Carrier generation and recombination: Difference between revisions

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{{Chembox
| Watchedfields = changed
| verifiedrevid = 477167117
| ImageFileL1 = Ethanol-2D-flat.png
|  ImageFileL1_Ref = {{chemboximage|correct|??}}
|  ImageSizeL1 = 131
|  ImageNameL1 = Full structural formula of ethanol
| ImageFileR1 = Ethanol-2D-skeletal.svg
|  ImageFileR1_Ref = {{chemboximage|correct|??}}
|  ImageSizeR1 = 111
|  ImageNameR1 = Skeletal formula of ethanol
| ImageFileL2 = Ethanol-3D-balls.png
|  ImageFileL2_Ref = {{chemboximage|correct|??}}
|  ImageSizeL2 = 131
|  ImageNameL2 = Ball-and-stick model of ethanol
| ImageFileR2 = Ethanol-3D-vdW.png
|  ImageFileR2_Ref = {{chemboximage|correct|??}}
|  ImageSizeR2 = 111
|  ImageNameR2 = Space-filling model of ethanol
| SystematicName = Ethanol<ref name="Pubchem">{{cite web|title = Ethanol – Compound Summary|url = http://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=702|work = The PubChem Project|location = USA|publisher = National Center for Biotechnology Information}}</ref>
| OtherNames = {{Plainlist|
* Absolute alcohol
* Alcohol
* Drinking alcohol
* Ethyl alcohol
* Ethyl hydrate
* Ethyl hydroxide
* Ethylic alcohol
* Ethylol
* Grain alcohol
* Hydroxyethane
* Methylcarbinol
}}
| Section1 = {{Chembox Identifiers
|  CASNo = 64-17-5
|  CASNo_Ref = {{cascite|correct|CAS}}
|  PubChem = 702
|  PubChem_Ref = {{Pubchemcite|correct|PubChem}}
|  ChemSpiderID = 682
|  ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
|  UNII = 3K9958V90M
|  UNII_Ref = {{fdacite|correct|FDA}}
|  EINECS = 200-578-6
|  UNNumber = 1170
|  DrugBank_Ref = {{drugbankcite|correct|drugbank}}
| DrugBank = DB00898
|  KEGG = D00068
|  KEGG_Ref = {{keggcite|correct|kegg}}
|  MeSHName = Ethanol
|  ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI = 16236
|  ChEMBL = 545
|  ChEMBL_Ref = {{ebicite|correct|EBI}}
|  RTECS = KQ6300000
|  ATCCode_prefix = D01
|  ATCCode_suffix = AE06
|  ATC_Supplemental = {{ATC|D08|AX08}}, {{ATC|V03|AB16}}, {{ATC|V03|AZ01}}
|  Beilstein = 1718733
|  Gmelin = 787
|  3DMet = B01253
|  SMILES = CCO
|  StdInChI = 1S/C2H6O/c1-2-3/h3H,2H2,1H3
|  StdInChI_Ref = {{stdinchicite|correct|chemspider}}
|  InChI = 1/C2H6O/c1-2-3/h3H,2H2,1H3
|  StdInChIKey = LFQSCWFLJHTTHZ-UHFFFAOYSA-N
|  StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
|  InChIKey = LFQSCWFLJHTTHZ-UHFFFAOYAB}}
| Section2 = {{Chembox Properties
|  C = 2
|  H = 6
|  O = 1
|  ExactMass = 46.041864814 g mol<sup>−1</sup>
|  Appearance = Colorless liquid
|  Density = 0.789 g/cm<sup>3</sup> (at 20°C)
|  MeltingPtC = −114
|  BoilingPtC = 78.37
|  LogP = -0.18
|  VaporPressure = 5.95 kPa (at 20 °C)
|  pKa = 15.9<ref>{{cite journal|doi=10.1021/ja01489a008|year=1960|last1=Ballinger|first1=P.|last2=Long|first2=F. A.|journal=Journal of the American Chemical Society|volume=82|issue=4|page=795}}</ref>
|  pKb = -1.9
|  RefractIndex = 1.361
|  Viscosity = 0.0012 Pa s (at 20 °C), 0.001074 Pa s (at 25 °C)<ref name=crc92>{{Cite book|editor=Lide, David R.|title=CRC Handbook of Chemistry and Physics|edition=92|year=2012|publisher=CRC Press/Taylor and Francis|location=Boca Raton, FL.|pages=6–232}}</ref>
|  Dipole = 1.69 D<ref name=crc89>{{Cite book|editor=Lide, David R.|title=CRC Handbook of Chemistry and Physics|edition=89|year=2008|publisher=CRC Press|location=Boca Raton|pages=9–55}}</ref>
}}
| Section3 = {{Chembox Pharmacology
|  AdminRoutes = Intramuscular<br />
Intravenous<br />
Oral<br />
Topical
|  Metabolism = Hepatic
|  [[Dependence liability]] – low-moderate
}}
| Section4 = {{Chembox Hazards
|  EUIndex = 603-002-00-5
|  EUClass = {{Hazchem F}}
|  RPhrases = {{R11}}
|  SPhrases = {{S2}}, {{S7}}, {{S16}}
|  NFPA-H = 2
|  NFPA-F = 3
|  NFPA-R = 0
|  FlashPt = 13–14 °C
|  Autoignition = 363 °C<ref>{{cite web |url=http://www.engineeringtoolbox.com/fuels-ignition-temperatures-d_171.html |title=Fuels and Chemicals – Autoignition Temperatures |publisher=engineeringtoolbox.com |postscript=<!-- Bot inserted parameter. Either remove it; or change its value to "." for the cite to end in a ".", as necessary. -->{{inconsistent citations}}
}}</ref>
|  LD50 = 5628 mg kg<sup>−1</sup> (oral, rat)
}}
}}
 
This page provides supplementary chemical data on [[ethanol]]. Except where noted otherwise, data relate to [[standard ambient temperature and pressure]].
 
== Material Safety Data Sheet == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet ([[Material safety data sheet|MSDS]]) for this chemical from a reliable source and follow its directions.
 
== Structure and properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Structure and properties
|-
| [[Index of refraction]], ''n''<sub>25</sub>
| 1.361 <!-- Please omit if not applicable -->
|-
| [[Dielectric constant]], ε<sub>r</sub>
| 24.3 ε<sub>0</sub> at 25&nbsp;°C <!-- Please omit if not applicable -->
|-
| [[Bond strength (chemistry)|Bond strength]]
| ? <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond length]]
| ? <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond angle]]
| ? <!-- Specify which angle, e.g. Cl-P-O. Please omit if not applicable -->
|-
| [[Magnetic susceptibility]]<ref>[http://nmr.chem.umn.edu/ResReports/NMR002.html NMR-002: Sample Devices and Magnetic Susceptibility<!-- Bot generated title -->]</ref>
| 5.8·10<sup>−7</sup> ([[cgs]] units, volume)
|-
| [[Surface tension]]
| 22.39 dyn/cm at 25&nbsp;°C
|-
| [[Viscosity]]<ref name="cheric_p">{{Cite web|url=http://www.cheric.org/research/kdb/hcprop/cmpsrch.php|title=Pure Component Properties|format=Queriable database|publisher=Chemical Engineering Research Information Center|accessdate=12 May 2007}}</ref>
|
{|
|-
| 6.285 mPa·s || at –50&nbsp;°C
|-
| 4.656 mPa·s || at –40&nbsp;°C
|-
| 3.530 mPa·s || at –30&nbsp;°C
|-
| 2.731 mPa·s || at –20&nbsp;°C
|-
| 2.419 mPa·s || at –15&nbsp;°C
|-
| 2.151 mPa·s || at –10&nbsp;°C
|-
| 1.920 mPa·s || at –5&nbsp;°C
|-
| 1.720 mPa·s || at 0&nbsp;°C
|-
| 1.546 mPa·s || at 5&nbsp;°C
|-
| 1.394 mPa·s || at 10&nbsp;°C
|-
| 1.261 mPa·s || at 15&nbsp;°C
|-
| 1.144 mPa·s || at 20&nbsp;°C
|-
| 1.040 mPa·s || at 25&nbsp;°C
|-
| 0.949 mPa·s || at 30&nbsp;°C
|-
| 0.794 mPa·s || at 40&nbsp;°C
|-
| 0.670 mPa·s || at 50&nbsp;°C
|-
| 0.570 mPa·s || at 60&nbsp;°C
|-
| 0.487 mPa·s || at 70&nbsp;°C
|-
| 0.452 mPa·s || at 75&nbsp;°C
|-
|}
|}
 
== Thermodynamic properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Phase behavior
|-
| [[Triple point]]
| 150&nbsp;K (&minus;123&nbsp;°C), 0.00043&nbsp;Pa
|-
| [[Critical point (thermodynamics)|Critical point]]
| 514&nbsp;K (241&nbsp;°C), 63 bar
|-
| [[Standard enthalpy change of fusion|Std enthalpy change<br/>of fusion]], Δ<sub>fus</sub>''H''<sup><s>o</s></sup>
| +4.9&nbsp;kJ/mol
|-
| [[Standard entropy change of fusion|Std entropy change<br/>of fusion]], Δ<sub>fus</sub>''S''<sup><s>o</s></sup>
| +31&nbsp;J/(mol·K)
|-
| [[Standard enthalpy change of vaporization|Std enthalpy change<br/>of vaporization]], Δ<sub>vap</sub>''H''<sup><s>o</s></sup>
| +38.56&nbsp;kJ/mol
|-
| [[Standard entropy change of vaporization|Std entropy change<br/>of vaporization]], Δ<sub>vap</sub>''S''<sup><s>o</s></sup>
| 109.67&nbsp;J/(mol·K)
|-
| [[Freezing-point depression|Molal freezing point constant]]
| –1.99&nbsp;°C kg/mol
|-
| [[Boiling-point elevation|Molal boiling point constant]]
| 1.19&nbsp;°C kg/mol
|-
! {{chembox header}} | Solid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>solid</sub>
| –277.7&nbsp;kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>solid</sub>
| 160.7&nbsp;J/(mol K)<ref name=atkins>{{cite book|last=Atkins|first=Peter|title=Atkins' Physical Chemistry|year=2010|publisher=Oxford University Press|pages=913–947}}</ref>
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 111.46&nbsp;J/(mol K) <ref name="atkins"/>
|-
! {{chembox header}} | Liquid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>liquid</sub>
| &minus;277.38&nbsp;kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>liquid</sub>
| 159.9&nbsp;J/(mol K)
|-
| [[Enthalpy of combustion]], Δ<sub>c</sub>''H''<sup><s>o</s></sup>
| –1370.7&nbsp;kJ/mol
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 112.4&nbsp;J/(mol K)
|-
! {{chembox header}} | Gas properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>gas</sub>
| &minus;235.3&nbsp;kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>gas</sub>
| 283&nbsp;J/(mol K)
|-
| [[Heat capacity]],<ref name="lange1525">''Lange's Handbook of Chemistry'' 10th ed, pp 1525-1528</ref><ref name="crc1582">''CRC Handbook of Chemistry and Physics'' 44th ed. pp 2582-2584</ref> ''c<sub>p</sub>''
| 78.28&nbsp;J/(mol K) at 90&nbsp;°C<br>87.53&nbsp;J/(mol K) at 110-220&nbsp;°C
|-
| [[Heat capacity ratio]],<ref name="lange1525"/><ref name="crc1582"/><br> ''γ'' = ''c<sub>p</sub>''/''c<sub>v</sub>''
| 1.13 at 90&nbsp;°C
|-
| [[van der Waals equation|van der Waals' constants]]<ref name="lange1522">''Lange's Handbook of Chemistry'' 10th ed, pp 1522-1524</ref>
| a = 1217.9 L<sup>2</sup> kPa/mol<sup>2</sup><br> b = 0.08407 liter per mole
|-
|}
 
== Spectral data == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | [[UV/VIS spectroscopy|UV-Vis]]
|-
| [[Lambda-max|λ<sub>max</sub>]]
| ? [[Nanometre|nm]]
|-
| [[molar absorptivity|Extinction coefficient]], ε
| ?
|-
! {{chembox header}} | [[Infrared|IR]]
|-
| Major absorption bands<ref name="aist">{{Cite web|url=http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/cre_index.cgi?lang=eng|title=Spectral Database for Organic Compounds|publisher=Advanced Industrial Science and Technology|format=Queriable database|accessdate=9 June 2007}}</ref>
|
{|
|-
| colspan="2" align="center" | (liquid film)
|-
! Wave number !! transmittance
|-
| 880&nbsp;cm<sup>&minus;1</sup> || 22%
|-
| 1048&nbsp;cm<sup>&minus;1</sup> || 6%
|-
| 1089&nbsp;cm<sup>&minus;1</sup> || 19%
|-
| 1275&nbsp;cm<sup>&minus;1</sup> || 52%
|-
| 1329&nbsp;cm<sup>&minus;1</sup> || 44%
|-
| 1384&nbsp;cm<sup>&minus;1</sup> || 32%
|-
| 1418&nbsp;cm<sup>&minus;1</sup> || 33%
|-
| 1650&nbsp;cm<sup>&minus;1</sup> || 26%
|-
| 1926&nbsp;cm<sup>&minus;1</sup> || 62%
|-
| 2899&nbsp;cm<sup>&minus;1</sup> || 12%
|-
| 2930&nbsp;cm<sup>&minus;1</sup> || 13%
|-
| 2977&nbsp;cm<sup>&minus;1</sup> || 4%
|}
|-
! {{chembox header}} | [[NMR Spectroscopy|NMR]]
|-
| [[Proton NMR]] <!-- Link to image of spectrum -->
| &nbsp;
|-
| [[Carbon-13 NMR]] <!-- Link to image of spectrum -->
| http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/IMG.cgi?fname=CDS00245&imgdir=cdsW;
|-
| Other NMR data <!-- Insert special data e.g. <sup>19</sup>F chem. shifts, omit if not used -->
| &nbsp;
|-
! {{chembox header}} | [[Mass Spectrometry|MS]]
|-
| Masses of <br>main fragments
| &nbsp; <!-- Give list of major fragments -->
|-
|}
 
==Vapor pressure of liquid  ==
 
{|
|-
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|- align=center
| {{chembox header}} | '''P in mm Hg''' || 1 || 10 || 40 || 100 || 400 || 760 || 1520 || 3800 || 7600 || 15200 || 30400 || 45600
|- align=center
| {{chembox header}} | '''P in Pa''' || 133.3 || 1333 || 5333 || 13332 || 53329 || 101325 || 202650 || 506625 || 1013250 || 2026500 || 4053000 || 6079501
|- align=center
| {{chembox header}} | '''T in&nbsp;°C''' || –31.3 || –2.3 || 19.0 || 34.9 || 63.5 || 78.4 || 97.5 || 126.0 || 151.8 || 183.0 || 218.0 || 242.0
|- align=center
| {{chembox header}} | '''T in K''' || 241.85 || 270.85 || 292.15 || 308.05 || 336.65 || 351.55 || 370.65 || 399.15 || 424.95 || 456.15 || 491.15 || 515.15
|}
|-
|
{|
|
[[Image:EtOHvaporpressureL.png|thumb|302px|left|Ethanol vapor pressure vs. temperature. Uses formula: <math>\scriptstyle P_{mmHg} = 10^{8.04494 - \frac {1554.3} {222.65+T}}</math> from ''Lange's Handbook of Chemistry'' 10th ed.]]
|
[[Image:EtOHlogVaporPressureL.png|thumb|500px|left|Log<sub>10</sub> of ethanol vapor pressure vs. temperature. Uses formula: <math>\scriptstyle \log_{10} {P_{mmHg}} = 8.04494 - \frac {1554.3} {222.65+T}</math>]]
|}
|}
{{Clear}}
 
==Density of ethanol at various temperatures (''kg/l'' or ''g/cm<sup>3</sup>'')==
Data obtained from ''Lange's Handbook of Chemistry'', 10th ed.
 
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
|- {{chembox header}} bgcolor="#F8EABA"
| 3&nbsp;°C || 0.80374 || 16&nbsp;°C || 0.79283 || 29&nbsp;°C || 0.78182
|-
| 4&nbsp;°C || 0.80290 || 17&nbsp;°C || 0.79198 || 30&nbsp;°C || 0.78097
|-
| 5&nbsp;°C || 0.80207 || 18&nbsp;°C || 0.79114 || 31&nbsp;°C || 0.78012
|-
| 6&nbsp;°C || 0.80123 || 19&nbsp;°C || 0.79029 || 32&nbsp;°C || 0.77927
|-
| 7&nbsp;°C || 0.80039 || 20&nbsp;°C || 0.78945 || 33&nbsp;°C || 0.77841
|-
| 8&nbsp;°C || 0.79956 || 21&nbsp;°C || 0.78860 || 34&nbsp;°C || 0.77756
|-
| 9&nbsp;°C || 0.79872 || 22&nbsp;°C || 0.78775 || 35&nbsp;°C || 0.77671
|-
| 10&nbsp;°C || 0.79788 || 23&nbsp;°C || 0.78691 || 36&nbsp;°C || 0.77585
|-
| 11&nbsp;°C || 0.79704 || 24&nbsp;°C || 0.78606 || 37&nbsp;°C || 0.77500
|-
| 12&nbsp;°C || 0.79620 || 25&nbsp;°C || 0.78522 || 38&nbsp;°C || 0.77414
|-
| || || 39&nbsp;°C || 0.77329 || 40&nbsp;°C || 0.77244
|}
These data correlate as Density (g/cm<sup>3</sup>) = -8.461834E-4 T(&nbsp;°C) + 0.8063372 with an R<sup>2</sup> coefficient of determination of 0.99999.
 
==Properties of aqueous ethanol solutions==
Data obtained from ''Lange's Handbook of Chemistry'', 10th ed. The annotation, '''d a&nbsp;°C/b&nbsp;°C''', indicates density of solution at temperature '''a''' divided by density of pure water at temperature '''b'''.
 
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
|- {{chembox header}}
| '''% wt<br>ethanol''' || '''% vol<br>ethanol''' || '''grams<br>ethanol<br>per 100 cc<br>15.56&nbsp;°C''' || '''d 10&nbsp;°C/4&nbsp;°C''' || '''d 20&nbsp;°C/4&nbsp;°C''' || '''d 25&nbsp;°C/4&nbsp;°C''' || '''d 30&nbsp;°C/4&nbsp;°C''' || '''d 20&nbsp;°C/20&nbsp;°C''' || '''d 25&nbsp;°C/25&nbsp;°C''' || '''freezing<br>temp.'''
|-
| 0.0 || 0.0 || 0.0 || 0.99973 || 0.99823 || 0.99708 || 0.99568 || 1.00000 || 1.00000 || 0&nbsp;°C
|-
| 1.0 || || || 0.99785 || 0.99636 || 0.99520 || 0.99379 || 0.99813 || 0.99811  ||
|-
| 2.0 || || || 0.99602 || 0.99453 || 0.99336 || 0.99194 || 0.99629 || 0.99627  ||
|-
| 2.5 || 3.13 || || || 0.99363 || || || || || –1&nbsp;°C
|-
| 3.0 || || || 0.99426 || 0.99275 || 0.99157 || 0.99014 || 0.99451 || 0.99447  ||
|-
| 4.0 || 5.00 || 3.97 || 0.99258 || 0.99103 || 0.98984 || 0.98839 || 0.99279 || 0.99274  ||
|-
| 4.8 || 6.00 || 4.76 || || 0.98971 || || || || || –2&nbsp;°C
|-
| 5.0 || || || 0.99098 || 0.98938 || 0.98817 || 0.98670 || 0.99113 || 0.99106 ||
|-
| 5.05 || 6.30 || 5.00 || || 0.98930 || || || || ||
|-
| 6.0 || || || 0.98946 || 0.98780 || 0.98656 || 0.98507 || 0.98955 || 0.98945  ||
|-
| 6.8 || 8.47 || || || 0.98658 || || || || || –3&nbsp;°C
|-
| 7.0 || || || 0.98801 || 0.98627 || 0.98500 || 0.98347 || 0.98802 || 0.98788  ||
|-
| 8.0 || || || 0.98660 || 0.98478 || 0.98346 || 0.98189 || 0.98653 || 0.98634  ||
|-
| 9.0 || || || 0.98524 || 0.98331 || 0.98193 || 0.98031 || 0.98505 || 0.98481  ||
|-
| 10.0 || 12.40 || 9.84 || 0.98393 || 0.98187 || 0.98043 || 0.97575 || 0.98361 || 0.98330 ||
|-
| 11.0 || || || 0.98267 || 0.98047 || 0.97897 || 0.97723 || 0.98221 || 0.98184 ||
|-
| 11.3 || 14.0 || 11.11 || || 0.98006 || || || || || –5&nbsp;°C
|-
| 12.0 || || || 0.98145 || 0.97910 || 0.97753 || 0.97573 || 0.98084 || 0.98039 ||
|-
| 13.0 || || || 0.98026 || 0.97775 || 0.97611 || 0.97424 || 0.97948 || 0.97897 ||
|-
| 13.78 || 17.00 || 13.49 || || || || || || || –6.1&nbsp;°C
|-
| 14.0 || || || 0.97911 || 0.97643 || 0.97472 || 0.97278 || 0.97816 || 0.97757 ||
|-
| 15.0 || || || 0.97800 || 0.97514 || 0.97334 || 0.97133 || 0.97687 || 0.97619 ||
|-
| 15.02 || 18.50 || 14.68 || || 0.97511 || || || || ||
|-
| 16.0 || || || 0.97692 || 0.97387 || 0.97199 || 0.96990 || 0.97560 || 0.97484 ||
|-
| 16.4 || 20.2 || || || 0.97336 || || || || || –7.5&nbsp;°C
|-
| 17.0 || || || 0.97583 || 0.97259 || 0.97062 || 0.96844 || 0.97431 || 0.97346 ||
|-
| 17.5 || 21.5 || || || 0.97194 || || || || || –8.7&nbsp;°C
|-
| 18.0 || 22.10 || 17.54 || 0.97473 || 0.97129 || 0.96923 || 0.96697 || 0.97301 || 0.97207 ||
|-
| 18.8 || 23.1 || || || 0.97024 || || || || || –9.4&nbsp;°C
|-
| 19.0 || || || 0.97363 || 0.96997 || 0.96782 || 0.96547 || 0.97169 || 0.97065 ||
|-
| 20.0 || || || 0.97252 || 0.96864 || 0.96639 || 0.96395 || 0.97036 || 0.96922 ||
|-
| 20.01 || 24.50 || 19.44 || || 0.96863 || || || || ||
|-
| 20.3 || 24.8 || || || 0.96823 || || || || || –10.6&nbsp;°C
|-
| 21.0 || || || 0.97139 || 0.96729 || 0.96495 || 0.96242 || 0.96901 || 0.96778 ||
|-
| 22.0 || || || 0.97024 || 0.96592 || 0.96348 || 0.96087 || 0.96763 || 0.96630 ||
|-
| 22.11 || 27.00 || 21.43 || || 0.96578 || || || || || –12.2&nbsp;°C
|-
| 23.0 || || || 0.96907 || 0.96453 || 0.96199 || 0.95929 || 0.96624 || 0.96481 ||
|-
| 24.0 || || || 0.96787 || 0.96312 || 0.96048 || 0.95769 || 0.96483 || 0.96329 ||
|-
| 24.2 || 29.5 || || || 0.96283 || || || || || –14.0&nbsp;°C
|-
| 25.0 || 30.40 || 24.12 || 0.96665 || 0.96168 || 0.95895 || 0.95607 || 0.96339 || 0.96176 ||
|-
| 26.0 || || || 0.96539 || 0.96020 || 0.95738 || 0.95422 || 0.96190 || 0.96018 ||
|-
| 26.7 || 32.4 || || || 0.95914 || || || || || –16.0&nbsp;°C
|-
| 27.0 || || || 0.96406 || 0.95867 || 0.95576 || 0.95272 || 0.96037 || 0.95856 ||
|-
| 28.0 || 33.90 || 26.90 || 0.96268 || 0.95710 || 0.95410 || 0.95098 || 0.95880 || 0.95689 ||
|-
| 29.0 || || || 0.96125 || 0.95548 || 0.95241 || 0.94922 || 0.95717 || 0.95520 ||
|-
| 29.9 || 36.1 || || || 0.95400 || || || || || –18.9&nbsp;°C
|-
| 30.0 || 36.20 || 28.73 || 0.95977 || 0.95382 || 0.95067 || 0.94741 || 0.95551 || 0.95345 ||
|-
| 31.0 || || || 0.95823 || 0.95212 || 0.94890 || 0.94557 || 0.95381 || 0.95168 ||
|-
| 32.0 || || || 0.95665 || 0.95038 || 0.94709 || 0.94370 || 0.95207 || 0.94986 ||
|-
| 33.0 || || || 0.95502 || 0.94860 || 0.94525 || 0.94180 || 0.95028 || 0.94802 ||
|-
| 33.8 || 40.5 || || || 0.94715 || || || || || –23.6&nbsp;°C
|-
| 34.0 || || || 0.95334 || 0.94679 || 0.94337 || 0.93986 || 0.94847 || 0.94613 ||
|-
| 35.0 || || || 0.95162 || 0.94494 || 0.94146 || 0.93790 || 0.94662 || 0.94422 ||
|-
| 35.04 || 41.90 || 33.25 || || 0.94486 || || || || ||
|-
| 36.0 || || || 0.94986 || 0.94306 || 0.93952 || 0.93591 || 0.94473 || 0.94227 ||
|-
| 37.0 || || || 0.94805 || 0.94114 || 0.93756 || 0.93390 || 0.94281 || 0.94031 ||
|-
| 38.0 || || || 0.94620 || 0.93919 || 0.93556 || 0.93186 || 0.94086 || 0.93830 ||
|-
| 39.0 || 46.3 || || 0.94431 || 0.93720 || 0.93353 || 0.92979 || 0.93886 || 0.93626 || –28.7&nbsp;°C
|-
| 40.0 || || || 0.94238 || 0.93518 || 0.93148 || 0.92770 || 0.93684 || 0.93421 ||
|-
| 40.04 || 47.40 || 37.61 || || 0.93510 || || || || ||
|-
| 41.0 || || || 0.94042 || 0.93314 || 0.92940 || 0.92558 || 0.93479 || 0.93212 ||
|-
| 42.0 || || || 0.93842 || 0.93107 || 0.92729 || 0.92344 || 0.93272 || 0.93001 ||
|-
| 43.0 || || || 0.93639 || 0.92897 || 0.92516 || 0.92128 || 0.93062 || 0.92787 ||
|-
| 44.0 || || || 0.93433 || 0.92685 || 0.92301 || 0.91910 || 0.92849 || 0.92571 ||
|-
| 45.0 ||  ||  || 0.93226 || 0.92472 || 0.92085 || 0.91692 || 0.92636 || 0.92355 ||
|-
| 45.31 || 53.00 || 42.07 || || 0.92406 || || || || ||
|-
| 46.0 || || || 0.93017 || 0.92257 || 0.91868 || 0.91472 || 0.92421 || 0.92137 ||
|-
| 46.3 || 53.8 || || || 0.92193 || || || || || –33.9&nbsp;°C
|-
| 47.0 || || || 0.92806 || 0.92041 || 0.91649 || 0.91250 || 0.92204 || 0.91917 ||
|-
| 48.0 || || || 0.92593 || 0.91823 || 0.91429 || 0.91028 || 0.91986 || 0.91697 ||
|-
| 49.0 || || || 0.92379 || 0.91604 || 0.91208 || 0.90805 || 0.91766 || 0.91475 ||
|-
| 50.0 || || || 0.92162 || 0.91384 || 0.90985 || 0.90580 || 0.91546 || 0.91251 ||
|-
| 50.16 || 58.0 || 46.04 || || 0.91349 || || || || ||
|-
| 51.0 || || || 0.91943 || 0.91160 || 0.90760 || 0.90353 || 0.91322 || 0.91026 ||
|-
| 52.0 || || || 0.91723 || 0.90936 || 0.90524 || 0.90125 || 0.91097 || 0.90799 ||
|-
| 53.0 || || || 0.91502 || 0.90711 || 0.90307 || 0.89896 || 0.90872 || 0.90571 ||
|-
| 54.0 || || || 0.91279 || 0.90485 || 0.90079 || 0.89667 || 0.90645 || 0.90343 ||
|-
| 55.0 || || || 0.91055 || 0.90258 || 0.89850 || 0.89437 || 0.90418 || 0.90113 ||
|-
| 55.16 || 63.0 || 50.00 || || 0.90220 || || || || ||
|-
| 56.0 || || || 0.90831 || 0.90031 || 0.89621 || 0.89206 || 0.90191 || 0.89833 ||
|-
| 56.1 || 63.6 || || || 0.90008 || || || || || –41.0&nbsp;°C
|-
| 57.0 || || || 0.90607 || 0.89803 || 0.89392 || 0.88975 || 0.89962 || 0.89654 ||
|-
| 58.0 || || || 0.90381 || 0.89574 || 0.89162 || 0.88744 || 0.89733 || 0.89423 ||
|-
| 59.0 || || || 0.90154 || 0.89344 || 0.88931 || 0.88512 || 0.89502 || 0.89191 ||
|-
| 60.0 || || || 0.89927 || 0.89113 || 0.88699 || 0.88278 || 0.89271 || 0.88959 ||
|-
| 60.33 || 68.0 || 53.98 || || 0.89038 || || || || ||
|-
| 61.0 || || || 0.89898 || 0.88882 || 0.88466 || 0.88044 || 0.89040 || 0.88725 ||
|-
| 62.0 || || || 0.89468 || 0.88650 || 0.88233 || 0.87809 || 0.88807 || 0.88491 ||
|-
| 63.0 || || || 0.89237 || 0.88417 || 0.87998 || 0.87574 || 0.88574 || 0.88256 ||
|-
| 64.0 || || || 0.89006 || 0.88183 || 0.87763 || 0.87337 || 0.88339 || 0.88020 ||
|-
| 65.0 || || || 0.88774 || 0.87948 || 0.87527 || 0.87100 || 0.88104 || 0.87783 ||
|-
| 66.0 || || || 0.88541 || 0.87713 || 0.87291 || 0.86863 || 0.87869 || 0.87547 ||
|-
| 67.0 || || || 0.88308 || 0.87477 || 0.87054 || 0.86625 || 0.87632 || 0.87309 ||
|-
| 68.0 || || || 0.88071 || 0.87241 || 0.86817 || 0.86387 || 0.87396 || 0.87071 ||
|-
| 69.0 || || || 0.87839 || 0.87004 || 0.86579 || 0.86148 || 0.87158 || 0.86833 ||
|-
| 70.0 || || || 0.87602 || 0.86766 || 0.86340 || 0.85908 || 0.86920 || 0.86593 ||
|-
| 71.0 || || || 0.87365 || 0.86527 || 0.86100 || 0.85667 || 0.86680 || 0.86352 ||
|-
| 71.9 || 78.3 || || || 0.86311 || || || || || –51.3&nbsp;°C
|-
| 72.0 || || || 0.87127 || 0.86287 || 0.85859 || 0.85426 || 0.86440 || 0.86110 ||
|-
| 73.0 || || || 0.86888 || 0.86047 || 0.85618 || 0.85184 || 0.86200 || 0.85869 ||
|-
| 74.0 || || || 0.86648 || 0.85806 || 0.85376 || 0.84941 || 0.85958 || 0.85626 ||
|-
| 75.0 || || || 0.86408 || 0.85564 || 0.85135 || 0.84698 || 0.85716 || 0.85383 ||
|-
| 76.0 || || || 0.86168 || 0.85322 || 0.84891 || 0.84455 || 0.85473 || 0.85140 ||
|-
| 77.0 || || || 0.85927 || 0.85079 || 0.84647 || 0.84211 || 0.85230 || 0.84895 ||
|-
| 78.0 || || || 0.85685 || 0.84835 || 0.84403 || 0.83966 || 0.84985 || 0.84650 ||
|-
| 79.0 || || || 0.85422 || 0.84590 || 0.84158 || 0.83720 || 0.84740 || 0.84404 ||
|-
| 80.0 || || || 0.85197 || 0.84344 || 0.83911 || 0.83473 || 0.84494 || 0.84157 ||
|-
| 81.0 || || || 0.84950 || 0.84096 || 0.83664 || 0.83224 || 0.84245 || 0.83909 ||
|-
| 82.0 || || || 0.84702 || 0.83848 || 0.83415 || 0.82974 || 0.83997 || 0.83659 ||
|-
| 83.0 || || || 0.84453 || 0.83599 || 0.83164 || 0.82724 || 0.83747 || 0.83408 ||
|-
| 84.0 || || || 0.84203 || 0.83348 || 0.82913 || 0.82473 || 0.83496 || 0.83156 ||
|-
| 85.0 || || || 0.83951 || 0.83095 || 0.82660 || 0.82220 || 0.83242 || 0.82902 ||
|-
| 86.0 || || || 0.83697 || 0.82840 || 0.82405 || 0.81965 || 0.82987 || 0.82646 ||
|-
| 87.0 || || || 0.83441 || 0.82554 || 0.82148 || 0.81708 || 0.82729 || 0.82389 ||
|-
| 88.0 || || || 0.83181 || 0.82323 || 0.81888 || 0.81448 || 0.82469 || 0.82128 ||
|-
| 89.0 || || || 0.82919 || 0.82062 || 0.81626 || 0.81186 || 0.82207 || 0.81865 ||
|-
| 90.0 || || || 0.82654 || 0.81797 || 0.81362 || 0.80922 || 0.81942 || 0.81600 ||
|-
| 91.00 || 94.00 || 74.62 || 0.82386 || 0.81529 || 0.81094 || 0.80655 || 0.81674 || 0.81331 ||
|-
| 92.0 || || || 0.82114 || 0.81257 || 0.80823 || 0.80384 || 0.81401 || 0.81060 ||
|-
| 93.0 || || || 0.81839 || 0.80983 || 0.80549 || 0.80111 || 0.81127 || 0.80785 ||
|-
| 94.0 || || || 0.81561 || 0.80705 || 0.80272 || 0.79835 || 0.80848 || 0.80507 ||
|-
| 95.0 || || || 0.81278 || 0.80424 || 0.79991 || 0.79555 || 0.80567 || 0.80225 ||
|-
| 96.0 || || || 0.80991 || 0.80138 || 0.79706 || 0.79271 || 0.80280 || 0.79939 ||
|-
| 97.0 || || || 0.80698 || 0.79846 || 0.79415 || 0.78981 || 0.79988 || 0.79648 ||
|-
| 98.0 || || || 0.80399 || 0.79547 || 0.79117 || 0.78684 || 0.79688 || 0.79349 ||
|-
| 99.0 || || || 0.80094 || 0.79243 || 0.78814 || 0.78382 || 0.79383 || 0.79045 ||
|-
| 100.0 || 100.0 || 79.39 || 0.79784 || 0.78934 || 0.78506 || 0.78075 || 0.79074 || 0.78736 || −114.3&nbsp;°C
|- {{chembox header}}
| '''% wt<br>ethanol''' || '''% vol<br>ethanol''' || '''grams<br>ethanol<br>per 100 cc<br>15.56&nbsp;°C''' || '''d 10&nbsp;°C/4&nbsp;°C''' || '''d 20&nbsp;°C/4&nbsp;°C''' || '''d 25&nbsp;°C/4&nbsp;°C''' || '''d 30&nbsp;°C/4&nbsp;°C''' || '''d 20&nbsp;°C/20&nbsp;°C''' || '''d 25&nbsp;°C/25&nbsp;°C''' || '''freezing<br>temp.'''
|}
 
==Boiling points of aqueous solutions==<!-- This section is linked from [[Azeotrope]] -->
Data obtained from ''CRC Handbook of Chemistry'' 44th ed., p2391
 
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|- {{chembox header}}
| rowspan="2" | '''BP&nbsp;°C'''
| colspan="2" | '''Weight % ethanol'''
| rowspan="2" | &nbsp; &nbsp;
| rowspan="2" | '''BP&nbsp;°C'''
| colspan="2" | '''Weight % ethanol'''
|- {{chembox header}}
| '''liquid''' || '''vapor''' || '''liquid''' || '''vapor'''
|-
| 78.1 || 95.5<sup>‡</sup> || 95.5<sup>‡</sup>
| rowspan="29" | &nbsp; &nbsp;
| || ||
|-
| 78.2 || 91 || 92 || 86.5 || 18 || 71
|-
| 78.4 || 85 || 89 || 87.0 || 17 || 70
|-
| 78.6 || 82 || 88 || 87.5 || 16 || 69
|-
| 78.8 || 80 || 87 || 88.0 || 15 || 68
|-
| 79.0 || 78 || 86 || 88.5 || 13 || 67
|-
| 79.2 || 76 || 85 || 89.0 || 12 || 65
|-
| 79.4 || 74 || 85 || 89.5 || 11 || 63
|-
| 79.6 || 72 || 84 || 90.0 || 10 || 61
|-
| 79.8 || 69 || 84 || 90.5 || 10 || 59
|-
| 80.0 || 67 || 83 || 91.0 || 9 || 57
|-
| 80.2 || 64 || 83 || 91.5 || 8 || 55
|-
| 80.4 || 62 || 82 || 92.0 || 8 || 53
|-
| 80.6 || 59 || 82 || 92.5 || 7 || 51
|-
| 80.8 || 56 || 81 || 93.0 || 6 || 49
|-
| 81.0 || 53 || 81 || 93.5 || 6 || 46
|-
| 81.2 || 50 || 80 || 94.0 || 5 || 44
|-
| 81.4 || 47 || 80 || 94.5 || 5 || 42
|-
| 81.6 || 45 || 80 || 95.0 || 4 || 39
|-
| 81.8 || 43 || 79 || 95.5 || 4 || 36
|-
| 82.0 || 41 || 79 || 96.0 || 3 || 33
|-
| 82.5 || 36 || 78 || 96.5 || 3 || 30
|-
| 83.0 || 33 || 78 || 97.0 || 2 || 27
|-
| 83.5 || 30 || 77 || 97.5 || 2 || 23
|-
| 84.0 || 27 || 77 || 98.0 || 1 || 19
|-
| 84.5 || 25 || 75 || 98.5 || 1 || 15
|-
| 85.0 || 23 || 74 || 99.0 || &lt; 1 || 10
|-
| 85.5 || 21 || 73 || 99.5 || &lt; 1 || 5
|-
| 86.0 || 20 || 72 || 100.0 || 0 || 0
|}
 
<sup>‡</sup>[[azeotrope|Azeotropic mixture]]
 
==References==
<references/>
*{{nist}}
 
{{DEFAULTSORT:Ethanol (Data Page)}}
[[Category:Chemical data pages]]

Revision as of 20:06, 11 January 2014

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This page provides supplementary chemical data on ethanol. Except where noted otherwise, data relate to standard ambient temperature and pressure.

Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source and follow its directions.

Structure and properties

Structure and properties
Index of refraction, n25 1.361
Dielectric constant, εr 24.3 ε0 at 25 °C
Bond strength ?
Bond length ?
Bond angle ?
Magnetic susceptibility[1] 5.8·10−7 (cgs units, volume)
Surface tension 22.39 dyn/cm at 25 °C
Viscosity[2]
6.285 mPa·s at –50 °C
4.656 mPa·s at –40 °C
3.530 mPa·s at –30 °C
2.731 mPa·s at –20 °C
2.419 mPa·s at –15 °C
2.151 mPa·s at –10 °C
1.920 mPa·s at –5 °C
1.720 mPa·s at 0 °C
1.546 mPa·s at 5 °C
1.394 mPa·s at 10 °C
1.261 mPa·s at 15 °C
1.144 mPa·s at 20 °C
1.040 mPa·s at 25 °C
0.949 mPa·s at 30 °C
0.794 mPa·s at 40 °C
0.670 mPa·s at 50 °C
0.570 mPa·s at 60 °C
0.487 mPa·s at 70 °C
0.452 mPa·s at 75 °C

Thermodynamic properties

Phase behavior
Triple point 150 K (−123 °C), 0.00043 Pa
Critical point 514 K (241 °C), 63 bar
Std enthalpy change
of fusion
, ΔfusHo
+4.9 kJ/mol
Std entropy change
of fusion
, ΔfusSo
+31 J/(mol·K)
Std enthalpy change
of vaporization
, ΔvapHo
+38.56 kJ/mol
Std entropy change
of vaporization
, ΔvapSo
109.67 J/(mol·K)
Molal freezing point constant –1.99 °C kg/mol
Molal boiling point constant 1.19 °C kg/mol
Solid properties
Std enthalpy change
of formation
, ΔfHosolid
–277.7 kJ/mol
Standard molar entropy,
Sosolid
160.7 J/(mol K)[3]
Heat capacity, cp 111.46 J/(mol K) [3]
Liquid properties
Std enthalpy change
of formation
, ΔfHoliquid
−277.38 kJ/mol
Standard molar entropy,
Soliquid
159.9 J/(mol K)
Enthalpy of combustion, ΔcHo –1370.7 kJ/mol
Heat capacity, cp 112.4 J/(mol K)
Gas properties
Std enthalpy change
of formation
, ΔfHogas
−235.3 kJ/mol
Standard molar entropy,
Sogas
283 J/(mol K)
Heat capacity,[4][5] cp 78.28 J/(mol K) at 90 °C
87.53 J/(mol K) at 110-220 °C
Heat capacity ratio,[4][5]
γ = cp/cv
1.13 at 90 °C
van der Waals' constants[6] a = 1217.9 L2 kPa/mol2
b = 0.08407 liter per mole

Spectral data

UV-Vis
λmax ? nm
Extinction coefficient, ε ?
IR
Major absorption bands[7]
(liquid film)
Wave number transmittance
880 cm−1 22%
1048 cm−1 6%
1089 cm−1 19%
1275 cm−1 52%
1329 cm−1 44%
1384 cm−1 32%
1418 cm−1 33%
1650 cm−1 26%
1926 cm−1 62%
2899 cm−1 12%
2930 cm−1 13%
2977 cm−1 4%
NMR
Proton NMR  
Carbon-13 NMR http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/IMG.cgi?fname=CDS00245&imgdir=cdsW;
Other NMR data  
MS
Masses of
main fragments
 

Vapor pressure of liquid

P in mm Hg 1 10 40 100 400 760 1520 3800 7600 15200 30400 45600
P in Pa 133.3 1333 5333 13332 53329 101325 202650 506625 1013250 2026500 4053000 6079501
T in °C –31.3 –2.3 19.0 34.9 63.5 78.4 97.5 126.0 151.8 183.0 218.0 242.0
T in K 241.85 270.85 292.15 308.05 336.65 351.55 370.65 399.15 424.95 456.15 491.15 515.15
Ethanol vapor pressure vs. temperature. Uses formula: from Lange's Handbook of Chemistry 10th ed.
Log10 of ethanol vapor pressure vs. temperature. Uses formula:

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Density of ethanol at various temperatures (kg/l or g/cm3)

Data obtained from Lange's Handbook of Chemistry, 10th ed.

3 °C 0.80374 16 °C 0.79283 29 °C 0.78182
4 °C 0.80290 17 °C 0.79198 30 °C 0.78097
5 °C 0.80207 18 °C 0.79114 31 °C 0.78012
6 °C 0.80123 19 °C 0.79029 32 °C 0.77927
7 °C 0.80039 20 °C 0.78945 33 °C 0.77841
8 °C 0.79956 21 °C 0.78860 34 °C 0.77756
9 °C 0.79872 22 °C 0.78775 35 °C 0.77671
10 °C 0.79788 23 °C 0.78691 36 °C 0.77585
11 °C 0.79704 24 °C 0.78606 37 °C 0.77500
12 °C 0.79620 25 °C 0.78522 38 °C 0.77414
39 °C 0.77329 40 °C 0.77244

These data correlate as Density (g/cm3) = -8.461834E-4 T( °C) + 0.8063372 with an R2 coefficient of determination of 0.99999.

Properties of aqueous ethanol solutions

Data obtained from Lange's Handbook of Chemistry, 10th ed. The annotation, d a °C/b °C, indicates density of solution at temperature a divided by density of pure water at temperature b.

% wt
ethanol
% vol
ethanol
grams
ethanol
per 100 cc
15.56 °C
d 10 °C/4 °C d 20 °C/4 °C d 25 °C/4 °C d 30 °C/4 °C d 20 °C/20 °C d 25 °C/25 °C freezing
temp.
0.0 0.0 0.0 0.99973 0.99823 0.99708 0.99568 1.00000 1.00000 0 °C
1.0 0.99785 0.99636 0.99520 0.99379 0.99813 0.99811
2.0 0.99602 0.99453 0.99336 0.99194 0.99629 0.99627
2.5 3.13 0.99363 –1 °C
3.0 0.99426 0.99275 0.99157 0.99014 0.99451 0.99447
4.0 5.00 3.97 0.99258 0.99103 0.98984 0.98839 0.99279 0.99274
4.8 6.00 4.76 0.98971 –2 °C
5.0 0.99098 0.98938 0.98817 0.98670 0.99113 0.99106
5.05 6.30 5.00 0.98930
6.0 0.98946 0.98780 0.98656 0.98507 0.98955 0.98945
6.8 8.47 0.98658 –3 °C
7.0 0.98801 0.98627 0.98500 0.98347 0.98802 0.98788
8.0 0.98660 0.98478 0.98346 0.98189 0.98653 0.98634
9.0 0.98524 0.98331 0.98193 0.98031 0.98505 0.98481
10.0 12.40 9.84 0.98393 0.98187 0.98043 0.97575 0.98361 0.98330
11.0 0.98267 0.98047 0.97897 0.97723 0.98221 0.98184
11.3 14.0 11.11 0.98006 –5 °C
12.0 0.98145 0.97910 0.97753 0.97573 0.98084 0.98039
13.0 0.98026 0.97775 0.97611 0.97424 0.97948 0.97897
13.78 17.00 13.49 –6.1 °C
14.0 0.97911 0.97643 0.97472 0.97278 0.97816 0.97757
15.0 0.97800 0.97514 0.97334 0.97133 0.97687 0.97619
15.02 18.50 14.68 0.97511
16.0 0.97692 0.97387 0.97199 0.96990 0.97560 0.97484
16.4 20.2 0.97336 –7.5 °C
17.0 0.97583 0.97259 0.97062 0.96844 0.97431 0.97346
17.5 21.5 0.97194 –8.7 °C
18.0 22.10 17.54 0.97473 0.97129 0.96923 0.96697 0.97301 0.97207
18.8 23.1 0.97024 –9.4 °C
19.0 0.97363 0.96997 0.96782 0.96547 0.97169 0.97065
20.0 0.97252 0.96864 0.96639 0.96395 0.97036 0.96922
20.01 24.50 19.44 0.96863
20.3 24.8 0.96823 –10.6 °C
21.0 0.97139 0.96729 0.96495 0.96242 0.96901 0.96778
22.0 0.97024 0.96592 0.96348 0.96087 0.96763 0.96630
22.11 27.00 21.43 0.96578 –12.2 °C
23.0 0.96907 0.96453 0.96199 0.95929 0.96624 0.96481
24.0 0.96787 0.96312 0.96048 0.95769 0.96483 0.96329
24.2 29.5 0.96283 –14.0 °C
25.0 30.40 24.12 0.96665 0.96168 0.95895 0.95607 0.96339 0.96176
26.0 0.96539 0.96020 0.95738 0.95422 0.96190 0.96018
26.7 32.4 0.95914 –16.0 °C
27.0 0.96406 0.95867 0.95576 0.95272 0.96037 0.95856
28.0 33.90 26.90 0.96268 0.95710 0.95410 0.95098 0.95880 0.95689
29.0 0.96125 0.95548 0.95241 0.94922 0.95717 0.95520
29.9 36.1 0.95400 –18.9 °C
30.0 36.20 28.73 0.95977 0.95382 0.95067 0.94741 0.95551 0.95345
31.0 0.95823 0.95212 0.94890 0.94557 0.95381 0.95168
32.0 0.95665 0.95038 0.94709 0.94370 0.95207 0.94986
33.0 0.95502 0.94860 0.94525 0.94180 0.95028 0.94802
33.8 40.5 0.94715 –23.6 °C
34.0 0.95334 0.94679 0.94337 0.93986 0.94847 0.94613
35.0 0.95162 0.94494 0.94146 0.93790 0.94662 0.94422
35.04 41.90 33.25 0.94486
36.0 0.94986 0.94306 0.93952 0.93591 0.94473 0.94227
37.0 0.94805 0.94114 0.93756 0.93390 0.94281 0.94031
38.0 0.94620 0.93919 0.93556 0.93186 0.94086 0.93830
39.0 46.3 0.94431 0.93720 0.93353 0.92979 0.93886 0.93626 –28.7 °C
40.0 0.94238 0.93518 0.93148 0.92770 0.93684 0.93421
40.04 47.40 37.61 0.93510
41.0 0.94042 0.93314 0.92940 0.92558 0.93479 0.93212
42.0 0.93842 0.93107 0.92729 0.92344 0.93272 0.93001
43.0 0.93639 0.92897 0.92516 0.92128 0.93062 0.92787
44.0 0.93433 0.92685 0.92301 0.91910 0.92849 0.92571
45.0 0.93226 0.92472 0.92085 0.91692 0.92636 0.92355
45.31 53.00 42.07 0.92406
46.0 0.93017 0.92257 0.91868 0.91472 0.92421 0.92137
46.3 53.8 0.92193 –33.9 °C
47.0 0.92806 0.92041 0.91649 0.91250 0.92204 0.91917
48.0 0.92593 0.91823 0.91429 0.91028 0.91986 0.91697
49.0 0.92379 0.91604 0.91208 0.90805 0.91766 0.91475
50.0 0.92162 0.91384 0.90985 0.90580 0.91546 0.91251
50.16 58.0 46.04 0.91349
51.0 0.91943 0.91160 0.90760 0.90353 0.91322 0.91026
52.0 0.91723 0.90936 0.90524 0.90125 0.91097 0.90799
53.0 0.91502 0.90711 0.90307 0.89896 0.90872 0.90571
54.0 0.91279 0.90485 0.90079 0.89667 0.90645 0.90343
55.0 0.91055 0.90258 0.89850 0.89437 0.90418 0.90113
55.16 63.0 50.00 0.90220
56.0 0.90831 0.90031 0.89621 0.89206 0.90191 0.89833
56.1 63.6 0.90008 –41.0 °C
57.0 0.90607 0.89803 0.89392 0.88975 0.89962 0.89654
58.0 0.90381 0.89574 0.89162 0.88744 0.89733 0.89423
59.0 0.90154 0.89344 0.88931 0.88512 0.89502 0.89191
60.0 0.89927 0.89113 0.88699 0.88278 0.89271 0.88959
60.33 68.0 53.98 0.89038
61.0 0.89898 0.88882 0.88466 0.88044 0.89040 0.88725
62.0 0.89468 0.88650 0.88233 0.87809 0.88807 0.88491
63.0 0.89237 0.88417 0.87998 0.87574 0.88574 0.88256
64.0 0.89006 0.88183 0.87763 0.87337 0.88339 0.88020
65.0 0.88774 0.87948 0.87527 0.87100 0.88104 0.87783
66.0 0.88541 0.87713 0.87291 0.86863 0.87869 0.87547
67.0 0.88308 0.87477 0.87054 0.86625 0.87632 0.87309
68.0 0.88071 0.87241 0.86817 0.86387 0.87396 0.87071
69.0 0.87839 0.87004 0.86579 0.86148 0.87158 0.86833
70.0 0.87602 0.86766 0.86340 0.85908 0.86920 0.86593
71.0 0.87365 0.86527 0.86100 0.85667 0.86680 0.86352
71.9 78.3 0.86311 –51.3 °C
72.0 0.87127 0.86287 0.85859 0.85426 0.86440 0.86110
73.0 0.86888 0.86047 0.85618 0.85184 0.86200 0.85869
74.0 0.86648 0.85806 0.85376 0.84941 0.85958 0.85626
75.0 0.86408 0.85564 0.85135 0.84698 0.85716 0.85383
76.0 0.86168 0.85322 0.84891 0.84455 0.85473 0.85140
77.0 0.85927 0.85079 0.84647 0.84211 0.85230 0.84895
78.0 0.85685 0.84835 0.84403 0.83966 0.84985 0.84650
79.0 0.85422 0.84590 0.84158 0.83720 0.84740 0.84404
80.0 0.85197 0.84344 0.83911 0.83473 0.84494 0.84157
81.0 0.84950 0.84096 0.83664 0.83224 0.84245 0.83909
82.0 0.84702 0.83848 0.83415 0.82974 0.83997 0.83659
83.0 0.84453 0.83599 0.83164 0.82724 0.83747 0.83408
84.0 0.84203 0.83348 0.82913 0.82473 0.83496 0.83156
85.0 0.83951 0.83095 0.82660 0.82220 0.83242 0.82902
86.0 0.83697 0.82840 0.82405 0.81965 0.82987 0.82646
87.0 0.83441 0.82554 0.82148 0.81708 0.82729 0.82389
88.0 0.83181 0.82323 0.81888 0.81448 0.82469 0.82128
89.0 0.82919 0.82062 0.81626 0.81186 0.82207 0.81865
90.0 0.82654 0.81797 0.81362 0.80922 0.81942 0.81600
91.00 94.00 74.62 0.82386 0.81529 0.81094 0.80655 0.81674 0.81331
92.0 0.82114 0.81257 0.80823 0.80384 0.81401 0.81060
93.0 0.81839 0.80983 0.80549 0.80111 0.81127 0.80785
94.0 0.81561 0.80705 0.80272 0.79835 0.80848 0.80507
95.0 0.81278 0.80424 0.79991 0.79555 0.80567 0.80225
96.0 0.80991 0.80138 0.79706 0.79271 0.80280 0.79939
97.0 0.80698 0.79846 0.79415 0.78981 0.79988 0.79648
98.0 0.80399 0.79547 0.79117 0.78684 0.79688 0.79349
99.0 0.80094 0.79243 0.78814 0.78382 0.79383 0.79045
100.0 100.0 79.39 0.79784 0.78934 0.78506 0.78075 0.79074 0.78736 −114.3 °C
% wt
ethanol
% vol
ethanol
grams
ethanol
per 100 cc
15.56 °C
d 10 °C/4 °C d 20 °C/4 °C d 25 °C/4 °C d 30 °C/4 °C d 20 °C/20 °C d 25 °C/25 °C freezing
temp.

Boiling points of aqueous solutions

Data obtained from CRC Handbook of Chemistry 44th ed., p2391

BP °C Weight % ethanol     BP °C Weight % ethanol
liquid vapor liquid vapor
78.1 95.5 95.5    
78.2 91 92 86.5 18 71
78.4 85 89 87.0 17 70
78.6 82 88 87.5 16 69
78.8 80 87 88.0 15 68
79.0 78 86 88.5 13 67
79.2 76 85 89.0 12 65
79.4 74 85 89.5 11 63
79.6 72 84 90.0 10 61
79.8 69 84 90.5 10 59
80.0 67 83 91.0 9 57
80.2 64 83 91.5 8 55
80.4 62 82 92.0 8 53
80.6 59 82 92.5 7 51
80.8 56 81 93.0 6 49
81.0 53 81 93.5 6 46
81.2 50 80 94.0 5 44
81.4 47 80 94.5 5 42
81.6 45 80 95.0 4 39
81.8 43 79 95.5 4 36
82.0 41 79 96.0 3 33
82.5 36 78 96.5 3 30
83.0 33 78 97.0 2 27
83.5 30 77 97.5 2 23
84.0 27 77 98.0 1 19
84.5 25 75 98.5 1 15
85.0 23 74 99.0 < 1 10
85.5 21 73 99.5 < 1 5
86.0 20 72 100.0 0 0

Azeotropic mixture

References

  1. NMR-002: Sample Devices and Magnetic Susceptibility
  2. Template:Cite web
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  4. 4.0 4.1 Lange's Handbook of Chemistry 10th ed, pp 1525-1528
  5. 5.0 5.1 CRC Handbook of Chemistry and Physics 44th ed. pp 2582-2584
  6. Lange's Handbook of Chemistry 10th ed, pp 1522-1524
  7. Template:Cite web