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== Nike Air Max Trainers UK W8eeiwkf ==
{{chembox
| Watchedfields = changed
| verifiedrevid = 431911872
|  Name = Ammonium hydrosulfide
|  ImageFileL1 = Ammonium-2D.svg
|  ImageFileR1 = Hydrogen sulfide ion.svg
|  IUPACName = ammonium hydrosulfide
|  OtherNames = ammonium bisulfide<br />ammonium hydrogen sulfide
| Section1 = {{Chembox Identifiers
|  ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 23805
| InChI = 1/H3N.H2S/h1H3;1H2
| InChIKey = HIVLDXAAFGCOFU-UHFFFAOYAU
| SMILES = [SH-].[NH4+]
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/H3N.H2S/h1H3;1H2
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = HIVLDXAAFGCOFU-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 12124-99-1
| RTECS = BS4900000
  }}
| Section2 = {{Chembox Properties
|  Formula = H<sub>5</sub>NS
|  MolarMass = 51.111 g/mol
|  Appearance = Yellow-orange fuming liquid.
|  Density = 1.17 g/cm<sup>3</sup><ref>Pradyot Patnaik. ''Handbook of Inorganic Chemicals''. McGraw-Hill, 2002, ISBN 0-07-049439-8</ref>
|  Solubility = Miscible in all proportions
|  SolubleOther = soluble in [[alcohol]], liquid [[ammonia]], liquid [[hydrogen sulfide]]; insoluble in [[benzene]], [[hexane]] and [[ether]]
|  MeltingPt =
|  BoilingPtC = 56.6
|  pKb =
|  RefractIndex = 1.74
  }}
| Section7 = {{Chembox Hazards
|  ExternalMSDS =
|  MainHazards = Toxic
|  NFPA-H = 3
|  NFPA-F = 3
|  NFPA-R =
|  FlashPt =
|  RPhrases = {{R11}}, {{R23}}, {{R24}}, {{R25}}.
|  SPhrases =
|  LD50 = 168 mg/kg (rat, oral)<ref name=GESTIS>{{GESTIS | CAS = 12124-99-1 | ZVG = 492163 | Name = ammonium hydrosulfide | Date = October 22, 2010}}</ref>
  }}
| Section8 = {{Chembox Related
|  OtherAnions = [[Ammonium sulfate]]
|  OtherCations = [[Sodium hydrosulfide]]
  }}
}}


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'''Ammonium hydrosulfide''' is the [[chemical compound]] with the [[Chemical formula|formula]] (NH<sub>4</sub>)SH. It is the [[salt]] derived from the [[ammonium]] [[cation]] and the [[hydrosulfide]] [[anion]]. The salt exists as colourless, water soluble, [[mica]]ceous crystals. The compound is encountered mainly as a solution, not as the solid. It is generated by mixing [[hydrogen sulfide]] and [[ammonia]].


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==Preparation==
Solutions of ammonium hydrosulfide can be prepared by passing [[hydrogen sulfide]] gas through concentrated [[ammonia]] solution.<ref>{{cite journal | author = Goodman, J. T.; Rauchfuss, T. B., | title = Tetraethylammonium-tetrathioperrhenate [Et<sub>4</sub>N][ReS<sub>4</sub>] | journal = [[Inorganic Syntheses]] | year = 2002 | volume = 33 | pages = 107–110}}</ref> According to a detailed 1895 report, hydrogen sulfide reacts with concentrated aqueous ammonia solution at room temperature to give (NH<sub>4</sub>)<sub>2</sub>S·2NH<sub>4</sub>HS. When this species is cooled to 0&nbsp;°C and treated with additional hydrogen sulfide, one obtains (NH<sub>4</sub>)<sub>2</sub>S·12NH<sub>4</sub>HS.<ref>{{cite journal | author = W. P. Bloxam | title = The Sulphides and Polysulphides of Ammonium | journal = [[J. Chem. Soc., Trans.]] | year = 1895 | volume = 67 | pages = 283 | doi = 10.1039/CT8956700277}}</ref> An ice-cold solution of this substance kept at 0&nbsp;°C and having hydrogen sulfide continually passed through it gives the hydrosulfide.


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The common "[[stink bomb]]" consists of an aqueous solution of ammonium sulfide. The mixture easily converts to [[ammonia]] and [[hydrogen sulfide]] gases. This conversion illustrates the ease of the following equilibrium:
: (NH<sub>4</sub>)SH<math>\overrightarrow{\leftarrow}</math> NH<sub>3</sub> + H<sub>2</sub>S
Both ammonia and hydrogen sulfide have a powerfully unpleasant smell.


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==References==
{{reflist}}


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[[Category:Ammonium compounds]]
[[Category:Sulfides]]


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<!-- this link is to ammoniumsulfide, not the hydrogensulfide [[de:Ammoniumsulfid]] -->
 
<!-- this link is to ammoniumsulfide, not the hydrogensulfide [[fi:Ammoniumsulfidi]] -->
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Revision as of 03:10, 22 April 2013

Template:Chembox

Ammonium hydrosulfide is the chemical compound with the formula (NH4)SH. It is the salt derived from the ammonium cation and the hydrosulfide anion. The salt exists as colourless, water soluble, micaceous crystals. The compound is encountered mainly as a solution, not as the solid. It is generated by mixing hydrogen sulfide and ammonia.

Preparation

Solutions of ammonium hydrosulfide can be prepared by passing hydrogen sulfide gas through concentrated ammonia solution.[1] According to a detailed 1895 report, hydrogen sulfide reacts with concentrated aqueous ammonia solution at room temperature to give (NH4)2S·2NH4HS. When this species is cooled to 0 °C and treated with additional hydrogen sulfide, one obtains (NH4)2S·12NH4HS.[2] An ice-cold solution of this substance kept at 0 °C and having hydrogen sulfide continually passed through it gives the hydrosulfide.

The common "stink bomb" consists of an aqueous solution of ammonium sulfide. The mixture easily converts to ammonia and hydrogen sulfide gases. This conversion illustrates the ease of the following equilibrium:

(NH4)SH NH3 + H2S

Both ammonia and hydrogen sulfide have a powerfully unpleasant smell.

References

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