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| [[File:QuantumHarmonicOscillatorAnimation.gif|thumb|300px|right|Some trajectories of a [[harmonic oscillator]] according to [[Newton's laws]] of [[classical mechanics]] (A-B), and according to the [[Schrödinger equation]] of [[quantum mechanics]] (C-H). In (A-B), the particle (represented as a ball attached to a [[Hooke's law|spring]]) oscillates back and forth. In (C-H), some solutions to the Schrödinger Equation are shown, where the horizontal axis is position, and the vertical axis is the real part (blue) or imaginary part (red) of the [[wavefunction]]. (C,D,E,F), but not (G,H), are [[energy eigenstate]]s. (H) is a [[coherent state]], a quantum state which approximates the classical trajectory.]]
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| The '''quantum harmonic oscillator''' is the [[quantum mechanics|quantum-mechanical]] analog of the [[harmonic oscillator|classical harmonic oscillator]]. Because an arbitrary [[Potential energy|potential]] can usually be approximated as a [[Harmonic oscillator#Simple harmonic oscillator|harmonic potential]] at the vicinity of a stable [[equilibrium point]], it is one of the most important model systems in quantum mechanics. Furthermore, it is one of the few quantum-mechanical systems for which an exact, [[analytical solution]] is known.<ref>
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| {{Cite book| author=[[David Griffiths (physicist)|Griffiths, David J.]] | title=Introduction to Quantum Mechanics |edition=2nd | publisher=Prentice Hall |year=2004 |isbn=0-13-805326-X}}</ref><ref>{{Cite book| author=[[Liboff, Richard L.]] | title=Introductory Quantum Mechanics | publisher=Addison-Wesley | year=2002 | isbn=0-8053-8714-5}}</ref><ref>{{Cite web
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| | last =Rashid
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| | first =Muneer A.
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| | authorlink =Munir Ahmad Rashid
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| | coauthors =
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| | title =Transition amplitude for time-dependent linear harmonic oscillator with Linear time-dependent terms added to the Hamiltonian
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| | work =M.A. Rashid - [[National University of Sciences and Technology, Pakistan|Center for Advanced Mathematics and Physics]]
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| | publisher =[[National Center for Physics]]
| |
| | year =2006
| |
| | url =http://www.ncp.edu.pk/docs/12th_rgdocs/Munir-Rasheed.pdf
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| | format =[[PDF]]-[[Microsoft PowerPoint]]
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| | doi =
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| | accessdate =2010 }}</ref>
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| ==One-dimensional harmonic oscillator==
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| ===Hamiltonian and energy eigenstates===
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| [[Image:HarmOsziFunktionen.png|thumb|Wavefunction representations for the first eight bound eigenstates, ''n'' = 0 to 7. The horizontal axis shows the position ''x''. Note: The graphs are not normalized, and the signs of some of the functions differ from those given in the text.]]
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| [[Image:Aufenthaltswahrscheinlichkeit harmonischer Oszillator.png|thumb|Corresponding probability densities.]]
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| The [[Hamiltonian (quantum mechanics)|Hamiltonian]] of the particle is:
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| :<math>\hat H = \frac{{\hat p}^2}{2m} + \frac{1}{2} m \omega^2 {\hat x}^2 \, ,</math>
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| | |
| where ''m'' is the particle's mass, ω is the [[angular frequency]] of the oscillator, ''<math>\hat x = x</math>'' is the [[position operator]], and ''<math>\hat p</math>'' is the [[momentum operator]], given by
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| :<math>\hat p = - i \hbar {\partial \over \partial x} \, .</math>
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| The first term in the Hamiltonian represents the possible kinetic energy states of the particle, and the second term represents its respectively corresponding possible potential energy states.
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| One may write the time-independent [[Schrödinger equation]],
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| :<math> \hat H \left| \psi \right\rangle = E \left| \psi \right\rangle \, ,</math>
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| | |
| where {{mvar|E}} denotes a yet-to-be-determined real number that will specify a time-independent [[energy level]], or eigenvalue, and the solution |''ψ''⟩ denotes that level's energy [[eigenstate]].
| |
| | |
| One may solve the differential equation representing this eigenvalue problem in the coordinate basis, for the [[wave function]] ⟨''x''|''ψ''⟩ = ''ψ(x)'', using a [[spectral method]]. It turns out that there is a family of solutions. In this basis, they amount to
| |
| :<math> \psi_n(x) = \frac{1}{\sqrt{2^n\,n!}} \cdot \left(\frac{m\omega}{\pi \hbar}\right)^{1/4} \cdot e^{
| |
| - \frac{m\omega x^2}{2 \hbar}} \cdot H_n\left(\sqrt{\frac{m\omega}{\hbar}} x \right), \qquad n = 0,1,2,\ldots. </math> | |
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| The functions ''H<sub>n</sub>'' are the [[Hermite polynomials]],
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| :<math>H_n(x)=(-1)^n e^{x^2}\frac{d^n}{dx^n}\left(e^{-x^2}\right)</math> .
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| The corresponding energy levels are
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| :<math> E_n = \hbar \omega \left(n + {1\over 2}\right)</math> .
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| This energy spectrum is noteworthy for three reasons. First, the energies are quantized, meaning that only discrete energy values (integer-plus-half multiples of {{math|''ħω''}}) are possible; this is a general feature of quantum-mechanical systems when a particle is confined. Second, these discrete energy levels are equally spaced, unlike in the [[Bohr model]] of the atom, or the [[particle in a box]]. Third, the lowest achievable energy (the energy of the {{math|''n'' {{=}} 0}} state, called the [[ground state]]) is not equal to the minimum of the potential well, but {{math|''ħω''/2}} above it; this is called [[zero-point energy]]. Because of the zero-point energy, the position and momentum of the oscillator in the ground state are not fixed (as they would be in a classical oscillator), but have a small range of variance, in accordance with the [[Heisenberg uncertainty principle]]. The zero-point energy also has important implications in [[quantum field theory]] and [[quantum gravity]].
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| Note that the ground state probability density is concentrated at the origin. This means the particle spends most of its time at the bottom of the potential well, as we would expect for a state with little energy. As the energy increases, the probability density becomes concentrated at the classical "turning points", where the state's energy coincides with the potential energy. This is consistent with the classical harmonic oscillator, in which the particle spends most of its time (and is therefore most likely to be found) at the turning points, where it is the slowest. The [[correspondence principle]] is thus satisfied.
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| ===Ladder operator method===
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| [[Image:QHarmonicOscillator.png|right|thumb|Probability densities <nowiki>|</nowiki>''ψ<sub>n</sub>''(''x'')<nowiki>|</nowiki><sup>2</sup> <!--or in pseudoTeX: <math>\left |\psi_n(x)\right |^2</math> --> for the bound eigenstates, beginning with the ground state (''n'' = 0) at the bottom and increasing in energy toward the top. The horizontal axis shows the position ''x'', and brighter colors represent higher probability densities.]]
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| The [[spectral method]] solution, though straightforward, is rather tedious. The "[[ladder operator]]" method, developed by [[Paul Dirac]], allows us to extract the energy eigenvalues without directly solving the differential equation. Furthermore, it is readily generalizable to more complicated problems, notably in [[quantum field theory]]. Following this approach, we define the operators {{mvar|a}} and its [[Hermitian adjoint|adjoint]] {{math|''a''<sup>†</sup>}},
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| :<math>\begin{align}
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| a &=\sqrt{m\omega \over 2\hbar} \left(\hat x + {i \over m \omega} \hat p \right) \\
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| a^{\dagger} &=\sqrt{m \omega \over 2\hbar} \left(\hat x - {i \over m \omega} \hat p \right)
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| \end{align}</math>
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| This leads to the useful representation of <math>\hat x</math> and <math>\hat p</math>,
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| :<math>\hat x = \sqrt{\frac{\hbar}{2m\omega}}(a+a^{\dagger})</math>
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| :<math>\hat p = i\sqrt{\frac{m \omega\hbar}{2}}(a^{\dagger}-a) ~.</math>
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| The operator {{mvar|a}} is not [[Hermitian operator|Hermitian]], since itself and its adjoint {{math|''a''<sup>†</sup>}} are not equal. Yet the energy eigenstates |''n''⟩, when operated on by these ladder operators, give
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| :<math>a^\dagger|n\rangle = \sqrt{n+1}\,|n+1\rangle</math>
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| :<math>a|n\rangle = \sqrt{n}\,|n-1\rangle</math> .
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| It is then evident that {{math|''a''<sup>†</sup>}}, in essence, appends a single quantum of energy to the oscillator, while {{mvar|a}} removes a quantum. For this reason, they are sometimes referred to as "creation" and "annihilation" operators.
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| From the relations above, we can also define a number operator {{mvar|N}}, which has the following property:
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| :<math> N = a^{\dagger}a</math>
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| :<math> N\left| n \right\rangle =n\left| n \right\rangle</math> .
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| The following [[commutator]]s can be easily obtained by substituting the [[canonical commutation relation]],
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| :<math>[a,a^{\dagger}]=1,\qquad[N,a^{\dagger}]=a^{\dagger},\qquad[N,a]=-a, </math>
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| And the Hamilton operator can be expressed as
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| :<math>H=\left(N+\frac{1}{2}\right)\hbar\omega,</math>
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| so the eigenstate of {{mvar|N}} is also the eigenstate of energy.
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| The commutation property yields
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| :<math>\begin{align}
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| Na^{\dagger}|n\rangle&=\left(a^{\dagger}N+[N,a^{\dagger}]\right)|n\rangle\\&=\left(a^{\dagger}N+a^{\dagger}\right)|n\rangle\\&=(n+1)a^{\dagger}|n\rangle,
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| \end{align} </math>
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| and similarly,
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| :<math>Na|n\rangle=(n-1)a|n\rangle.</math>
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| This means that {{mvar|a}} acts on |''n''⟩ to produce, up to a multiplicative constant, |''n''–1⟩, and {{math|''a''<sup>†</sup>}} acts on |''n''⟩ to produce |''n''+1⟩. For this reason, {{mvar|a}} is called a "lowering operator", and {{math|''a''<sup>†</sup>}} a "raising operator". The two operators together are called [[ladder operator]]s. In quantum field theory, {{mvar|a}} and {{math|''a''<sup>†</sup>}} are alternatively called "annihilation" and "creation" operators because they destroy and create particles, which correspond to our quanta of energy.
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| Given any energy eigenstate, we can act on it with the lowering operator, {{mvar|a}}, to produce another eigenstate with {{math|''ħω''}} less energy. By repeated application of the lowering operator, it seems that we can produce energy eigenstates down to {{math|''E'' {{=}} −∞}}. However, since
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| :<math>n=\langle n|N|n\rangle=\langle n|a^{\dagger}a|n\rangle=\left(a|n\rangle\right)^{\dagger}a|n\rangle\geqslant 0,</math>
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| the smallest eigen-number is 0, and
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| :<math>a \left| 0 \right\rangle = 0 </math>.
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| In this case, subsequent applications of the lowering operator will just produce zero kets, instead of additional energy eigenstates. Furthermore, we have shown above that
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| :<math>H \left|0\right\rangle = \frac{\hbar\omega}{2} \left|0\right\rangle</math>
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| Finally, by acting on |0⟩ with the raising operator and multiplying by suitable normalization factors, we can produce an infinite set of energy eigenstates
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| :<math>\left\{\left| 0 \right \rangle, \left| 1 \right \rangle, \left| 2 \right \rangle, ... , \left| n \right \rangle, ...\right\}</math>,
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| such that
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| :<math> H \left|n\right\rangle = \hbar\omega \left(n +\frac{1}{2} \right) \left|n\right\rangle </math> ,
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| which matches the energy spectrum given in the preceding section.
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| Arbitrary eigenstates can be expressed in terms of |0⟩,
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| :<math>|n\rangle=\frac{\left(a^{\dagger}\right)^{n}}{\sqrt{n!}}|0\rangle </math> .
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| :Proof:
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| ::<math>\begin{align}
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| \langle n|aa^{\dagger}|n\rangle&=\langle n|\left([a,a^{\dagger}]+a^{\dagger}a\right)|n\rangle=\langle n|\left(N+1\right)|n\rangle=n+1\\\Rightarrow a^{\dagger}|n\rangle&=\sqrt{n+1}|n+1\rangle\\\Rightarrow|n\rangle&=\frac{a^{\dagger}}{\sqrt{n}}|n-1\rangle=\frac{\left(a^{\dagger}\right)^{2}}{\sqrt{n(n-1)}}|n-2\rangle=\cdots=\frac{\left(a^{\dagger}\right)^{n}}{\sqrt{n!}}|0\rangle.
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| \end{align}</math>
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| The ground state |0⟩ in the position representation is determined by ''a'' |0⟩ = 0,
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| :<math>
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| \begin{align}
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| &\left\langle x\left|a \right| 0 \right\rangle = 0~~~~~~~~~~\Longrightarrow\\
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| &\left(x + \frac{\hbar}{m\omega}\frac{d}{dx}\right)\left\langle x|0\right\rangle = 0~~~~~~\Longrightarrow\\
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| &\left\langle x|0\right\rangle = \left(\frac{m\omega}{\pi\hbar}\right)^{\frac{1}{4}}\exp\left(-\frac{m\omega}{2\hbar}x^{2}\right)=\psi_0 ~,
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| \end{align}
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| </math>
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| and hence
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| ::<math> \langle x| a^{\dagger} |0\rangle =\psi_1 ~,</math>
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| and so on, as in the previous section.
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| ===Natural length and energy scales===
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| The quantum harmonic oscillator possesses natural scales for length and energy, which can be used to simplify the problem. These can be found by [[nondimensionalization#Quantum harmonic oscillator|nondimensionalization]]. The result is that, if we measure energy in units of {{math|''ħω''}} and distance in units of {{math|{{sqrt|''ħ''/(''mω'')}}}}, then the Schrödinger equation becomes
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| :<math> H = - {1\over2} {d^2 \over dx^2 } + {1 \over 2} x^2 ,</math>
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| while the energy eigenfunctions and eigenvalues become
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| :<math>\psi_n(x)\equiv \left\langle x | n \right\rangle = {1 \over \sqrt{2^n n!}} \pi^{-1/4} \hbox{exp} (-x^2 / 2) H_n(x),</math>
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| :<math>E_n = n + \tfrac{1}{2},</math>
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| where {{math|''H''<sub>''n''</sub>(''x'')}} are the [[Hermite polynomials]].
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| To avoid confusion, we will not adopt these "natural units" in this article. However, they frequently come in handy when performing calculations, by bypassing clutter.
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| ===Phase space solutions===
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| In the [[phase space formulation]] of quantum mechanics, solutions to the quantum harmonic oscillator in [[quasiprobability distribution#Fock state|several different representations]] of the [[quasiprobability distribution]] can be written in closed form. The most widely used of these is for the [[Wigner function]], which has the solution
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| :<math>F_n(u) = \frac{(-1)^n}{\pi \hbar} L_n\left(4\frac{u}{\hbar \omega}\right) e^{-2u/\hbar \omega} ~,</math>
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| where
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| :<math>u=\frac{1}{2} m \omega^2 x^2 + \frac{p^2}{2m}</math>
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| and ''L<sub>n</sub>'' are the [[Laguerre polynomials]]. This example shows how the Hermite polynomials and Laguerre polynomials are interrelated through the [[Wigner–Weyl transform]].
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| ==''N''-dimensional harmonic oscillator==
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| The one-dimensional harmonic oscillator is readily generalizable to ''N'' dimensions, where ''N'' = 1, 2, 3, ... . In one dimension, the position of the particle was specified by a single [[coordinate system|coordinate]], ''x''. In ''N'' dimensions, this is replaced by ''N'' position coordinates, which we label ''x''<sub>1</sub>, ..., ''x''<sub>''N''</sub>. Corresponding to each position coordinate is a momentum; we label these ''p''<sub>1</sub>, ..., ''p''<sub>''N''</sub>. The [[canonical commutation relations]] between these operators are
| |
| | |
| :<math>\begin{matrix}
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| \left[x_i , p_j \right] &=& i\hbar\delta_{i,j} \\
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| \left[x_i , x_j \right] &=& 0 \\
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| \left[p_i , p_j \right] &=& 0
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| \end{matrix}</math>.
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| The Hamiltonian for this system is
| |
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| :<math> H = \sum_{i=1}^N \left( {p_i^2 \over 2m} + {1\over 2} m \omega^2 x_i^2 \right)</math>.
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| As the form of this Hamiltonian makes clear, the ''N''-dimensional harmonic oscillator is exactly analogous to ''N'' independent one-dimensional harmonic oscillators with the same mass and spring constant. In this case, the quantities ''x''<sub>1</sub>, ..., ''x''<sub>''N''</sub> would refer to the positions of each of the ''N'' particles. This is a convenient property of the <math>r^2</math> potential, which allows the potential energy to be separated into terms depending on one coordinate each.
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| This observation makes the solution straightforward. For a particular set of quantum numbers {''n''} the energy eigenfunctions for the ''N''-dimensional oscillator are expressed in terms of the 1-dimensional eigenfunctions as:
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| :<math>
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| \langle \mathbf{x}|\psi_{\{n\}}\rangle
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| =\prod_{i=1}^N\langle x_i|\psi_{n_i}\rangle
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| </math>
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| In the ladder operator method, we define ''N'' sets of ladder operators,
| |
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| :<math>\begin{matrix}
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| a_i &=& \sqrt{m\omega \over 2\hbar} \left(x_i + {i \over m \omega} p_i \right) \\
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| a^{\dagger}_i &=& \sqrt{m \omega \over 2\hbar} \left( x_i - {i \over m \omega} p_i \right)
| |
| \end{matrix}</math>.
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| By a procedure analogous to the one-dimensional case, we can then show that each of the ''a''<sub>''i''</sub> and ''a''<sup>†</sup><sub>''i''</sub> operators lower and raise the energy by ℏω respectively. The Hamiltonian is
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| :<math>
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| H = \hbar \omega \, \sum_{i=1}^N \left(a_i^\dagger \,a_i + \frac{1}{2}\right).
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| </math>
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| This Hamiltonian is invariant under the dynamic symmetry group ''U(N)'' (the unitary group in ''N'' dimensions), defined by
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| :<math>
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| U\, a_i^\dagger \,U^\dagger = \sum_{j=1}^N a_j^\dagger\,U_{ji}\quad\hbox{for all}\quad
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| U \in U(N),
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| </math>
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| where <math>U_{ji}</math> is an element in the defining matrix representation of ''U(N)''.
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| The energy levels of the system are
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| | |
| :<math> E = \hbar \omega \left[(n_1 + \cdots + n_N) + {N\over 2}\right]</math>.
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| :<math>
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| n_i = 0, 1, 2, \dots \quad (\hbox{the energy level in dimension } i).
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| </math>
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| As in the one-dimensional case, the energy is quantized. The ground state energy is ''N'' times the one-dimensional energy, as we would expect using the analogy to ''N'' independent one-dimensional oscillators. There is one further difference: in the one-dimensional case, each energy level corresponds to a unique quantum state. In ''N''-dimensions, except for the ground state, the energy levels are ''degenerate'', meaning there are several states with the same energy.
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| The degeneracy can be calculated relatively easily. As an example, consider the 3-dimensional case: Define ''n'' = ''n''<sub>1</sub> + ''n''<sub>2</sub> + ''n''<sub>3</sub>. All states with the same ''n'' will have the same energy. For a given ''n'', we choose a particular ''n''<sub>1</sub>. Then ''n''<sub>2</sub> + ''n''<sub>3</sub> = ''n'' − ''n''<sub>1</sub>. There are ''n'' − ''n''<sub>1</sub> + 1 possible groups {''n''<sub>2</sub>, ''n''<sub>3</sub>}. ''n''<sub>2</sub> can take on the values 0 to ''n'' − ''n''<sub>1</sub>, and for each ''n''<sub>2</sub> the value of ''n''<sub>3</sub> is fixed. The degree of degeneracy therefore is:
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| | |
| :<math>
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| g_n = \sum_{n_1=0}^n n - n_1 + 1 = \frac{(n+1)(n+2)}{2}
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| </math>
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| Formula for general ''N'' and ''n'' [''g''<sub>n</sub> being the dimension of the symmetric irreducible ''n''<sup>th</sup> power representation of the unitary group ''U(N)'']:
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| :<math>
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| g_n = \binom{N+n-1}{n}
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| </math>
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| The special case ''N = 3'', given above, follows directly from this general equation. This is however, only true for distinguishable particle, or one particle in N dimensions (as dimensions are distinguishable). For the case of ''N'' bosons in a one dimension harmonic trap, the degeneracy scales as the number of ways to partition an integer ''n'' using integers less than or equal to ''N''.
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| :<math>
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| g_n = p(N_{-},n)
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| </math>
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| This arises due to the constraint of putting ''N'' quanta into a state ket where <math>\sum_{k=0}^\infty k n_k = n </math> and <math> \sum_{k=0}^\infty n_k = N </math>, which are the same constraints as in integer partition.
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| ===Example: 3D isotropic harmonic oscillator===
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| The Schrödinger equation of a spherically-symmetric three-dimensional harmonic oscillator can be solved explicitly by separation of variables, see [[Particle in a spherically symmetric potential#3D isotropic harmonic oscillator|this article]] for the present case. This procedure is analogous to the separation performed in the [[Hydrogen-like atom#Schrödinger equation in a spherically symmetric potential|hydrogen-like atom]] problem, but with the [[Particle in a spherically symmetric potential|spherically symmetric potential]]
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| :<math>V(r) = {1\over 2} \mu \omega^2 r^2,</math>
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| where <math>\mu</math> is the mass of the problem. (Because ''m'' will be used below for the magnetic quantum number, mass is indicated by <math>\mu</math>, instead of ''m'', as earlier in this article.)
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| The solution reads
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| :<math>\psi_{klm}(r,\theta,\phi) = N_{kl} r^{l}e^{-\nu r^2}{L_k}^{(l+{1\over 2})}(2\nu r^2) Y_{lm}(\theta,\phi)</math>
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| where
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| :<math>N_{kl}=\sqrt{\sqrt{\frac{2\nu ^{3}}{\pi }}\frac{2^{k+2l+3}\;k!\;\nu ^{l}}{
| |
| (2k+2l+1)!!}}\,</math> is a normalization constant.
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| :<math>\nu \equiv {\mu \omega \over 2 \hbar}</math>
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| :<math>{L_k}^{(l+{1\over 2})}(2\nu r^2)</math>
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| are [[Laguerre polynomials#Generalized Laguerre polynomials|generalized Laguerre polynomials]]. The order ''k'' of the polynomial is a non-negative integer.
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| :<math>Y_{lm}(\theta,\phi)\,</math> is a [[spherical harmonics|spherical harmonic function]].
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| :<math>\hbar</math> is the reduced [[Planck constant]]: <math>\hbar\equiv\frac{h}{2\pi}</math>.
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| The energy eigenvalue is
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| :<math>E=\hbar \omega \left(2k+l+\frac{3}{2}\right) ~.</math>
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| The energy is usually described by the single [[quantum number]]
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| :<math>n\equiv 2k+l ~.</math>
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| Because ''k'' is a non-negative integer, for every even ''n'' we have <math>l=0,2...,n-2,n</math> and for every odd ''n'' we have <math>l=1,3...,n-2,n</math>. The magnetic quantum number ''m'' is an integer satisfying <math>-l \le m \le l</math>, so for every ''n'' and ''l'' there are ''2l+1'' different [[quantum state]]s, labeled by ''m''. Thus, the degeneracy at level ''n'' is
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| :<math>\sum_{l=\ldots,n-2,n} (2l+1) = {(n+1)(n+2)\over 2} ~,</math>
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| where the sum starts from 0 or 1, according to whether ''n'' is even or odd.
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| This result is in accordance with the dimension formula above, and amounts to the dimensionality of a symmetric representation of ''SU(3)'', the relevant degeneracy group.
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| | |
| ==Harmonic oscillators lattice: phonons==
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| | |
| We can extend the notion of harmonic oscillator to a one lattice of many particles. Consider a one-dimensional quantum mechanical [[harmonic chain]] of ''N'' identical atoms. This is the simplest quantum mechanical model of a lattice, and we will see how [[phonon]]s arise from it. The formalism that we will develop for this model is readily generalizable to two and three dimensions.
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| As in the previous section, we denote the positions of the masses by <math>x_1,x_2,...</math>, as measured from their equilibrium positions (i.e. <math>x_i=0</math> if the particle {{mvar| i}} is at its equilibrium position.) In two or more dimensions, the <math>x_i</math> are vector quantities. The [[Hamiltonian (quantum mechanics)|Hamiltonian]] for this system is
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| :<math>\mathbf{H} = \sum_{i=1}^N {p_i^2 \over 2m} + {1\over 2} m \omega^2 \sum_{\{ij\} (nn)} (x_i - x_j)^2\ </math>
| |
| | |
| where {{mvar|m}} is the mass of each atom (assuming is equal for all), and <math>\, x_i</math> and <math>\, p_i</math> are the position and [[momentum]] operators for the ''i''th atom and the sum is made over the nearest neighbors (nn). However, as one expect, in a lattice could also appear waves that could behave as particles. For the treatment of [[waves]], is custom to treat with the [[fourier space]] which uses [[normal modes]] of the [[wavevector]] as variables instead coordinates of particles. The number of normal modes are the same to the particles however the [[fourier space]] are very useful given the [[Fourier series|periodicity]] of the system.
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| | |
| We introduce, then, a set of {{mvar|N}} "normal coordinates" <math>\, Q_k</math>, defined as the [[discrete Fourier transform]]s of the {{mvar|x}}s, and {{mvar|N}} "conjugate momenta" {{mvar|Π}} defined as the Fourier transforms of the {{mvar|p}}s:
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| :<math>
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| Q_k = {1\over\sqrt{N}} \sum_{l} e^{ikal} x_l</math>
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| :<math>
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| \Pi_{k} = {1\over\sqrt{N}} \sum_{l} e^{-ikal} p_l.
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| </math>
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| The quantity <math>\, k_n</math> will turn out to be the [[Wavenumber|wave number]] of the phonon, i.e. 2π divided by the [[wavelength]]. It takes on quantized values, because the number of atoms is finite.
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| This choice retains the desired commutation relations in either real space or wave vector space
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| | |
| : <math> \begin{align}
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| \left[x_l , p_m \right]&=i\hbar\delta_{l,m} \\
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| \left[ Q_k , \Pi_{k'} \right] &={1\over N} \sum_{l,m} e^{ikal} e^{-ik'am} [x_l , p_m ] \\
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| &= {i \hbar\over N} \sum_{m} e^{iam\left(k-k'\right)} = i\hbar\delta_{k,k'} \\
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| \left[ Q_k , Q_{k'} \right] &= \left[ \Pi_k , \Pi_{k'} \right] = 0
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| \end{align}</math>
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| From the general result
| |
| | |
| : <math> \begin{align}
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| \sum_{l}x_l x_{l+m}&={1\over N}\sum_{kk'}Q_k Q_{k'}\sum_{l} e^{ial\left(k+k'\right)}e^{iamk'}= \sum_{k}Q_k Q_{-k}e^{iamk} \\
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| \sum_{l}{p_l}^2 &= \sum_{k}\Pi_k \Pi_{-k} .
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| \end{align}</math>
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| | |
| It is easy to show that the potential energy term is
| |
| : <math>
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| {1\over 2} m \omega^2 \sum_{j} (x_j - x_{j+1})^2= {1\over 2}\omega^2\sum_{k}Q_k Q_{-k}(2-e^{ika}-e^{-ika})= {1\over 2} \sum_{k}{\omega_k}^2Q_k Q_{-k} ,</math>
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| where
| |
| | |
| :<math>\omega_k = \sqrt{2 \omega^2 (1 - \cos(ka))}.\ </math>
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| | |
| The Hamiltonian may be written in wave vector space as
| |
| :<math>\mathbf{H} = {1\over {2m}}\sum_k \left(
| |
| { \Pi_k\Pi_{-k} } + m^2 \omega_k^2 Q_k Q_{-k} .
| |
| \right)</math>
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| | |
| Note that the couplings between the position variables have been transformed away; if the {{mvar|Q}}s and {{mvar| Π}}s were [[Hermitian operator|hermitian]](which they are not), the transformed Hamiltonian would describe {{mvar|N}} ''uncoupled'' harmonic oscillators.
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| | |
| The form of the quantization depends on the choice of boundary conditions; for simplicity, we impose ''periodic'' boundary conditions, defining the {{math|(''N''+1)}}th atom as equivalent to the first atom. Physically, this corresponds to joining the chain at its ends. The resulting quantization is
| |
| | |
| :<math>k=k_n = {2n\pi \over Na}
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| \quad \hbox{for}\ n = 0, \pm1, \pm2, ... , \pm {N \over 2}.\ </math>
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| | |
| The upper bound to {{mvar|n}} comes from the minimum wavelength, which is twice the lattice spacing {{mvar|a}}, as discussed above.
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| | |
| The harmonic oscillator eigenvalues or energy levels for the mode <math>\omega_k</math> are :
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| | |
| ::<math>E_n = \left({1\over2}+n\right)\hbar\omega_k \quad\quad\quad n=0,1,2,3 ......</math>
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| | |
| If we ignore the [[zero-point energy|zero-point]] energy then the levels are evenly spaced at :
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|
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| ::{{math|''ħω'', 2''ħω'', 3''ħω'', ... }}
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| So an '''exact''' amount of [[energy]] {{math| ''ħω''}}, must be supplied to the harmonic oscillator lattice to push it to the next energy level. In comparison to the [[photon]] case when the [[electromagnetic field]] is quantised, the quantum of vibrational energy is called a [[phonon]].
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| All quantum systems show wave-like and particle-like properties. The particle-like properties of the phonon are best understood using the methods of [[second quantization]] and operator techniques described later.<ref name="Mahan">{{cite book|last=Mahan|first=GD|authorlink=|title=many particle physics|publisher= springer|location=New York|isbn=0306463385|year=1981}}</ref>
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| ==Applications==
| |
| | |
| * The vibrations of a [[diatomic molecule]] are an example of a two-body version of the quantum harmonic oscillator. In this case, the angular frequency is given by
| |
| :<math>\omega = \sqrt{\frac{k}{\mu}} </math>
| |
| where <math>\mu</math> is the [[reduced mass]] and is determined by the mass of the two atoms.<ref>{{Cite web|title=Quantum Harmonic Oscillator|work=Hyperphysics|accessdate=24 September 2009|url=http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/hosc.html}}</ref>
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| * [[Hooke's atom]] is a simple model of the [[helium]] atom using the quantum harmonic oscillator
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| * Modelling phonons, as discussed above
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| * Charge, q, with mass, m, in a uniform magnetic field, B, is an example of a one-dimensional quantum harmonic oscillator. <ref name="Landau and Lifshitz">{{cite book|title=Quantum mechanics non-relativistic theory|year=1977|publisher=Butterworth Heinemann|location=Amsterdam|isbn=9780080503486 0080503489|page=455|url=http://site.ebrary.com/id/10685767}}</ref>
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| ==See also==
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| {{Div col}}
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| *[[Quantum machine]]
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| *[[Gas in a harmonic trap]]
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| *[[Creation and annihilation operators]]
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| *[[Coherent state]]
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| *[[Morse potential]]
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| *[[Bertrand's theorem]]
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| *[[Molecular vibration#Quantum mechanics|Molecular vibration]]
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| {{Div col end}}
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| ==References==
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| {{Reflist}}
| |
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| ==External links==
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| *[http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/hosc.html Quantum Harmonic Oscillator]
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| *Calculation using a [[noncommutative]] [[free monoid]]: [http://www.schmarsow.net/oscillate.pdf (mathematical version)] / [http://www.schmarsow.net/oscillateSmall.pdf (abbreviated version)]
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| *[http://behindtheguesses.blogspot.com/2009/03/quantum-harmonic-oscillator-ladder.html Rationale for choosing the ladder operators]
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| *[http://www.brummerblogs.com/curvature/3d-harmonic-oscillator-eigenfunctions/ Live 3D intensity plots of quantum harmonic oscillator]
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| *[https://noppa.oulu.fi/noppa/kurssi/763693s/materiaali/763693S_monqo.pdf Driven and damped quantum harmonic oscillator (lecture notes of course "quantum optics in electric circuits")]
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| {{Use dmy dates|date=September 2010}}
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| {{DEFAULTSORT:Quantum Harmonic Oscillator}}
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| [[Category:Quantum models]]
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