Image-based modeling and rendering: Difference between revisions

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m →‎Light modeling: clean up, typos fixed: wave length → wavelength using AWB
 
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The '''Swain equation''' relates the [[kinetic isotope effect]] for the [[Hydrogen-1|protium]]/[[tritium]] combination with that of the [[Hydrogen-1|protium]]/[[deuterium]] combination according to:
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:<math>\frac{k_H}{k_T} =  (\frac{k_H}{k_D})^{1.442}</math>
 
where k<sub>H,D,T</sub> are the [[reaction rate constant]]s for the protonated, deuterated and tritiated reactants respectively.
 
== External links ==
# [http://emsp.em.doe.gov/EMSPprojects1996_2002/completed/55103.pdf Applied Swain equation]
 
== References ==
# ''Use of Hydrogen Isotope Effects to Identify the Attacking Nucleophile in the Enolization of Ketones Catalyzed by Acetic Acid'' C. Gardner Swain, Edward C. Stivers, Joseph F. Reuwer, Jr. Lawrence J. Schaad; [[J. Am. Chem. Soc.]]; '''1958'''; 80(21); 5885-5893. [http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/1958/80/i21/f_ja01554a077.pdf First Page]
 
[[Category:Chemical kinetics]]
[[Category:Equations]]

Latest revision as of 06:13, 13 December 2014

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