Sugeno integral

Silver cyanate is a chemical compound and the cyanate salt of silver.

It can be prepared by reaction of potassium cyanate or urea with silver nitrate.

$\mathrm{A}\mathrm{g}\mathrm{N}{\mathrm{O}}_{\mathrm{3}}+\mathrm{K}\mathrm{O}\mathrm{C}\mathrm{N}\mathrm{⟶}\mathrm{A}\mathrm{g}\mathrm{O}\mathrm{C}\mathrm{N}\mathrm{\downarrow }+\mathrm{K}\mathrm{N}{\mathrm{O}}_{\mathrm{3}}$

$\mathrm{A}\mathrm{g}\mathrm{N}{\mathrm{O}}_{\mathrm{3}}+{\mathrm{H}}_{\mathrm{2}}\mathrm{N}\text{-}\mathrm{C}\mathrm{(}\mathrm{O}\mathrm{)}\text{-}\mathrm{N}{\mathrm{H}}_{\mathrm{2}}\mathrm{⟶}$ $\mathrm{A}\mathrm{g}\mathrm{O}\mathrm{C}\mathrm{N}\mathrm{\downarrow }+\mathrm{N}{\mathrm{H}}_{\mathrm{4}}\mathrm{N}{\mathrm{O}}_{\mathrm{3}}$

Silver cyanate is a beige to gray powder. It crystallises in the monoclinic crystal system in space group P2₁/m with parameters a = 547.3 pm, b = 637.2 pm, c = 341.6 pm und β = 91°.

With nitric acid silver cyanate reacts to form carbon dioxide and ammonium nitrate.

$\mathrm{A}\mathrm{g}\mathrm{O}\mathrm{C}\mathrm{N}+\mathrm{2}\mathrm{H}\mathrm{N}{\mathrm{O}}_{\mathrm{3}}+{\mathrm{H}}_{\mathrm{2}}\mathrm{O}\mathrm{⟶}$

$\mathrm{A}\mathrm{g}\mathrm{N}{\mathrm{O}}_{\mathrm{3}}+\mathrm{C}{\mathrm{O}}_{\mathrm{2}}\mathrm{\uparrow }+\mathrm{N}{\mathrm{H}}_{\mathrm{4}}\mathrm{N}{\mathrm{O}}_{\mathrm{3}}$

See also

• Justus Von Liebig
• Friedrich Woehler
• Silver fulminate
• Isomerism

References

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