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This page provides supplementary chemical data on [[toluene]].
 
==MSDS sheets==
* [http://hazard.com/msds/mf/baker/baker/files/t3913.htm Baker]
 
==Structure and properties==
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Structure and properties
|-
| [[Index of refraction]], ''n''<sub>D</sub>
| 1.4969 at 20°C <!-- Please omit if not applicable -->
|-
| [[Abbe number]]
|? <!-- Please omit if not applicable -->
|-
| [[Dielectric constant]], ε<sub>r</sub>
| 2.379 ε<sub>0</sub> at 25°C
|-
| [[Bond strength]]
| ? <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond length]]
| ? <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond angle]]
| ? <!-- Specify which angle, e.g. Cl-P-O. Please omit if not applicable -->
|-
| [[Magnetic susceptibility]]
| ? <!-- Please omit if not applicable -->
|-
| [[Surface tension]]
| 28.52 dyn/cm at 25°C
|-
| [[Viscosity]]<ref name="cheric_p">{{Cite web|url=http://www.cheric.org/research/kdb/hcprop/cmpsrch.php|title=Pure Component Database|publisher=Chemical Engineering Research Information Center|format=Queriable database|accessdate=12 May 2007}}</ref>
|
{|
|-
| 1.1813 mPa·s || at –25°C
|-
| 1.0787 mPa·s || at –20°C
|-
| 0.9888 mPa·s || at –15°C
|-
| 0.9095 mPa·s || at –10°C
|-
| 0.8393 mPa·s || at –5°C
|-
| 0.7770 mPa·s || at 0°C
|-
| 0.7214 mPa·s || at 5°C
|-
| 0.6717 mPa·s || at 10°C
|-
| 0.6270 mPa·s || at 15°C
|-
| 0.5867 mPa·s || at 20°C
|-
| 0.5503 mPa·s || at 25°C
|-
| 0.5173 mPa·s || at 30°C
|-
| 0.4873 mPa·s || at 35°C
|-
| 0.4599 mPa·s || at 40°C
|-
| 0.4349 mPa·s || at 45°C
|-
| 0.4120 mPa·s || at 50°C
|-
|}
|-
|}
 
== Thermodynamic properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Phase behavior
|-
| [[Triple point]]
| 178.15 K (&minus;94.99 °C), ? Pa
|-
| [[Critical point (thermodynamics)|Critical point]]
| 591.79 K (318.64 °C), 4.109 MPa
|-
| [[Standard enthalpy change of fusion|Std enthalpy change<br/>of fusion]]Δ<sub>fus</sub>''H''<sup><s>o</s></sup>
| 6.636 kJ/mol
|-
| [[Standard entropy change of fusion|Std entropy change<br/>of fusion]]Δ<sub>fus</sub>''S''<sup><s>o</s></sup>
| 37.25 J/(mol·K)
|-
| [[Standard enthalpy change of vaporization|Std enthalpy change<br/>of vaporization]]Δ<sub>vap</sub>''H''<sup><s>o</s></sup>
| 38.06 kJ/mol
|-
| [[Standard entropy change of vaporization|Std entropy change<br/>of vaporization]]Δ<sub>vap</sub>''S''<sup><s>o</s></sup>
| 87.30 J/(mol·K)
|-
! {{chembox header}} | Solid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]] Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>solid</sub>
| ? kJ/mol
|-
| [[Standard molar entropy]]<br/>''S''<sup><s>o</s></sup><sub>solid</sub>
| ? J/(mol K)
|-
| [[Heat capacity]] ''c<sub>p</sub> <sub>liquid</sub>''
| 181,2 J/(mol K)
|-
| [[Heat capacity]] ''c<sub>p</sub> <sub>gas</sub>''
| 103,6 J/(mol K)
|-
! {{chembox header}} | Liquid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]] Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>liquid</sub>
| +12.0 kJ/mol
|-
| [[Standard molar entropy]]<br/>''S''<sup><s>o</s></sup><sub>liquid</sub>
| 220.96 J/(mol K)
|-
| [[Heat capacity]] ''c<sub>p</sub>''
| 155.96 J/(mol K)
|-
! {{chembox header}} | Gas properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]] Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>gas</sub>
| +50.00 kJ/mol
|-
| [[Standard molar entropy]]<br/>''S''<sup><s>o</s></sup><sub>gas</sub>
| ? J/(mol K)
|-
| [[Heat capacity]] ''c<sub>p</sub>''
| 103.7 J/(mol K)
|-
| [[van der Waals equation|van der Waals' constants]]<ref name="lange1522">''Lange's Handbook of Chemistry'' 10th ed, pp 1522-1524</ref>
| a = 2438 L<sup>2</sup> kPa/mol<sup>2</sup><br> b = 0.1463 liter per mole
|-
|}
 
==Vapor pressure of liquid==
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| {{chembox header}} | '''P in mm Hg''' || 1 || 10 || 40 || 100 || 400 || 760 || 1520 || 3800 || 7600 || 15200 || 30400 || 45600
|-
| {{chembox header}} | '''T in °C''' || -25 || 6.4 || 31.8 || 51.9 || 89.5 || 110.6 || 136.5 || 178.0 || 215.8 || 262.5 || 319.0 || &nbsp;—
|}
Table data obtained from ''CRC Handbook of Chemistry and Physics'' 44th ed.
 
[[Image:logTolueneVaporPressure.png|thumb|860px|left|'''log<sub>10</sub> of Toluene vapor pressure.''' Uses formula: <math>\scriptstyle \log_{10} P_{mmHg} = 6.95464 - \frac {1344.8} {T+219.482}</math> obtained from ''Lange's Handbook of Chemistry'', 10th ed.]]{{Clear}}
 
==Spectral data==
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-color: #C0C090;"
 
! width="85%" align="center" cellspacing="3" style="font-size:95%; border: 1px solid #C0C090; background-color: #F8EABA; margin-bottom: 3px;" colspan="2" | [[UV/VIS spectroscopy|UV-Vis]]
|-
| Spectrum
| [http://webbook.nist.gov/cgi/cbook.cgi?ID=C108883&Units=SI&Mask=400#UV-Vis-Spec NIST]
|-
| [[Lambda-max]]
| 253, 259, 261, 268[[Nanometre|nm]]
|-
| Log [[molar absorptivity|Ε]]
| 2.36, 2.42, 2.43, 2.27
|-
! {{Chembox header}} colspan="2" | [[Infrared|IR]]
|-
| Spectrum
| [http://webbook.nist.gov/cgi/cbook.cgi?ID=C108883&Units=SI&Type=IR-SPEC&Index=2#IR-SPEC NIST]
|-
| Major absorption bands
| 3028, 1605, 1496, 729, 696 cm<sup>&minus;1</sup>
|-
! {{Chembox header}} colspan="2" | [[NMR Spectroscopy|NMR]]
|-
| [[Proton NMR]]
| (CDCl<sub>3</sub>, 300 MHz) δ 7.17-7.11 (m, 2H), 7.08-7.01 (m, 3H), 2.32 (s, 3H)
|-
| [[Carbon-13 NMR]] <!-- Link to image of spectrum -->
| (CDCl<sub>3</sub>, 100 MHz) δ 137.7, 128.7, 127.9, 125.0, 20.8
|-
| Other NMR data <!-- Insert special data e.g. <sup>19</sup>F chem. shifts, omit if not used -->
| ?
|-
! width="85%" align="center" cellspacing="3" style="font-size:95%; border: 1px solid #C0C090; background-color: #F8EABA; margin-bottom: 3px;" colspan="2" | [[Mass Spectrometry|MS]]
|-
| Masses of <br>main fragments
| ? <!-- Give list of major fragments -->
|-
| {{Chembox header}} colspan="2" | <small>Except where noted otherwise, data are given for<br>[[standard ambient temperature and pressure|standard ambient temperature and pressure (25°C, 101.3 kPa)]]<br/>[[wikipedia:Chemical infobox|Disclaimer and references]]</small>
|}
 
==References==
<references/>
[http://webbook.nist.gov/cgi/cbook.cgi?Name=toluene&Units=SI NIST website]
 
Except where noted otherwise, data relate to [[standard ambient temperature and pressure]].
 
[[wikipedia:Chemical infobox|Disclaimer]] applies.
 
{{Use dmy dates|date=September 2010}}
 
{{DEFAULTSORT:Toluene (Data Page)}}
[[Category:Chemical data pages]]

Revision as of 20:35, 23 September 2013

This page provides supplementary chemical data on toluene.

MSDS sheets

Structure and properties

Structure and properties
Index of refraction, nD 1.4969 at 20°C
Abbe number ?
Dielectric constant, εr 2.379 ε0 at 25°C
Bond strength ?
Bond length ?
Bond angle ?
Magnetic susceptibility ?
Surface tension 28.52 dyn/cm at 25°C
Viscosity[1]
1.1813 mPa·s at –25°C
1.0787 mPa·s at –20°C
0.9888 mPa·s at –15°C
0.9095 mPa·s at –10°C
0.8393 mPa·s at –5°C
0.7770 mPa·s at 0°C
0.7214 mPa·s at 5°C
0.6717 mPa·s at 10°C
0.6270 mPa·s at 15°C
0.5867 mPa·s at 20°C
0.5503 mPa·s at 25°C
0.5173 mPa·s at 30°C
0.4873 mPa·s at 35°C
0.4599 mPa·s at 40°C
0.4349 mPa·s at 45°C
0.4120 mPa·s at 50°C

Thermodynamic properties

Phase behavior
Triple point 178.15 K (−94.99 °C), ? Pa
Critical point 591.79 K (318.64 °C), 4.109 MPa
Std enthalpy change
of fusion
ΔfusHo
6.636 kJ/mol
Std entropy change
of fusion
ΔfusSo
37.25 J/(mol·K)
Std enthalpy change
of vaporization
ΔvapHo
38.06 kJ/mol
Std entropy change
of vaporization
ΔvapSo
87.30 J/(mol·K)
Solid properties
Std enthalpy change
of formation
ΔfHosolid
? kJ/mol
Standard molar entropy
Sosolid
? J/(mol K)
Heat capacity cp liquid 181,2 J/(mol K)
Heat capacity cp gas 103,6 J/(mol K)
Liquid properties
Std enthalpy change
of formation
ΔfHoliquid
+12.0 kJ/mol
Standard molar entropy
Soliquid
220.96 J/(mol K)
Heat capacity cp 155.96 J/(mol K)
Gas properties
Std enthalpy change
of formation
ΔfHogas
+50.00 kJ/mol
Standard molar entropy
Sogas
? J/(mol K)
Heat capacity cp 103.7 J/(mol K)
van der Waals' constants[2] a = 2438 L2 kPa/mol2
b = 0.1463 liter per mole

Vapor pressure of liquid

P in mm Hg 1 10 40 100 400 760 1520 3800 7600 15200 30400 45600
T in °C -25 6.4 31.8 51.9 89.5 110.6 136.5 178.0 215.8 262.5 319.0  —

Table data obtained from CRC Handbook of Chemistry and Physics 44th ed.

log10 of Toluene vapor pressure. Uses formula: obtained from Lange's Handbook of Chemistry, 10th ed.

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Spectral data

UV-Vis
Spectrum NIST
Lambda-max 253, 259, 261, 268nm
Log Ε 2.36, 2.42, 2.43, 2.27
IR
Spectrum NIST
Major absorption bands 3028, 1605, 1496, 729, 696 cm−1
NMR
Proton NMR (CDCl3, 300 MHz) δ 7.17-7.11 (m, 2H), 7.08-7.01 (m, 3H), 2.32 (s, 3H)
Carbon-13 NMR (CDCl3, 100 MHz) δ 137.7, 128.7, 127.9, 125.0, 20.8
Other NMR data ?
MS
Masses of
main fragments
?
Except where noted otherwise, data are given for
standard ambient temperature and pressure (25°C, 101.3 kPa)
Disclaimer and references

References

  1. Template:Cite web
  2. Lange's Handbook of Chemistry 10th ed, pp 1522-1524

NIST website

Except where noted otherwise, data relate to standard ambient temperature and pressure.

Disclaimer applies.

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