Sugeno integral: Difference between revisions

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| ImageFile =  
| ImageSize =
| SystematicName = Silver(I) cyanate
| OtherNames =
| Section1 = {{Chembox Identifiers
|  CASNo = 3315-16-0
|  CASNo_Ref = {{cascite|correct|}}
|  PubChem = 76827
|  ChemSpiderID = 69282
|  SMILES = [Ag+].[O-]C#N
| InChI = 1/CHNO.Ag/c2-1-3;/h3H;/q;+1/p-1
|  InChIKey = DWBPIWPCOSHWCK-REWHXWOFAQ
| StdInChI = 1S/CHNO.Ag/c2-1-3;/h3H;/q;+1/p-1
|  StdInChIKey = DWBPIWPCOSHWCK-UHFFFAOYSA-M
  }}
| Section2 = {{Chembox Properties
| Formula = AgOCN
|  MolarMass = 149.885 g/mol
|  Appearance =  
|  Density =
|  MeltingPt =
|  BoilingPt =
|  Solubility =
  }}
| Section3 = {{Chembox Hazards
|  MainHazards =
|  FlashPt =
|  Autoignition =
  }}
}}
 
'''Silver cyanate''' is a [[chemical compound]] and the [[cyanate]] [[salt]] of [[silver]].
 
It can be prepared by reaction of [[potassium cyanate]] or [[urea]] with [[silver nitrate]].<ref name="buch">{{Literatur | Autor = Willy Kühne | Titel = Lehrbuch der physiologischen Chemie | Verlag = | ISBN = | Jahr = 1868 | Online = {{Google Buch | BuchID = q8U9AAAAYAAJ | Linktext = Seite 470 | Seite = 470 }} }}</ref>
 
:<math>\mathrm{AgNO_3 + KOCN \longrightarrow AgOCN \downarrow +\ KNO_3}</math>
:<math>\mathrm{AgNO_3 + H_2N\text{-}C(O)\text{-}NH_2 \longrightarrow}</math> <math>\mathrm{AgOCN \downarrow +\ NH_4NO_3}</math>
 
Silver cyanate is a beige to gray powder. It crystallises in the [[monoclinic crystal system]] in [[space group]]  ''P''2<sub>1</sub>/''m'' with parameters  a&nbsp;=&nbsp;547.3&nbsp;[[Picometer|pm]], b&nbsp;=&nbsp;637.2&nbsp;pm, c&nbsp;=&nbsp;341.6&nbsp;pm und β&nbsp;=&nbsp;91°.<ref>[http://scripts.iucr.org/cgi-bin/paper?a04540 D. Britton, J. D. Dunitz: ''The crystal structure of silver cyanate''], Acta Cryst. (1965). 18, 424-428, {{DOI|10.1107/S0365110X65000944}}</ref>
 
With [[nitric acid]] silver cyanate reacts to form [[carbon dioxide]] and [[ammonium nitrate]].<ref name="Milbauer">J. Milbauer: ''Bestimmung und Trennung der Cyanate, Cyanide, Rhodanide und Sulfide'' in [[Fresenius' Journal of Analytical Chemistry]] 42 (1903) 77-95, {{DOI|10.1007/BF01302741}}.</ref>
 
:<math>\mathrm{AgOCN + 2HNO_3 + H_2O \longrightarrow}</math>
:<math>\mathrm{AgNO_3 + CO_2 \uparrow +\ NH_4NO_3}</math>
 
== See also ==
* [[Justus Von Liebig]]
* [[Friedrich Woehler]]
* [[Silver fulminate]]
* [[Isomerism]]
 
==References==
{{Reflist}}
 
[[Category:Silver compounds]]
[[Category:Cyanates]]

Latest revision as of 11:13, 4 January 2015

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