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In [[condensed matter physics]], '''biexcitons''' are created from two free [[excitons]].
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== Formation of biexcitons ==
In quantum information and computation, it is essential to construct coherent combinations of quantum states.
The basic quantum operations can be performed on a sequence of pairs of physically distinguishable quantum bits and, therefore, can be illustrated by a simple four-level system.
 
In an optically driven system where the <math>| 0 1 \rangle</math> and <math>| 1 0 \rangle</math> states can be directly excited, direct excitation of the upper <math>| 1 1 \rangle</math> level from the ground state <math>| 0 0 \rangle</math> is usually forbidden and the most efficient alternative is coherent nondegenerate two-photon excitation, using <math>| 0 1 \rangle</math> or <math>| 1 0 \rangle</math> as an intermediate state.
<ref>G. Chen et al, "Biexciton Quantum Coherence in a Single Quantum Dot", ''Phys. Rev. Lett.'', '''88''' (11), 117901 (2002)</ref>
<ref>Xiaoqin Li et al, "An All-Optical Quantum Gate in a Semiconductor Quantum Dot", ''Science'', '''301''', 809 (2003)</ref>
 
[[Image:Biexciton levels.gif|thumb|Model for a single [[quantum dots]]. <math>E_b</math> is the biexciton binding energy]]
 
== Observation of biexcitons ==
Three possibilities of observing biexcitons exist:
<ref>G. Vektrais, "A new approach to the molecular biexciton theory", ''J. Chem. Phys.'', '''101''' (4), 3031 (1994)</ref>
 
(a) excitation from the one-[[exciton]] band to the biexciton band (pump-probe experiments);
 
(b) two-photon absorption of light from the ground state to the biexciton state;
 
(c) [[luminescence]] from a biexciton state made up from two free [[excitons]] in a dense [[exciton]] system.
 
== Binding energy of biexcitons ==
The biexciton is a [[quasi-particle]] formed from two [[excitons]], and its energy is expressed as
 
:<math>E_{b} = 2 E_{X} - E_{XX}</math>
 
where <math>E_{XX}</math> is the biexciton energy, <math>E_{X}</math> is the [[exciton]] energy, and
 
:<math>E_{b}</math> is the biexciton binding energy.
 
When a biexciton is annihilated, it disintegrates into a free [[exciton]] and a photon. The energy of the photon is smaller than that of the biexciton by the biexciton binding energy,
so the biexciton [[luminescence]] peak appears on the low-energy side of the [[exciton]] peak.
 
The biexciton binding energy in semiconductor [[quantum dots]] has been the subject of extensive theoretical study. Because a biexciton is a composite of two electrons and two holes, we must solve a four-body problem under spatially restricted conditions. The biexciton binding energies for CuCl [[quantum dots]], as measured by the site selective [[luminescence]] method, increased with decreasing [[quantum dot]] size. The data were well fitted by the function
 
:<math>B_{XX} = \frac{c_1}{a^2} + \frac{c_2}{a} + B_{bulk}</math>
 
where <math>B_{XX}</math> is biexciton binding energy, <math>a</math> is the radius of the [[quantum dots]], <math>B_{bulk}</math> is the binding energy of bulk crystal, and <math>c_1</math> and <math>c_2</math> are fitting parameters.
<ref>S. Park et al, "Fabrication of CuCl Quantum Dots and the Size Dependence of the Biexciton Binding Energy", ''Journal of the Korean Physical Society'', '''37''' (3), 309-312 (2000)</ref>
 
=== A simple model for describing binding energy of biexcitons ===
In the effective-mass approximation, the [[Hamiltonian (quantum mechanics)|Hamiltonian]] of the system consisting of two electrons (1, 2) and two holes (a, b) is given by
 
:<math>H_{XX} = - \frac{\hbar^2}{2 m_e^*} ({\nabla_1}^2 + {\nabla_2}^2) - \frac{\hbar^2}{2 m_h^*} ({\nabla_a}^2 + {\nabla_b}^2) + V</math>
 
where <math>m_e^*</math> and <math>m_h^*</math> are the effective masses of electrons and holes, respectively, and
 
:<math>V = V_{12} - V_{1a} - V_{1b} - V_{2a} - V_{2b} + V_{ab}</math>
 
where <math>V_{ij}</math> denotes the [[Coulomb interaction]] between the charged particles <math>i</math> and <math>j</math> (<math>i, j = 1, 2, a, b</math> denote the two electrons and two holes in the biexciton) given by
 
:<math>V_{ij} = \frac{e^2}{\epsilon |\mathbf{r}_i - \mathbf{r}_j|}</math>
 
where <math>\epsilon</math> is the dielectric constant of the material.
 
Denoting <math>\mathbf{R}</math> and <math>\mathbf{r}</math> are the c.m. coordinate and the relative coordinate of the biexciton, respectively, and <math>M = m_e^* + m_h^*</math> is the [[Effective mass (solid-state physics)|effective mass]] of the [[exciton]], the Hamiltonian becomes
 
:<math>H_{XX} = - \frac{\hbar^2}{4 M} {\nabla_R}^2 - \frac{\hbar^2}{M} {\nabla_r}^2 - \frac{\hbar^2}{2 \mu} ({\nabla_{1a}}^2 + {\nabla_{2b}}^2) + V</math>
 
where <math>1/\mu = 1/{m_e^*} + 1/{m_h^*}</math>; <math>{\nabla_{1a}}^2</math> and <math>{\nabla_{2b}}^2</math> are the Laplacians with respect to relative coordinates between electron and hole, respectively.
And <math>{\nabla_r}^2</math> is that with respect to relative coordinate between the c. m. of [[excitons]], and <math>{\nabla_R}^2</math> is that with respect to the c. m. coordinate <math>\mathbf{R}</math> of the system.
 
In the units of the [[exciton]] Rydberg and [[Bohr radius]], the Hamiltonian can be written in dimensionless form
 
:<math>H_{XX} = - ({\nabla_{1a}}^2 + {\nabla_{2b}}^2) - {2 \sigma}{(1 + \sigma)^2} {\nabla_r}^2 + V </math>
 
where <math>\sigma = {m_e^*}/{m_h^*}</math> with neglecting kinetic energy operator of c. m. motion. And <math>V</math> can be written as
 
:<math>V = 2 (\frac{1}{r_{12}} - \frac{1}{r_{1a}} - \frac{1}{r_{1b}} - \frac{1}{r_{2a}} - \frac{1}{r_{2b}} + \frac{1}{r_{ab}})</math>
 
To solve the problem of the bound states of the biexciton complex, it is required to find the wave functions <math>\psi</math> satisfying the wave equation
 
:<math>H_{XX} \psi = E_{XX} \psi</math>
 
If the eigenvalue <math>E_{XX}</math> can be obtained, the binding energy of the biexciton can be also acquired
 
:<math>E_{b} = 2 E_{X} - E_{XX}</math>
 
where <math>E_{b}</math> is the binding energy of the biexciton and <math>E_{X}</math> is the energy of [[exciton]].
<ref>J. Liu et al, "Binding Energy of biexcitons in Two-Dimensional Semiconductors", ''Chin. Phys. Lett.'', '''15''' (8), 588 (1998)</ref>
 
=== Binding energy in nanotubes ===
Biexcitons with bound complexes formed by two [[excitons]] are predicted to be surprisingly stable for [[carbon nanotube]] in a wide diameter range.
Thus, a biexciton binding energy exceeding the inhomogeneous [[exciton]] line width is predicted for a wide range of nanotubes.
 
The biexciton binding energy in carbon nanotube is quite accurately approximated by an inverse dependence on <math>r</math>, except perhaps for the smallest values of <math>r</math>.
 
:<math>E_{XX} \approx \frac{0.195 eV}{r}</math>
 
The actual biexciton binding energy is inversely proportional to the physical nanotube radius.
<ref>T. G. Perdersen et al, "Stability and Signatures of biexcitons in Carbon nanotubes", ''Nanolett.'', '''5''' (2), 291 (2005)</ref>
Experimental evidence of biexcitons has yet to be found.
 
=== Binding energy in CuCl QDs ===
The binding energy of biexcitons increase with the decrease in their size and its size dependence and bulk value are well represented by the expression
 
:<math>\frac{78}{{a^*}^2} + \frac{52}{{a^*}} + 33</math> (meV)
 
where <math>a^*</math> is the effective radius of microcrystallites in a unit of nm. The enhanced [[Coulomb interaction]] in microcrystallites still increase the biexciton binding energy in the large-size regime, where the quantum confinement energy of [[excitons]] is not considerable.
<ref>Y. Masumoto et al, "Biexciton binding energy in CuCl quantum dots", ''Phys. Rev. B'', '''50''' (24), 18658 (1994)</ref>
 
== References ==
{{reflist|2}}
 
[[Category:Condensed matter physics]]
[[Category:Spintronics]]
[[Category:Quasiparticles]]

Latest revision as of 06:45, 8 May 2014

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