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In [[physics]], [[astronomy]], [[chemistry]], [[biology]] and [[geography]] '''number density''' (symbol: ''n'') is an [[intensive quantity]] used to describe the degree of concentration of [[countable]] objects ([[Elementary particle|particle]]s, [[molecules]], [[phonon]]s, [[Cell (biology)|cell]]s, [[galaxy|galaxies]], etc.) in physical [[space]]: [[Three-dimensional space|three-dimensional]] volume number density, [[Two-dimensional space|two-dimensional]] area number density, or [[One-dimensional space|one-dimensional]] line number density. [[Population density]] is an example of areal number density. The term '''number concentration''' (symbol: ''C'') is sometimes used in chemistry for the same quantity, particularly when comparing with other [[concentration]]s.
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==Definition==
Volume number density is the number of specified objects per unit [[volume]]:<ref>{{GoldBookRef | file = N04260 | title = number concentration}}</ref>
: <math>n = \frac{N}{V} </math> ,
 
where
:''N'' is the total number of objects in a volume ''V''.
 
Here it is assumed<ref>{{Citation
  | author1 = Clayton T. Crowe
  | author2 = Martin Sommerfeld
  | author3 =  Yutaka Tsuji
  | title = Multiphase flows with droplets and particles: allelochemical interactions
  | year = 1998
  | page = 18
  | place =
  | publisher = [[CRC Press]]
  | url =
  | doi =
  | id =
  | isbn = 0-8493-9469-4}}</ref> that ''N'' is large enough that [[rounding]] of the count to the nearest [[integer]] does not introduce much of an [[Random error|error]], however ''V'' is chosen to be small enough that the resulting ''n'' does not depend much on the [[Volume|size]] or [[shape]] of the volume ''V''.
 
==Units==
In [[SI]] system of units, number density is measured in m<sup>&minus;3</sup>, although cm<sup>&minus;3</sup> is often used. However, these units are not quite practical when dealing with atoms or molecules of [[gas]]es, [[liquid]]s or [[solid]]s at [[room temperature]] and [[atmospheric pressure]], because the resulting numbers are extremely large (on the order of 10<sup>20</sup>). Using the number density of an [[ideal gas]] at 0&nbsp;[[Celsius|°C]] and 1&nbsp;[[Atmosphere (unit)|atm]] as a [[yardstick]]: 1&nbsp;[[amagat]]&nbsp;= [[Loschmidt constant|2.6867774×10<sup>25</sup>]]&nbsp;m<sup>&minus;3</sup> is often introduced as a unit of number density, for any substances at any conditions (not necessarily limited to an ideal gas at 0&nbsp;°C and 1&nbsp;atm).<ref>{{Citation
  | author = Joseph Kestin
  | title = A Course in Thermodynamics
  | volume = 2
  | year = 1979
  | page = 230
  | place =
  | publisher = Taylor & Francis
  | url =
  | doi =
  | id =
  | isbn = 0-89116-641-6}}</ref>
 
==Usage==
Using the number density as a [[Function (mathematics)|function]] of [[Coordinate system|spatial coordinates]], the total number of objects ''N'' in the entire volume ''V'' can be calculated as
 
: <math>N=\iiint_V n(x,y,z)\;dV </math> ,
 
where
:<math>dV=dx\,dy\,dz</math> is a volume element. If each object possesses the same [[mass]] ''m''<sub>0</sub>, the total mass ''m'' of all the objects in the volume ''V'' can be expressed as
 
: <math>m=\iiint_V m_0\, n(x,y,z)\;dV </math> .
 
Similar expressions are valid for [[electric charge]] or any other [[extensive quantity]] associated with countable objects. For example, replacing <math>m\rightarrow q</math> (total charge) and <math>m_0\rightarrow q_0</math> (charge of each object) in the above equation will lead to a correct expression for charge.  
 
The number density of [[solution|solute]] molecules in a [[solvent]] is sometimes called [[concentration]], although usually concentration is expressed as a number of [[Mole (unit)|moles]] per unit volume (and thus called [[molar concentration]]).
 
==Relation to other quantities==
===Molar concentration===
For any substance, the '''number density''' ''n'' (in units of m<sup>&minus;3</sup>) can be expressed in terms of its [[molar concentration]] ''c'' (in units of [[Mole (unit)|mole]]/m<sup>3</sup>) as:
 
:<math>n=N_{\rm A}\,c</math> ,
where ''N''<sub>A</sub> is the [[Avogadro constant]] ≈ 6.022×10<sup>23</sup>&nbsp;mol<sup>&minus;1</sup>. This is still true if the [[spatial dimension]] unit, metre, in both ''n'' and ''c'' is consistently replaced by any other spatial dimension unit, e.g. if ''n'' is in units of cm<sup>&minus;3</sup> and ''c'' is in units of [[Mole (unit)|mole]]/cm<sup>3</sup>, or if ''n'' is in units of [[Litre|L]]<sup>&minus;1</sup> and ''c'' is in units of [[Mole (unit)|mole]]/[[Litre|L]], etc.
 
===Mass density===
For [[atom]]s or [[molecule]]s of a well-defined [[molecular mass]] ''M'' (in units of [[Kilogram|kg]]/[[Mole (unit)|mole]]), the '''number density''' can be expressed in terms of the mass [[density]] of a substance ''ρ'' (in units of kg/m<sup>3</sup>) as
 
:<math>n=\frac{N_{\rm A}}{M}\rho</math> .
Note that the ratio ''M''/''N''<sub>A</sub> is the mass of a single atom or molecule in units of [[Kilogram|kg]].
 
==Examples==
The following table lists common examples of number densities at 1&nbsp;[[atmosphere (unit)|atm]] and 20&nbsp;[[Celsius|°C]], unless otherwise noted.
 
{| class="wikitable" align="center" style="text-align:center"
|+ Molecular<ref name=mol>For [[Chemical element|elemental]] substances, atomic densities/concentrations are used</ref> number density and related parameters of some materials
! Material  !!colspan="2" | Number density (''n'') !! [[Molar concentration]] (''c'') !![[Density]] (<math>\rho</math>) !! [[Molar mass]] (''M'')
|-
|align="right" | [[Units of measurement|Units]] ||align="center" |(10<sup>27</sup> m<sup>&minus;3</sup>) or<br>(10<sup>21</sup> cm<sup>&minus;3</sup>)||align="center" |([[amagat]])||align="center" |(10<sup>3</sup> [[Mole (unit)|mol]]/m<sup>3</sup>) or ([[Mole (unit)|mol]]/[[Litre|L]])||(10<sup>3</sup> kg/m<sup>3</sup>) or ([[gram|g]]/[[cubic centimeter|cm<sup>3</sup>]])||(10<sup>&minus;3</sup> kg/[[Mole (unit)|mol]]) or ([[gram|g]]/[[Mole (unit)|mol]])
|-
|align="left"| [[ideal gas]] ||0.02504||0.932||0.04158||41.58×10<sup>&minus;6</sup>×''M''||''M''
|-
|align="left"| [[Density of air|dry air]] ||0.02504||0.932||0.04158||1.2041×10<sup>&minus;3</sup>||28.9644
|-
|align="left"| [[Water (data page)|water]] ||33.3679||1241.93||55.4086||0.99820||18.01524
|-
|align="left"| [[Carbon|diamond]] ||176.2||6556||292.5||3.513||12.01
|}
 
==See also==
* [[Columnar number density]]
 
==References and notes==
{{Reflist}}
 
[[Category:Density]]
[[Category:Physical quantities]]
 
[[lv:Koncentrācija#Fizikā lietots jēdziens]]

Revision as of 16:51, 8 February 2014

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