D-fuconate dehydratase: Difference between revisions

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{{enzyme
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| Name = (-)-endo-fenchol synthase
| EC_number = 4.2.3.10
| CAS_number = 117758-41-5
| IUBMB_EC_number = 4/2/3/10
| GO_code = 0050437
| image =
| width =
| caption =
}}
In [[enzymology]], a '''(-)-endo-fenchol synthase''' ({{EC number|4.2.3.10}}) is an [[enzyme]] that [[catalysis|catalyzes]] the [[chemical reaction]]
 
:geranyl diphosphate + H<sub>2</sub>O <math>\rightleftharpoons</math> (-)-endo-fenchol + diphosphate
 
Thus, the two [[substrate (biochemistry)|substrates]] of this enzyme are [[geranyl diphosphate]] and [[water|H<sub>2</sub>O]], whereas its two [[product (chemistry)|products]] are [[(-)-endo-fenchol]] and [[diphosphate]].
 
This enzyme belongs to the family of [[lyase]]s, specifically those carbon-oxygen lyases acting on phosphates.  The systematic name of this enzyme class is '''geranyl-diphosphate diphosphate-lyase [cyclizing, (-)-endo-fenchol-forming]'''. Other names in common use include '''(-)-endo-fenchol cyclase''', and '''geranyl pyrophosphate:(-)-endo-fenchol cyclase'''.  This enzyme participates in [[monoterpenoid]] [[biosynthesis]]. 
 
==References==
{{reflist|1}}
* {{cite journal | author = Croteau R, Miyazaki JH, Wheeler CJ | date = 1989 | title = Monoterpene biosynthesis: mechanistic evaluation of the geranyl pyrophosphate:(-)-endo-fenchol cyclase from fennel (Foeniculum vulgare) | journal = Arch. Biochem. Biophys.  | volume = 269 | pages = 507&ndash;16  | pmid = 2919880 | doi = 10.1016/0003-9861(89)90134-3 | issue = 2 }}
* {{cite journal | author = Croteau R, Satterwhite DM, Wheeler CJ, Felton NM | date = 1988 | title = Biosynthesis of monoterpenes. Stereochemistry of the enzymatic cyclization of geranyl pyrophosphate to (-)-endo-fenchol | journal = J. Biol. Chem.  | volume = 263 | pages = 15449&ndash;53  | pmid = 3170591 | issue = 30 }}
 
 
{{4.2-enzyme-stub}}
 
[[Category:EC 4.2.3]]
[[Category:Enzymes of unknown structure]]

Latest revision as of 06:34, 17 May 2014

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