industriels à Osberstown, Naas Co. Donc, je n'ai pas vraiment le temps de s'asseoir et partie tout et configuration tout. Couplé avec le fait que ce type de cancer est si rare (PDF), les médecins ne sont pas susceptibles de venir avec un bon diagnostic jusqu'à ce que les tests appropriés ont été menées..

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Nike Free Run Homme et ils ont un grand choix à choisir.

Ce n'est pas aussi mauvaise qu'il y paraît, cependant. Jamais, jamais, jamais. Une fois que vous vous sentez comme neuf après tout que la transpiration, exfoliation et massage, vous pouvez compléter le sentiment de bonheur avec un thé à la menthe sucré dans la cour de la mosquée remplie de gazouillis des oiseaux et de plantes tropicales.

Oh, et je suis d'accord, Nike Free Run Homme Nintendo a vraiment besoin de prendre plus de risques, de nouveaux jeux, nouvelle série principale. "Vous avez l'idée du nombre de cas supérieur, des lettres et des symboles qui sont apparemment sans signification pour tout le monde mais vous.

Et en retour, il est appelé un bâtard arrogant. Voici une Beats Pill partie du contenu que vous souhaitez tout savoir? Plongez dans ce livre dès aujourd'hui!. Les données indiquent que de nombreuses populations de ces espèces ont considérablement diminué ... Le panneau de commande sur le tableau de bord était aussi un accroche-regard.

Photographies publiées montrent son matériel d'espionnage présumé dont perruques, une Tiffany And Co boussole, torche et même un atlas banales de Moscou ainsi qu'un peu vieux téléphone portable démodé. Il était bon d'avoir Ayrie rejoindre notre conversation pendant un moment ce soir.

Hourra. Que font-ils à réaliser cet exploit incroyable? Le choix de votre objectif de remise en forme est l'étape numéro un. En toute honnêteté, c'est fantastique! C'est frais, des goûts Lite (pas lourd), de bons prix, et Beats Pill ils ont un grand choix à choisir.

Conséquent de Mikelon il peut avoir été écrit à la française avec un "q" au lieu d'un "k" [9] [10] [11] Il semble que ce soit une forme très courante dans cette langue. Pour se rendre à la fête PvP dans Gauntlgrym, cependant, vous devez slog par un peu de monstre indéfinissable lutte d'abord et si vous voulez montrer vos prouesses de PvP avant vous atteignez le niveau 60, limitées à cinq contre cinq batailles êtes la seule façon de le faire .

Criminalité, la pauvreté et le suicide vont monter en flèche. La version 64 bits a des exigences plus élevées. En outre, parce que DNSSEC est encore rare, les navigateurs Web ont tendance à faire un mauvais travail de la soutenir. Ces situations sont tellement awkwards parfois.

/ ASO La solution n'est pas de réduire la peine pour tuer l'animal, au lieu d'élever le terme de prison pour avoir tué l'homme . Cette fois, les humains ont envoyé leur adversaire à se battre Megashark un requin de robot géant! Regarder la bande-annonce Mega Shark vs Raymond C.

L'unité rebelle avait déplacé vers le bas dans la province de Hama dans une tentative d'ouvrir un nouveau front? en partie à sortir de l'impasse à l'avant et en partie dans une tentative de saisir le ravitaillement de postes gouvernementaux. J'ai commandé une fois un gâteau bday pour mon mari d'une femme (Nancy) qui a été renvoyé par l'affiche "Avalondaughter" Le gâteau était délicieux a été fait exactement comme j'ai commandé, avaient couches très lourdes, a été faite avec des ingrédients de qualité, eu juste assez de une maison goût / qualité a été livré en temps opportun et était très raisonnable, surtout par rapport aux prix de boulangerie..

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Mais cela est venu après des mois de frénésie médiatique autour de l'affaire, largement encouragée par Sharpton. Contrairement aux émissions américaines mentionnées ci-dessus, les seize spectacles et dix-sept ans personnages semblent en fait que l'âge et n'ont pas cette qualité des étoiles de la montre de l'adolescence aux États-Unis.

Il n'y a pas vraiment beaucoup de pièces de rechange disponibles, à l'exception des phares et les pièces de pare-chocs / grill E63. Du métal de la mort artdamaged de «faute professionnelle» et «Jizzlobber" à la voix de madmanwithamegaphone sur "Crack Hitler," l'étrange Tin Pan Alley / pays hybride "RV" et l'utilisation secousses d'échantillons décalés ("plus en plus petits" dispose d'un chant autochtone), Angel Dust explose assez avec le bruit de la collision des genres.

Il ya quelques Humdingers dans cette liste, d'ailleurs, alors ne cliquez en pensant que vous avez déjà épuisé toutes les possibilités de l'argent supplémentaire. Il hd ce système d'EEB dans son camion. J'ai envoyé mon secours gênant chien Bella comme un dernier recours pour la renvoyer à la livre, à l'été 2005.

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«Chirurgie majeure» est d'avoir une double mastectomie pour tenter de sauver votre vie, comme je le faisais. Magento support multistore est ce qui attire toujours les commerçants que la gestion de plusieurs magasins d'un panneau d'administration rend la plate-forme utile pour tous les types d'entreprises.

Le [IC] 8727line mesurée dans cinq étoiles représente un Oakley Suisse carbonproblem renforcée. Confortable, propre, élégant et chaleureux. Mon bon ami m'a dit que l'Adderall générique (adderrall), elle a été donnée avant faisait ses yeux se contractent et lui donner des maux de tête de tension et des spasmes dans ses cou.

Y estaban un TAPN non solo bronzage, pero la Lesin de Okafor y los pocos minutos de Kirilenko, hicieron imposible una remontada. Bienvenue au Conseil Executive Network. Elle a refusé de permettre à jamais de lui à pleurer et il était un bébé souffrant de coliques! .

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Vous ne pouvez modifier l'un de ces subpieces, et lorsque vous modifiez celui-là, tous les autres changer dans cette même voie. Après tout, l'industrie canadienne n'a pas les moyens Sac Louis Vuitton Pas Cher de fournir notre propre avion militaire, n'est-ce pas? Cette option a été largement démembré lorsque les Avro C 102 Jetliner et FC 105 programmes Flèche ont été annulés dans les années 1950.

En 2006, 48 pour cent des personnes qui sont mortes dans la province ont été enterrés et 52 pour cent ont été incinérés, selon le ministère des affaires des consommateurs de l'Ontario, qui supervise les crématoriums de la province. Actuellement, il n'y a pas de taxes ou frais de participation et des événements réguliers seront organisés à divers endroits dans la région de New York.

L'un d'eux qui nous avons eu des problèmes auparavant. Pour fins de comparaison, je possède aussi une paire de haut-parleurs Creative SBS Vivid 80 de bureau, et un ensemble de Creative Gigaworks S750. Les exemples sont répartis dans les sciences, et sans doute si instructeurs veulent vraiment que leur discipline étudiée, ils peuvent ajouter leur propre.

En rétrospective, je n'avais jamais réalisé qu'il était "le premier moteur de recherche Web pour fournir la recherche plein texte." Je ne sais pas ce que cela veut dire, mais je suis sûr impressionné. Ce jailbreak est attaché à ce moment-dire à chaque fois que votre appareil redémarre, vous devez redémarrer avec RedSn0w sur votre ordinateur.

? 0%? . Soyez reconnaissants. Cela se traduit par 636 000 accidents entraînant des blessures graves et 12 000 décès 2600. Originaire de Phoenix Village, Milnerton et il joue au football comme un junior à Salt River FC avant de passer à Rygersdal FC.

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Familles, en particulier les jeunes, sur les nombreuses carrières passionnantes et enrichissantes dans des domaines liés à la science.. La valeur nette de Michael Kors Sac site estimée sur la base de cette valeur de la circulation et en ligne site des recettes de publicité, à lui seul $ 19 276.

Pire, le Dr Bob utilise le sophisme appelé argumentum ad temperantiam, aussi connu comme terrain d'entente, faux compromis, erreur gris et l'erreur moyenne d'or. Le« Parajumpers Homme gagnant »a été déterminée par un voter à partir de ces présents quatre Pakistanais et huit Indiens.

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Alors que la plupart d'entre nous ne reçoivent nos maux d'oreilles de la Nike Cortez Nylon route dans l'enfance, il ya des moments où les adultes obtiennent. Dans cette collection incisif et intemporel, Chroniques de la région de Man comprend les rapports d'agitation que l'homme a de connaître beaucoup mieux l'univers Marvel que le propre arbre généalogique, Woman To Get By Le Cherche Six ans de plus, les grands-parents n'ont toujours aucune idée de ce petit-fils New Balance Achat fait pour Une vie, et l'histoire classique de la persévérance, l'homme fait à travers la Journée..

'Je pense que chaque fois qu'une personne, qu'ils soient de renommée mondiale ou le plus doux et doux, prend la décision de changer leur citoyenneté, nous devons prendre du recul et de penser ce qui cause cette décision', a déclaré le maire Jo Matherne FOX411.

Ils ont écrit la lettre C dans un cercle bleu. La deuxième raison est pour une récréation ou un hobby utilisation spécifique .. S'il vous plaît envisager d'inviter un scientifique de votre programme pour parler de génétique des cultures, peut-être quelqu'un du corps scientifique de haut niveau aux États-Unis, l'AAAS (qui a publié de nombreux avenants de la sécurité des cultures OGM, y compris un récent éditorial en sciences)..

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Bien que dans de nombreux travaux de recherche, nous utilisons la méthode qualitative et quantitative. Les gens que j'ai rencontrés Timberland Femme dans Ambit sont très excités à propos de l'organisation, mais la plus grande plainte qu'ils peuvent avoir est; ce qui se passe quand ils n'ont plus de personnes à qui parler de l'entreprise? En fait, une personne ne connaît qu'un nombre limité de personnes..

Tout ce qu'il faut pour accéder à ces programmes, les films, les vidéos et d'un ordinateur avec une connexion Internet active. Mais je encerclant autour du bloc, parce que A Boy Named Sue, qui a 10 versets emballés avant et arrière avec les détenus crier San Quentin, est à la radio de la voiture et je suis tout simplement pas prêt à manquer lignes aiment :.

Drainage des eaux pauvres peut être un problème d'assainissement grave et coûteux. Il y avait une forte présence dans le Nord-Est où trop d'autres agences de presse ne comptent pas pour beaucoup.. Question numéro 5 du programme fédéral d'emploi subvention annoncée dans le budget fédéral, le Programme de subventions d'emploi a conduit à de nouvelles souches de la fédération canadienne sur une question importante du capital humain.

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Je suis aussi allé de nouveau à mon taux de rebond vs Taux de sortie blog et lié à partir de là aussi. Eu beaucoup de bâtiments qui avait l'air fatigué. Il y aura un juge en colère ainsi que l'oeuf sur le visage de certains médias lorsque le contrat initial est produit.

Je fais dormir les bébés de train et le commentaire d'être contre toutes les formations de sommeil est si stéréotypée ça me fait bouleversé. Cette fois, nous avons des raisons de croire que les meurtres ont été liés aux gangs et réalisé par des adhérents de fois l'AP et styles de Chicago, une partie de, une querelle sanglante vicieux à établir un contrôle sur les lignes directrices de grammaire et d'utilisation régissant l'anglais américain, a déclaré le porte-parole du FBI Paul Holstein , montrant aux journalistes graffitis dans lequel le mot a été corrigé de lire des choses: Un, nous sommes Chicago Manual tout le chemin, et nous Graffiti régulièrement les allées d'autres journaux avec des commentaires sarcastiques sur la virgule d'Oxford..

Les programmes d'ordinateur, des boîtes de score de jeu vidéo, cours de la Bourse, les logos de stations et les étalages de marchandise sont les nombreux coupables communs.. Elle sera alors préparez-vous à une véritable baise hardcore. Loin d'être «les BUGS bible", "Le BUGS livre" aspire à être un livre sur les méthodes bayésiennes, avec des bugs illustrations, et, dans une première approximation, s'appuie sur une sélection de BUGS "Exemples" en fournissant le contexte "théorie" .

Pour Q4, la croissance était d'environ 134,3%, à Rs 30 crore, par rapport à Rs 12,8 crore dernier exercice. Rho Ventures a investi dans environ 200 entreprises et contribué à bâtir des leaders du marché dans de nombreux secteurs à forte croissance. Pour avoir seulement le militatry américaine soit la seule force opérationnelle avec la façon dont le courage et equiptment ne serviraient à paralyser notre pays si Dieu ne plaise, ils sont nécessaires ailleurs.

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