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{{Unreferenced|date=July 2009}}
[[File:Bingham_mayo.jpg|thumb|right|302px|[[Mayonnaise]] is a Bingham plastic. The surface has ridges and peaks because Bingham plastics mimic solids under low shear stresses.]]
In [[quantum mechanics]], the case of a '''particle in a one-dimensional ring''' is similar to the [[particle in a box]]. The [[Schrödinger equation]] for a [[free particle]] which is restricted to a ring (technically, whose [[configuration space]] is the [[circle]] <math>S^1</math>) is
A '''Bingham plastic''' is a [[viscoplastic]] material that behaves as a rigid body at low stresses but flows as a [[viscosity|viscous]] [[fluid]] at high stress. It is named after [[Eugene C. Bingham]] who proposed its mathematical form.<ref>E.C. Bingham,(1916) ''U.S. Bureau of Standards Bulletin'', 13, 309-353 "An Investigation of the Laws of Plastic Flow"</ref>


:<math> -\frac{\hbar^2}{2m}\nabla^2 \psi = E\psi </math>
It is used as a common [[mathematical model]] of [[mud]] flow in [[drilling engineering]], and in the handling of [[slurry|slurries]]. A common example is [[toothpaste]],<ref name=Steffe>J. F. Steffe (1996) ''Rheological Methods in Food Process Engineering'' 2nd ed ISBN 0-9632036-1-4</ref> which will not be [[extruded]] until a certain [[pressure]] is applied to the tube. It then is pushed out as a solid plug.


== Wave function ==
==Explanation==
[[File:Bingham1a.svg|thumb|left|302px|Figure 1. Bingham Plastic flow as described by Bingham]]
'''Figure 1''' shows a graph of the behaviour of an ordinary viscous (or Newtonian) fluid in red, for example in a pipe. If the pressure at one end of a pipe is increased this produces a stress on the fluid tending to make it move (called the [[shear stress]]) and the volumetric flow rate increases proportionally. However for a Bingham Plastic fluid (in blue), stress can be applied but it will not flow until a certain value, the [[yield stress]], is reached. Beyond this point the flow rate increases steadily with increasing shear stress. This is roughly the way in which Bingham presented his observation, in an experimental study of paints.<ref>E. C. Bingham (1922) ''Fluidity and Plasticity'' McGraw-Hill (New York) page 219</ref> These properties allow a Bingham plastic to have a textured surface with peaks and ridges instead of a featureless surface like a Newtonian fluid.
[[File:Bingham2a.svg|thumb|right|302px|Figure 2. Bingham Plastic flow as described currently]]
'''Figure 2''' shows the way in which it is normally presented currently.<ref name=Steffe/> The graph shows [[shear stress]] on the vertical axis and [[shear rate]] on the horizontal one. (Volumetric flow rate depends on the size of the pipe, shear rate is a measure of how the velocity changes with distance. It is proportional to flow rate, but does not depend on pipe size.) As before, the Newtonian fluid flows and gives a shear rate for any finite value of shear stress. However, the Bingham Plastic again does not exhibit any shear rate (no flow and thus no velocity) until a certain stress is achieved. For the Newtonian fluid the slope of this line is the [[viscosity]], which is the only parameter needed to describe its flow. By contrast the Bingham Plastic requires two parameters, the '''yield stress''' and the slope of the line, known as the '''plastic viscosity'''.


Using [[polar coordinates]] on the 1-dimensional ring, the [[wave function]] depends only on the [[angle|angular]] [[coordinate]], and so
The physical reason for this behaviour is that the liquid contains particles (e.g. clay) or large molecules (e.g. polymers) which have some kind of interaction, creating a weak solid structure, formerly known as a '''false body''', and a certain amount of stress is required to break this structure. Once the structure has been broken, the particles move with the liquid under viscous forces. If the stress is removed, the particles associate again.


:<math> \nabla^2 = \frac{1}{r^2} \frac{\partial^2}{\partial \theta^2} </math>
==Definition==
The material is rigid for [[shear stress]] ''τ'', less than a critical value <math>\tau_0</math>. Once the critical shear [[shear stress|stress]] (or "[[yield (engineering)|yield stress]]") is exceeded, the material flows in such a way that the [[shear rate]], ∂''u''/∂''y'' (as defined in the article on [[viscosity]]), is directly proportional to the amount by which the applied shear stress exceeds the yield stress:


Requiring that the wave function be [[periodic function|periodic]] in <math> \ \theta </math> with a period <math> 2 \pi</math> (from the demand that the wave functions be single-valued [[function (mathematics)|function]]s on the [[circle]]), and that they be [[normalizing constant|normalized]] leads to the conditions
:<math>\frac {\partial u} {\partial y} = \left\{\begin{matrix} 0 &, \tau < \tau_0 \\ (\tau - \tau_0)/ {\mu} &, \tau \ge \tau_0 \end{matrix}\right.</math>


:<math> \int_{0}^{2 \pi} \left| \psi ( \theta ) \right|^2 \, d\theta = 1\ </math>,
==Friction Factor Formulae==
In fluid flow, it is a common problem to calculate the pressure drop in an established piping network.<ref>{{Cite book| title=Chemical Engineering Fluid Mechanics. | first1=Ron | last1=Darby | publisher=Marcel Dekker | year=1996 | isbn=0-8247-0444-4| postscript=<!--None--> }}. See Chapter 6.</ref> Once the friction factor, ''f'', is known, it becomes easier to handle different pipe-flow problems, viz. calculating the pressure drop for evaluating pumping costs or to find the flow-rate in a piping network for a given pressure drop. It is usually extremely difficult to arrive at exact analytical solution to calculate the friction factor associated with flow of non-Newtonian fluids and therefore explicit approximations are used to calculate it. Once the friction factor has been calculated the pressure drop can be easily determined for a given flow by the [[Darcy–Weisbach equation]]:
:<math> \ f = \ {2 h_f g D \over L V^2}</math>


and
where:
* <math>{\bold \ h_f}</math> is the frictional head loss  ([[SI units]]: m)
* <math>{\bold \ f}</math> is the friction factor  ([[SI units]]: Dimensionless)
* <math>{\bold \ L}</math> is the pipe length  ([[SI units]]: m)
* <math>{\bold \ g}</math> is the gravitational acceleration  ([[SI units]]: m/s²)
* <math>{\bold \ D}</math> is the pipe diameter  ([[SI units]]: m)
* <math>{\bold \ V}</math> is the mean fluid velocity  ([[SI units]]: m/s)


:<math> \ \psi (\theta) = \ \psi ( \theta + 2\pi)</math>
===Laminar flow===
An exact description of friction loss for Bingham plastics in fully developed laminar pipe flow was first published by Buckingham.<ref>Buckingham, E. (1921). "on Plastic Flow through Capillary Tubes". ''ASTM Proceedings'' '''21''': 1154–1156.</ref> His expression, the ''Buckingham-Reiner'' equation, can be written in a dimensionless form as follows:
:<math> \ f_L = \ {64 \over Re}\left[1 + {He\over 6 Re} - {64\over3}\left({He^4\over {f_L}^3 Re^7}\right)\right]</math>


Under these conditions, the solution to the Schrödinger equation is given by
where:
* <math>{\bold \ f_L}</math> is the laminar flow friction factor  ([[SI units]]: Dimensionless)
* <math>{\bold \ Re}</math> is the [[Reynolds number]]  ([[SI units]]: Dimensionless)
* <math>{\bold \ He}</math> is the Hedstrom number  ([[SI units]]: Dimensionless)


:<math> \psi_{\pm}(\theta) = \frac{1}{\sqrt{2 \pi}}\, e^{\pm i \frac{r}{\hbar} \sqrt{2 m E} \theta } </math>
The [[Reynolds number]] and the Hedstrom number are respectively defined as:
:<math> \mathrm{Re} = {D {\ V} \over {\nu_\infty}} </math>, and


== Energy eigenvalues ==
:<math> \mathrm{He} = {\ D^2 {\tau_o} \over {\rho{\nu_\infty}^2}} </math>


The [[energy]] [[eigenvalue]]s <math> E </math> are [[quantization (physics)|quantize]]d because of the periodic [[boundary condition]]s, and they are required to satisfy
where:
* <math>{\bold \rho}</math> is the mass density of fluid  ([[SI units]]: kg/m<sup>3</sup>)
* <math>{\bold \ \nu_\infty}</math> is the kinematic [[viscosity]] of fluid  ([[SI units]]: m²/s)


:<math> e^{\pm i \frac{r}{\hbar} \sqrt{2 m E} \theta } =  e^{\pm i \frac{r}{\hbar} \sqrt{2 m E} (\theta +2 \pi)}</math>, or
===Turbulent flow===
:<math> e^{\pm i 2 \pi \frac{r}{\hbar} \sqrt{2 m E} } = 1 = e^{i 2 \pi n}</math>
Darby and Melson developed an empirical expression that determines the friction factor for turbulent-flow regime of Bingham plastic fluids, and is given by:<ref name=Darby>Darby, R. and Melson J.(1981). "How to predict the friction factor for flow of Bingham plastics". ''Chemical Engineering'' '''28''': 59–61.</ref>
:<math> \ f_T = \ {10^a} \ {Re^{-0.193}} </math>
where:
* <math>{\bold \ f_T}</math> is the turbulent flow friction factor  ([[SI units]]: Dimensionless)
* <math> \ a = -1.378\left[1 + 0.146{\ e^{-2.9\times {10^{-5}}}Re}\right] </math>


The eigenfunction and eigenenergies are
==Approximations of the ''Buckingham-Reiner'' equation==
:<math> \psi(\theta) = \frac{1}{\sqrt{2 \pi }} \, e^{\pm i n \theta }</math>
Although an exact analytical solution of the ''Buckingham-Reiner'' equation can be obtained because it is a fourth order polynomial equation in ''f'', due to complexity of the solution it is rarely employed. Therefore, researchers have tried to develop explicit approximations for the ''Buckingham-Reiner'' equation.
:<math> E_n = \frac{n^2 \hbar^2}{2 m r^2} </math> where <math>n = 0,\pm 1,\pm 2,\pm 3, \ldots</math>


Therefore, there are two degenerate [[quantum state]]s for every value of <math> n>0 </math> (corresponding to <math> \ e^{\pm i n \theta}</math>). Therefore there are 2n+1 states with energies up to an energy indexed by the number n.
===Swamee-Aggarwal Equation===
The ''Swamee Aggarwal'' equation is used to solve directly for the Darcy–Weisbach friction factor ''f'' for laminar flow of Bingham plastic fluids.<ref>Swamee, P.K. and Aggarwal, N.(2011). "Explicit equations for laminar flow of Bingham plastic fluids". ''Journal of Petroleum Science and Engineering''. {{doi|10.1016/j.petrol.2011.01.015}}.</ref> It is an approximation of the implicit ''Buckingham-Reiner'' equation, but the discrepancy from experimental data is well within the accuracy of the data.
The ''Swamee-Aggarwal'' equation is given by:
:<math> \ f_L = \ {64 \over Re}  + {10.67 + 0.1414{({He\over Re})^{1.143}}\over {\left[1 + 0.0149{({He\over Re})^{1.16}}\right]Re  }}\left({He\over Re}\right)</math>


The case of a particle in a one-dimensional ring is an instructive example when studying the [[quantization (physics)|quantization]] of [[angular momentum]] for, say, an [[electron]] orbiting the [[Atomic nucleus|nucleus]]. The [[azimuth]]al wave functions in that case are identical to the energy [[eigenfunction]]s of the particle on a ring.
===Danish-Kumar Solution===
Danish ''et al.'' have provided an explicit procedure to calculate the friction factor ''f'' by using the Adomian decomposition method.<ref>Danish, M. ''et al.'' (1981). "Approximate explicit analytical expressions of friction factor for flow
of Bingham fluids in smooth pipes using Adomian decomposition method". ''Communications in Nonlinear Science and Numerical Simulation'' '''16''': 239–251.</ref> The friction factor containing two terms through this method is given as:
:<math> f_L = \frac{K_1 + \dfrac{4 K_2}{\left( K_1 + \frac{K_1 K_2}{K_1^4 + 3 K_2}\right)^3}}{1+ \dfrac{3 K_2}{\left(K_1 + \frac{K_1 K_2}{K_1^4 + 3 K_2}\right)^4}}</math>
where:
:<math> \ K_1 = \ {16 \over Re} + {16 He \over 6{Re^2}}</math>, and
:<math> \ K_2 = \ - {16 {He^4} \over 3{Re^8}}</math>


The statement that any wavefunction for the particle on a ring can be written as a [[quantum superposition|superposition]] of [[energy]] [[eigenfunction]]s is exactly identical to the [[Fourier theorem]] about the development of any periodic [[function (mathematics)|function]] in a [[Fourier series]].
==Combined Equation for friction factor for all flow regimes==
===Darby-Melson Equation===
In 1981, Darby and Melson, using the approach of Churchill<ref>Churchill, S.W. (1977). "Friction factor equation spans all fluid-flow regimes". ''Chemical Engineering'' '''Nov. 7''': 91–92.</ref> and of Churchill and Usagi,<ref>Churchill, S.W. and Usagi, R.A. (1972). "A general expression for the correlation of rates of transfer and other phenomena". ''AIChE Journal'' '''18(6)''': 1121-1128.</ref> developed an expression to get a single friction factor equation valid for all flow regimes:<ref name=Darby/>
:<math> \ f = \ {\left[{f_L}^m + {f_T}^m\right]}^{1\over m}</math>
where:
:<math> \ m = \ 1.7 + {40000\over Re} </math>


This simple model can be used to find approximate energy levels of some ring molecules, such as benzene.
Both ''Swamee-Aggarwal'' equation and the ''Darby-Melson'' equation can be combined to give an explicit equation for determining the friction factor of Bingham plastic fluids in any regime. Relative roughness is not a parameter in any of the equations because the friction factor of Bingham plastic fluids is not sensitive to pipe roughness.


== Application ==
==References==
{{reflist}}


In [[organic chemistry]], [[aromatic]] compounds contain atomic rings, such as [[benzene]] rings (the [[Friedrich August Kekulé von Stradonitz|Kekulé]] structure) consisting  of five or six, usually [[carbon]], atoms. So does the surface of "[[Buckyball (molecule)|buckyballs]]" (buckminsterfullerene). These molecules are exceptionally stable.
{{DEFAULTSORT:Bingham Plastic}}
[[Category:Materials]]
[[Category:Non-Newtonian fluids]]
[[Category:Viscosity]]
[[Category:Offshore engineering]]


The above explains why the ring behaves like a circular [[waveguide]], with the valence electrons orbiting in both directions.
[[bs:Binghamova plastika]]
 
[[de:Bingham-Fluid]]
To fill all energy levels up to n requires <math>2\times(2n+1)</math> electrons, as electrons have additionally two possible orientations of their spins.
[[fa:پلاستیک بینگهام]]
 
[[fr:Fluide de Bingham]]
The rule that <math>4n+2</math> excess electrons in the ring produces an exceptionally stable ("aromatic") compound, is known as the [[Hückel's rule]].
[[nl:Bingham plastic]]
 
[[zh:宾汉流体]]
Further in rotational spectroscopy this model may be used as an approximation of rotational energy levels.
 
== See also ==
 
* [[Angular momentum]]
* [[Harmonic analysis]]
* [[One-dimensional periodic case]]
 
{{DEFAULTSORT:Particle In A Ring}}
[[Category:Quantum models]]

Revision as of 04:35, 12 August 2014

Mayonnaise is a Bingham plastic. The surface has ridges and peaks because Bingham plastics mimic solids under low shear stresses.

A Bingham plastic is a viscoplastic material that behaves as a rigid body at low stresses but flows as a viscous fluid at high stress. It is named after Eugene C. Bingham who proposed its mathematical form.[1]

It is used as a common mathematical model of mud flow in drilling engineering, and in the handling of slurries. A common example is toothpaste,[2] which will not be extruded until a certain pressure is applied to the tube. It then is pushed out as a solid plug.

Explanation

Figure 1. Bingham Plastic flow as described by Bingham

Figure 1 shows a graph of the behaviour of an ordinary viscous (or Newtonian) fluid in red, for example in a pipe. If the pressure at one end of a pipe is increased this produces a stress on the fluid tending to make it move (called the shear stress) and the volumetric flow rate increases proportionally. However for a Bingham Plastic fluid (in blue), stress can be applied but it will not flow until a certain value, the yield stress, is reached. Beyond this point the flow rate increases steadily with increasing shear stress. This is roughly the way in which Bingham presented his observation, in an experimental study of paints.[3] These properties allow a Bingham plastic to have a textured surface with peaks and ridges instead of a featureless surface like a Newtonian fluid.

Figure 2. Bingham Plastic flow as described currently

Figure 2 shows the way in which it is normally presented currently.[2] The graph shows shear stress on the vertical axis and shear rate on the horizontal one. (Volumetric flow rate depends on the size of the pipe, shear rate is a measure of how the velocity changes with distance. It is proportional to flow rate, but does not depend on pipe size.) As before, the Newtonian fluid flows and gives a shear rate for any finite value of shear stress. However, the Bingham Plastic again does not exhibit any shear rate (no flow and thus no velocity) until a certain stress is achieved. For the Newtonian fluid the slope of this line is the viscosity, which is the only parameter needed to describe its flow. By contrast the Bingham Plastic requires two parameters, the yield stress and the slope of the line, known as the plastic viscosity.

The physical reason for this behaviour is that the liquid contains particles (e.g. clay) or large molecules (e.g. polymers) which have some kind of interaction, creating a weak solid structure, formerly known as a false body, and a certain amount of stress is required to break this structure. Once the structure has been broken, the particles move with the liquid under viscous forces. If the stress is removed, the particles associate again.

Definition

The material is rigid for shear stress τ, less than a critical value . Once the critical shear stress (or "yield stress") is exceeded, the material flows in such a way that the shear rate, ∂u/∂y (as defined in the article on viscosity), is directly proportional to the amount by which the applied shear stress exceeds the yield stress:

Friction Factor Formulae

In fluid flow, it is a common problem to calculate the pressure drop in an established piping network.[4] Once the friction factor, f, is known, it becomes easier to handle different pipe-flow problems, viz. calculating the pressure drop for evaluating pumping costs or to find the flow-rate in a piping network for a given pressure drop. It is usually extremely difficult to arrive at exact analytical solution to calculate the friction factor associated with flow of non-Newtonian fluids and therefore explicit approximations are used to calculate it. Once the friction factor has been calculated the pressure drop can be easily determined for a given flow by the Darcy–Weisbach equation:

where:

Laminar flow

An exact description of friction loss for Bingham plastics in fully developed laminar pipe flow was first published by Buckingham.[5] His expression, the Buckingham-Reiner equation, can be written in a dimensionless form as follows:

where:

The Reynolds number and the Hedstrom number are respectively defined as:

, and

where:

Turbulent flow

Darby and Melson developed an empirical expression that determines the friction factor for turbulent-flow regime of Bingham plastic fluids, and is given by:[6]

where:

Approximations of the Buckingham-Reiner equation

Although an exact analytical solution of the Buckingham-Reiner equation can be obtained because it is a fourth order polynomial equation in f, due to complexity of the solution it is rarely employed. Therefore, researchers have tried to develop explicit approximations for the Buckingham-Reiner equation.

Swamee-Aggarwal Equation

The Swamee Aggarwal equation is used to solve directly for the Darcy–Weisbach friction factor f for laminar flow of Bingham plastic fluids.[7] It is an approximation of the implicit Buckingham-Reiner equation, but the discrepancy from experimental data is well within the accuracy of the data. The Swamee-Aggarwal equation is given by:

Danish-Kumar Solution

Danish et al. have provided an explicit procedure to calculate the friction factor f by using the Adomian decomposition method.[8] The friction factor containing two terms through this method is given as:

where:

, and

Combined Equation for friction factor for all flow regimes

Darby-Melson Equation

In 1981, Darby and Melson, using the approach of Churchill[9] and of Churchill and Usagi,[10] developed an expression to get a single friction factor equation valid for all flow regimes:[6]

where:

Both Swamee-Aggarwal equation and the Darby-Melson equation can be combined to give an explicit equation for determining the friction factor of Bingham plastic fluids in any regime. Relative roughness is not a parameter in any of the equations because the friction factor of Bingham plastic fluids is not sensitive to pipe roughness.

References

43 year old Petroleum Engineer Harry from Deep River, usually spends time with hobbies and interests like renting movies, property developers in singapore new condominium and vehicle racing. Constantly enjoys going to destinations like Camino Real de Tierra Adentro.

bs:Binghamova plastika de:Bingham-Fluid fa:پلاستیک بینگهام fr:Fluide de Bingham nl:Bingham plastic zh:宾汉流体

  1. E.C. Bingham,(1916) U.S. Bureau of Standards Bulletin, 13, 309-353 "An Investigation of the Laws of Plastic Flow"
  2. 2.0 2.1 J. F. Steffe (1996) Rheological Methods in Food Process Engineering 2nd ed ISBN 0-9632036-1-4
  3. E. C. Bingham (1922) Fluidity and Plasticity McGraw-Hill (New York) page 219
  4. 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.

    My blog: http://www.primaboinca.com/view_profile.php?userid=5889534. See Chapter 6.
  5. Buckingham, E. (1921). "on Plastic Flow through Capillary Tubes". ASTM Proceedings 21: 1154–1156.
  6. 6.0 6.1 Darby, R. and Melson J.(1981). "How to predict the friction factor for flow of Bingham plastics". Chemical Engineering 28: 59–61.
  7. Swamee, P.K. and Aggarwal, N.(2011). "Explicit equations for laminar flow of Bingham plastic fluids". Journal of Petroleum Science and Engineering. 21 year-old Glazier James Grippo from Edam, enjoys hang gliding, industrial property developers in singapore developers in singapore and camping. Finds the entire world an motivating place we have spent 4 months at Alejandro de Humboldt National Park..
  8. Danish, M. et al. (1981). "Approximate explicit analytical expressions of friction factor for flow of Bingham fluids in smooth pipes using Adomian decomposition method". Communications in Nonlinear Science and Numerical Simulation 16: 239–251.
  9. Churchill, S.W. (1977). "Friction factor equation spans all fluid-flow regimes". Chemical Engineering Nov. 7: 91–92.
  10. Churchill, S.W. and Usagi, R.A. (1972). "A general expression for the correlation of rates of transfer and other phenomena". AIChE Journal 18(6): 1121-1128.