Ambient isotopy: Difference between revisions

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[[File:Kopp Herman.jpg|thumb|right|Hermann Kopp]]
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'''Kopp's law''' can refer to either of two relationships discovered by the German chemist [[Hermann Franz Moritz Kopp]] (1817–1892).
 
#Kopp found "that the molecular heat capacity of a solid compound is the sum of the atomic heat capacities of the elements composing it; the elements having atomic heat capacities lower than those required by the law of Dulong and Petit retain these lower values in their compounds."<ref>See page 96 of {{cite book | title = Physical Chemistry for Colleges | author = Millard, Earl Bowman | year = 1921 | publisher = McGraw-Hill| location = New York | url = http://books.google.com/?id=oYE6AAAAMAAJ&pg=PA96&dq=Kopp%27s+Law}}</ref>
#In studying organic compounds, Kopp found a regular relationship between boiling points and the number of CH<sub>2</sub> groups present.<ref>See page 942 of {{cite book | title = Elements of Chemistry | author = Miller, William Allen | year = 1869| publisher = Longmans, Green, Reader, and Dyer | location = London | url = http://books.google.com/?id=b7ktAAAAYAAJ&pg=PA942&dq=Kopp%27s+law }}</ref>
 
== Kopp–Neumann law ==
'''Kopp–Neumann law''' states that the [[specific heat]] ''C'' per unit [[mass]] (in J•kg<sup>−1</sup>•K<sup>−1</sup>) for [[alloy]]s can be calculated from the following equation:
 
<math>C=\sum_{i=1}^N(C_i \cdot f_i)</math>
 
where: ''i'' - subsequent numbers from 1 to ''N'', ''N'' - total number of alloy constituents, ''C<sub>i</sup>'' and ''f<sub>i</sup>'' - [[specific heat]] and [[mass fraction]] of the ''i''-th constituent.
 
 
 
==References ==
* [[Frederick Seitz]], The Modern Theory of Solids, McGraw-Hill, New York, USA, 1940, [[ASIN]]: B000OLCK08
<references />
 
==Further reading==
 
*{{cite journal | title = The Life Work of Hermann Kopp | author = Thorpe, T. E. | journal = Memorial lectures delivered before the Chemical Society | year = 1901 | volume = 25 | pages = 774&ndash;815 | url = http://books.google.com/?id=dcfQAAAAMAAJ&pg=PA775&dq=Herman+Kopp+memorial}}
 
[[Category:Thermodynamics]]
 
 
{{chemistry-stub}}
{{physics-stub}}

Latest revision as of 03:15, 26 November 2014

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