Binomial series: Difference between revisions

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en>PMajer
Undid revision 584036634 by Winsteps (talk) Undone edit with misleading formula. Here α can also be a negative integer, so that α! makes no sense.
en>LutzL
Signs were correct. Cumulative factors are 3/2, 1/2, -1/2, -3/2. Alternation of sign because of minus sign in 1-x^2.
 
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{{Unreferenced|date=December 2009}}
In [[physics]], '''interaction energy''' is the contribution to the total [[energy]] that is caused by an [[interaction]] between the objects being considered.


The interaction energy usually depends on the relative position of the objects. For example, <math>Q_1 Q_2 / (4 \pi \epsilon_0 \Delta r)</math> is the [[electrostatics|electrostatic]] interaction energy between two objects with charges <math>Q_1</math>, <math>Q_2</math>.


==Supermolecular interaction energy==
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A straightforward approach for evaluating the interaction energy is to calculate the difference between the energies of isolated objects and their assembly. In the case of two objects, ''A'' and ''B'', the interaction energy can be written as:
 
<math>\Delta E_{int} = E(A,B) - \left( E(A) + E(B) \right)</math>,
 
where <math>E(A)</math> and <math>E(B)</math> are the energies of the isolated objects (monomers), and <math>E(A,B)</math> the energy of their interacting assembly (dimer).
 
For larger system, consisting of ''N'' objects, this procedure can be generalized to provide a total many-body interaction energy:
 
<math>\Delta E_{int} = E(A_{1}, A_{2}, .., A_{N}) - \sum_{i=1}^{N} E(A_{i})</math>.
 
By calculating the energies for monomers, dimers, trimers, etc., in an N-object system, a complete set of two-, three-, and up to N-body interaction energies can be derived.
 
The supermolecular approach has an important disadvantage in that the final interaction energy is usually much smaller than the total energies from which it is calculated, and therefore contains a much larger relative uncertainty. In the case where energies are derived from quantum chemical calculations using finite atom centered basis functions, [[basis set superposition error]]s can also contribute some degree of artificial stabilisation.
 
==See also==
* [[Energy]]
* [[Force]]
* [[Interaction]]
* [[Perturbation theory (quantum mechanics)]]
* [[Potential]]
 
{{DEFAULTSORT:Interaction Energy}}
[[Category:Interaction]]
[[Category:Energy (physics)]]

Latest revision as of 02:51, 10 August 2014


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