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The '''quantum pendulum''' is fundamental in understanding hindered internal rotations in chemistry, quantum features of scattering atoms as well as numerous other quantum phenomena.  Though a pendulum not subject to the small-angle approximation has an inherent non-linearity, the [[Schrödinger]] equation for the quantized system can be solved relatively easily.


==Schrödinger Equation==


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Using Lagrangian theory from classical mechanics, one can develop a Hamiltonian for the system.  A simple pendulum has one generalized coordinate (the angular displacement <math> \phi </math>) and two constraints (the length of the string is constant and there is no motion along the z axis). The kinetic energy and potential energy of the system can be found to be as follows:


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:<math>T=\frac{1}{2} m l^2 \dot{\phi}^2 </math>
:<math>U=m g l (1-\cos(\phi)) </math>


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This results in the Hamiltonian:
:<math>\hat{H} = \frac{\hat{p}^2}{2 m l^2} + m g l (1-\cos(\phi))</math>


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The time-dependent [[Schrödinger]] equation for the system is as follows:


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:<math>i \hbar \frac{d\Psi}{dt} = - \frac{\hbar^2}{2 m l^2} \frac {\mathrm{d}^2 \Psi} {\mathrm{d} \phi^2}+m g l (1-\cos(\phi)) \Psi </math>


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One must solve the time-independent [[Schrödinger]] equation to find the energy levels and corresponding eigenstates. This is best accomplished by changing the independent variable as follows:
:<math>\eta = \phi + \pi </math>
:<math>E \psi = - \frac{\hbar^2}{2 m l^2} \frac {\mathrm{d}^2 \psi} {\mathrm{d} \eta^2}+m g l (1+\cos(\eta)) \psi </math>


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This is simply Mathieu's equation where the solutions are [[Mathieu functions]]
 
:<math>0 = \frac {\mathrm{d}^2 \psi} {\mathrm{d} \eta^2}+(\frac{2 m E^2} {\hbar^2}-\frac{2 m^2 g l^3} {\hbar^2}-\frac{2 m^2 g l^3} {\hbar^2} \cos(\eta)) \psi </math>
 
==Solutions==
 
===Energies===
Given <math>q</math>, for countably many special values of <math>a</math>, called ''characteristic values'', the Mathieu equation admits solutions which are periodic with period <math>2\pi</math>. The characteristic values of the Mathieu cosine, sine functions respectively are written <math>a_n(q), \, b_n(q)</math>, where n is a [[natural number]].  The periodic special cases of the Mathieu cosine and sine functions are often written <math>CE(n,q,x), \, SE(n,q,x)</math> respectively, although they are traditionally given a different normalization (namely, that their L<sup>2</sup> norm equal <math>\pi</math>). 
 
The boundary conditions in the quantum pendulum imply that <math>a_n(q), \, b_n(q)</math> are as follows for a given q:
 
:<math>0 = \frac {\mathrm{d}^2 \psi} {\mathrm{d} \eta^2}+(\frac{2 m E l^2} {\hbar^2}-\frac{2 m^2 g l^3} {\hbar^2}-\frac{2 m^2 g l^3} {\hbar^2} \cos(\eta)) \psi </math>
 
:<math>a_n(q), \, b_n(q)=\frac{2 m E l^2} {\hbar^2}-\frac{2 m^2 g l^3} {\hbar^2} </math>
 
The energies of the system, <math>E=m g l+\frac{\hbar^2 a_n(q), \, b_n(q)}{2 m l^2}</math> for even/odd solutions respectively, are quantized based on the characteristic values found by solving the [[Mathieu equation]]
 
The effective potential depth can be defined as follows:
 
<math>q=\frac{m^2 g l^3} {\hbar^2} </math>
 
A depth potential depth yields the dynamics of a particle in an independent potential. In contrast, a shallow potential depth, [[Bloch waves]] as well as [[quantum tunneling]] become of importance.
 
===General Solution===
The general solution of the above differential equation for a given value of a and q is a set of linearly independent Mathieu cosines and Mathieu sines, which are even and odd solutions respectively.  In general, the Mathieu functions are aperiodic; however, for characteristic values of <math> a_n(q), \, b_n(q) </math>, the Mathieu cosine and sine become periodic with a period of <math> 2 \pi </math>.
 
===Eigenstates===
 
For positive values of q, the following is true:
:<math>C \left( a_n(q),q,x \right) = \frac{CE(n,q,x)}{CE(n,q,0)}</math>
:<math>S \left( b_n(q),q,x \right) = \frac{SE(n,q,x)}{SE^\prime(n,q,0)}.</math>
Here are the first few periodic Mathieu cosine functions for q=1:
[[Image:MathieuCE.gif|center]]
Note that, for example, <math>CE(1,1,x)</math> (green) resembles a cosine function, but with flatter hills and shallower valleys.
 
== Bibliography ==
*{{cite book | last1=Bransden | first1=B. H. | last2 = Joachain | first2 = C. J. | title = Quantum mechanics | edition = 2nd | publisher = Pearson Education|location=Essex| year = 2000|isbn=0-582-35691-1}}
*{{cite book | last=Davies|first= John H.|title=The Physics of Low-Dimensional Semiconductors: An Introduction | publisher=Cambridge University Press|year=2006|isbn=0-521-48491-X|edition=6th reprint}}
*{{cite book | last=Griffiths|first= David J.|title=Introduction to Quantum Mechanics |edition=2nd | publisher=Prentice Hall |year=2004 |isbn=0-13-111892-7}}
*Muhammad Ayub, ''Atom Optics Quantum Pendulum'', 2011, Islamabad, Pakistan., http://lanl.arxiv.org/PS_cache/arxiv/pdf/1012/1012.6011v1.pdf
 
==External links==
* [http://lanl.arxiv.org/PS_cache/arxiv/pdf/1012/1012.6011v1.pdf Atom Optics Quantum Pendulum]
 
{{DEFAULTSORT:Quantum Pendulum}}
[[Category:Quantum mechanics]]
[[Category:Quantum models]]

Revision as of 01:20, 25 July 2013

The quantum pendulum is fundamental in understanding hindered internal rotations in chemistry, quantum features of scattering atoms as well as numerous other quantum phenomena. Though a pendulum not subject to the small-angle approximation has an inherent non-linearity, the Schrödinger equation for the quantized system can be solved relatively easily.

Schrödinger Equation

Using Lagrangian theory from classical mechanics, one can develop a Hamiltonian for the system. A simple pendulum has one generalized coordinate (the angular displacement ϕ) and two constraints (the length of the string is constant and there is no motion along the z axis). The kinetic energy and potential energy of the system can be found to be as follows:

T=12ml2ϕ˙2
U=mgl(1cos(ϕ))

This results in the Hamiltonian:

H^=p^22ml2+mgl(1cos(ϕ))

The time-dependent Schrödinger equation for the system is as follows:

idΨdt=22ml2d2Ψdϕ2+mgl(1cos(ϕ))Ψ

One must solve the time-independent Schrödinger equation to find the energy levels and corresponding eigenstates. This is best accomplished by changing the independent variable as follows:

η=ϕ+π
Eψ=22ml2d2ψdη2+mgl(1+cos(η))ψ

This is simply Mathieu's equation where the solutions are Mathieu functions

0=d2ψdη2+(2mE222m2gl322m2gl32cos(η))ψ

Solutions

Energies

Given q, for countably many special values of a, called characteristic values, the Mathieu equation admits solutions which are periodic with period 2π. The characteristic values of the Mathieu cosine, sine functions respectively are written an(q),bn(q), where n is a natural number. The periodic special cases of the Mathieu cosine and sine functions are often written CE(n,q,x),SE(n,q,x) respectively, although they are traditionally given a different normalization (namely, that their L2 norm equal π).

The boundary conditions in the quantum pendulum imply that an(q),bn(q) are as follows for a given q:

0=d2ψdη2+(2mEl222m2gl322m2gl32cos(η))ψ
an(q),bn(q)=2mEl222m2gl32

The energies of the system, E=mgl+2an(q),bn(q)2ml2 for even/odd solutions respectively, are quantized based on the characteristic values found by solving the Mathieu equation

The effective potential depth can be defined as follows:

q=m2gl32

A depth potential depth yields the dynamics of a particle in an independent potential. In contrast, a shallow potential depth, Bloch waves as well as quantum tunneling become of importance.

General Solution

The general solution of the above differential equation for a given value of a and q is a set of linearly independent Mathieu cosines and Mathieu sines, which are even and odd solutions respectively. In general, the Mathieu functions are aperiodic; however, for characteristic values of an(q),bn(q), the Mathieu cosine and sine become periodic with a period of 2π.

Eigenstates

For positive values of q, the following is true:

C(an(q),q,x)=CE(n,q,x)CE(n,q,0)
S(bn(q),q,x)=SE(n,q,x)SE(n,q,0).

Here are the first few periodic Mathieu cosine functions for q=1:

File:MathieuCE.gif

Note that, for example, CE(1,1,x) (green) resembles a cosine function, but with flatter hills and shallower valleys.

Bibliography

External links