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{{Redirect|Ubh}}
In mathematics, the '''spectrum of a [[C*-algebra]]''' or '''dual of a C*-algebra''' ''A'', denoted ''Â'', is the set of [[unitary equivalence]] classes of  [[irreducible representation|irreducible]] *-representations of ''A''. A [[*-representation]] π of ''A'' on a [[Hilbert space]] ''H'' is '''irreducible''' if, and only if, there is no closed subspace ''K'' different from ''H'' and {0} which is invariant under all operators π(''x'') with ''x'' ∈ ''A''. We implicitly assume that irreducible representation means ''non-null'' irreducible representation, thus excluding trivial (i.e. identically 0) representations on one-[[dimension]]al [[space (mathematics)|spaces]]. As explained below, the spectrum ''Â'' is also naturally a [[topological space]]; this generalizes the notion of the [[spectrum of a ring]].
{{Infobox unbihexium}}
'''Unbihexium''' ({{IPAc-en|icon|ˌ|uː|n|b|aɪ|ˈ|h|ɛ|k|s|i|ə|m}}), also known as '''[[Mendeleev's predicted elements|eka]]-[[plutonium]]''' or element 126, is a hypothetical [[chemical element]] with [[atomic number]] 126 and symbol Ubh. It is of interest because of its location at the peak of the hypothesized [[island of stability]].


==History==
One of the most important applications of this concept is to provide a notion of [[duality (mathematics)|dual]] object for any [[locally compact group]].  This dual object is suitable for formulating a [[Fourier transform]] and a [[Plancherel theorem]] for [[unimodular group|unimodular]] [[separable space|separable]] locally compact groups of type I and a decomposition theorem for arbitrary representations of separable locally compact groups of type I.  The resulting duality theory for locally compact groups is however much weaker than the [[Tannaka–Krein duality]] theory for [[compact topological group]]s or [[Pontryagin duality]] for locally compact ''abelian'' groups, both of which are complete invariants. That the dual is not a complete invariant is easily seen as the  dual of any finite dimensional full matrix algebra M<sub>''n''</sub>('''C''') consists of a single point.
The first attempt to synthesize unbihexium was performed in 1971 by Bimbot ''et al.'' using the hot fusion reaction:


:<math>\,^{232}_{90}\mathrm{Th} + \,^{84}_{36}\mathrm{Kr} \to \,^{316}_{126}\mathrm{Ubh} ^{*} \to \  no \ atoms</math>
== Primitive spectrum ==


A high energy [[alpha particle]] was observed and taken as possible evidence for the synthesis of unbihexium. Recent research{{which?|date=October 2011}} suggests that this is highly unlikely as the sensitivity of experiments performed in 1971 would have been several orders of magnitude too low according to current understanding.
The [[topology]] of ''Â''  can be defined in several equivalent ways. We first define it in terms of the '''primitive spectrum''' .


To date, no other attempt has been made to synthesize unbihexium.
The primitive spectrum of ''A'' is the set of [[primitive ideal]]s Prim(''A'') of ''A'', where  a primitive ideal is the kernel of an irreducible *-representation. The set of primitive ideals is a [[topological space]] with the '''hull-kernel topology''' (or '''Jacobson topology''').  This is defined as follows: If ''X'' is a set of primitive ideals, its '''hull-kernel closure''' is


==Target-projectile combinations leading to Z=126 compound nuclei==
:<math> \overline{X} = \{\rho \in \operatorname{Prim}(A): \rho \supseteq \bigcap_{\pi \in X} \pi\}. </math>
The table below contains various combinations of targets and projectiles which could be used to form compound nuclei with Z=126. The only practical [[isotope]]s of unbihexium that would be considerably longer-lived than others are <sup>310</sup>Ubh and <sup>322</sup>Ubh.


{|class="wikitable" style="text-align:center"
Hull-kernel closure is easily shown to be an [[idempotent]] operation, that is
!Target!!Projectile!!CN!!Attempt result
|-
!<sup>232</sup>Th
|<sup>84</sup>Kr||<sup>316</sup>Ubh||{{No|Failure to date}}
|}


Another way to synthesize unbihexium would be to overshoot it by fusion of <sup>130</sup>Te and <sup>204</sup>Hg; successive alpha decay of the compound nucleus <sup>334</sup>Utb would land right on <sup>322</sup>Ubh (predicted to be relatively stable). <sup>130</sup>Te constitutes about 34% of the natural element; however, <sup>204</sup>Hg only constitutes about 7% of natural mercury. This method of synthesis could also be used to synthesize <sup>298</sup>[[Flerovium|Fl]], after the alpha decay of <sup>322</sup>Ubh.
:<math> \overline{\overline{X}} = \overline{X},</math>


==Stable unbihexium==
and it can be shown to satisfy the [[Kuratowski closure axioms]]. As a consequence, it can be shown that there is a unique topology &tau; on Prim(''A'')  such that the closure of a set ''X'' with  respect to &tau; is identical to the hull-kernel closure of ''X''.
Calculations according to the [[Hartree-Fock method|Hartree-Fock]]-Bogoliubov Method using the non-relativistic Skyrme interaction have proposed Z=126 as a [[nuclear shell model|closed proton shell]]. In this region of the periodic table, N=184 and N=196 have been suggested as [[nuclear shell model|closed neutron shell]]s. Therefore the isotopes of most interest are <sup>310</sup>Ubh and <sup>322</sup>Ubh, for these might be considerably longer-lived than other isotopes.


==Predicted chemistry==
Since unitarily equivalent representations have the same kernel, the map &pi; {{mapsto}} ker(&pi;) factors through a [[surjective]] map
Unbihexium is predicted to belong to a new block of [[Valence electron|valence]] g-electron atoms, although the g-block's position left of the [[f-block]] is speculative. The expected electron configuration is [Uuo]5[[g-orbital|g]]<sup>6</sup> 8[[s-orbital|s]]<sup>2</sup> although there may be a smearing out of the energies of 5g, 6f and 7[[d-orbital|d]] orbitals.


Recent calculations have suggested a stable [[Fluoride|monofluoride]] UbhF may be possible, resulting from a bonding interaction between the 5g [[Atomic orbital|orbital]] on Ubh and the 2[[p-orbital|p]] orbital on [[fluorine]].<ref>{{Cite journal|last=Jacoby|first=Mitch|title=As-yet-unsynthesized superheavy atom should form a stable diatomic molecule with fluorine|journal=Chemical & Engineering News|year=2006|volume=84|issue=10|pages=19|url=http://pubs.acs.org/cen/news/84/i10/8410notw9.html|accessdate=2008-01-14}}</ref> Other predicted oxidation states include III, IV, VI, and VIII.
:<math> \operatorname{k}: \hat{A} \rightarrow \operatorname{Prim}(A). </math>


==Unbihexium in popular culture== 
We use the map ''k'' to define the topology on ''Â'' as follows:
The science fiction short story "Silence is Golden" by American science fiction author [[Lou Antonelli]] is based on the supposed discovery of unbihexium in a Texas open-pit mine. The story, published by Revolution Science Fiction in August 2003, received an Honorable Mention in "The Year's Best Science Fiction, 21st annual collection" (St. Martin's Press, New York, N.Y. [[Gardner Dozois]], ed. 2004). 


==See also==
'''Definition'''. The open sets of ''Â'' are inverse images ''k''<sup>&minus;1</sup>(''U'') of open subsets ''U'' of Prim(''A''). This is indeed a topology.
*[[Island of stability]]: [[Flerovium]]–[[Unbinilium]]–Unbihexium
*[[Unbipentium]]–[[Unbiseptium]]
*[[Period 8 element]]


==References==
The hull-kernel topology is an analogue for non-commutative rings of the [[Zariski topology]] for commutative rings.
{{Reflist}}
{{Use dmy dates|date=September 2010}}


{{Compact extended periodic table}}
The topology on ''Â'' induced from the hull-kernel topology has other characterizations in terms of [[state (functional analysis)|state]]s of ''A''.


[[Category:Chemical elements]]
== Examples ==
[[Category:Hypothetical chemical elements]]


[[de:Unbihexium]]
=== Commutative C*-algebras ===
[[el:Ουνμπιχέξιο]]
[[File:3-dim commut algebra, subalgebras, ideals.svg|thumb|left|224px|3-dimensional  commutative C*-algebra and its ideals. Each of 8 ideals corresponds to a closed subset of discrete 3-points space (or to an open complement). Primitive ideals correspond to closed [[singleton (mathematics)|singletons]]. See details at the image description page.]]
[[fr:Unbihexium]]
The spectrum of a commutative C*-algebra ''A'' coincides with the [[Gelfand transformation|usual dual]] of ''A'' (not to be confused with the [[Banach space|dual]] ''A''' of the Banach space ''A'').  In particular, suppose ''X'' is a [[compact space|compact]] [[Hausdorff space]].  Then there is a [[natural transformation|natural]] [[homeomorphism]]
[[ko:운비헥슘]]
 
[[id:Unbiheksium]]
:<math> \operatorname{I}: X \cong \operatorname{Prim}( \operatorname{C}(X)).</math>
[[mrj:Унбигексий]]
 
[[ja:ウンビヘキシウム]]
This mapping is defined by
[[pl:Unbihexium]]
 
[[ru:Унбигексий]]
: <math>  \operatorname{I}(x) = \{f \in \operatorname{C}(X): f(x) = 0 \}.</math>
[[sk:Unbihexium]]
 
[[vi:Unbihexi]]
I(''x'') is a closed maximal ideal in C(''X'') so is in fact primitive. For details of the proof, see the Dixmier reference.  For a commutative C*-algebra,
[[zh:Ubh]]
 
:<math> \hat{A} \cong \operatorname{Prim}(A).</math>
 
=== The C*-algebra of bounded operators ===
 
Let ''H'' be a separable [[Hilbert space]]. ''L''(''H'') has two norm-closed *-ideals: ''I''<sub>0</sub>&nbsp;=&nbsp;{0} and the ideal ''K''&nbsp;=&nbsp;''K''(''H'') of compact operators.  Thus as a set, Prim(''L''(''H'')) =&nbsp;{''I''<sub>0</sub>,&nbsp;''K''}. Now
 
* {''K''} is a closed subset of Prim(''L''(''H'')).
 
* The closure of {''I''<sub>0</sub>} is Prim(''L''(''H'')).
 
Thus Prim(''L''(''H'')) is a non-Hausdorff space.
 
The spectrum of ''L''(''H'') on the other hand is much larger.  There are many inequivalent irreducible representations with kernel ''K''(''H'') or with kernel&nbsp;{0}.
 
=== Finite dimensional C*-algebras ===
 
Suppose ''A'' is a finite dimensional C*-algebra.  It is known ''A'' is isomorphic to a finite direct sum of full matrix algebras:
 
:<math> A \cong \bigoplus_{e \in \operatorname{min}(A)} A e, </math>
 
where min(''A'') are the minimal central projections of ''A''.  The spectrum of ''A'' is canonically isomorphic to min(''A'') with the [[discrete topology]].  For finite dimensional C*-algebras, we also have the isomorphism
 
:<math> \hat{A} \cong \operatorname{Prim}(A).</math>
 
== Other characterizations of the spectrum ==
 
The hull-kernel topology is easy to describe abstractly, but in practice for C*-algebras associated to [[locally compact]] [[topological group]]s, other characterizations of the topology on the spectrum in terms of positive definite functions are desirable.
 
In fact, the topology on ''Â'' is intimately connected with the concept of [[weak containment]] of representations as is shown by the following:
 
'''Theorem'''.  Let ''S'' be subset of ''Â''. Then the following are equivalent for an irreducile representation &pi;
 
# The equivalence class of &pi; in ''Â'' is in the closure of ''S''
# Every state associated to &pi;, that is one of the form
 
::<math> f_\xi(x) = \langle \xi  \mid \pi(x) \xi \rangle </math>
 
:with ||&xi;||=1, is the weak limit of states associated to representations in ''S''.
 
The second condition means exactly that &pi; is weakly contained in ''S''.
 
The [[GNS construction]] is a recipe for associating states of a C*-algebra ''A'' to representations of ''A''.  By one of the basic theorems associated to the GNS construction, a state ''f'' is [[pure state|pure]] if and only if the associated representation &pi;<sub>''f''</sub> is irreducible. Moreover, the mapping &kappa;: PureState(''A'') &rarr; ''Â'' defined by ''f'' {{mapsto}} &pi;<sub>''f''</sub> is a surjective map.
 
From the previous theorem one can easily prove the following;
 
'''Theorem''' The mapping
 
: <math> \kappa: \operatorname{PureState}(A) \rightarrow \hat{A} </math>
 
given by the GNS construction is continuous and open.
 
=== The space Irr<sub>''n''</sub>(''A'') ===
 
There is yet another characterization of the topology on ''Â'' which arises by considering the space of representations as a topological space with an appropriate pointwise convergence topology.  More precisely, let ''n'' be a cardinal number and let ''H''<sub>''n''</sub> be the canonical Hilbert space of dimension ''n''.
 
Irr<sub>''n''</sub>(''A'') is the space of irreducible *-representations of ''A'' on ''H''<sub>''n''</sub> with the point-weak topology.  In terms of convergence of nets, this topology is defined by &pi;<sub>''i''</sub> &rarr; &pi; if and only if
 
:<math> \langle \pi_i(x) \xi \mid \eta \rangle \rightarrow \langle \pi(x) \xi \mid \eta \rangle \quad \forall \xi, \eta \in H_n \ x \in A. </math>
 
It turns out that this topology on Irr<sub>''n''</sub>(''A'') is the same as the point-strong topology, i.e. &pi;<sub>''i''</sub> &rarr; &pi; if and only if
 
:<math> \pi_i(x) \xi  \rightarrow \pi(x) \xi  \quad \mbox{ normwise } \forall \xi \in H_n \ x \in A. </math>
 
'''Theorem'''. Let ''Â''<sub>''n''</sub> be the subset of ''Â'' consisting of equivalence classes of representations whose underlying  Hilbert space has dimension ''n''.  The canonical map Irr<sub>''n''</sub>(''A'') &rarr; ''Â''<sub>''n''</sub> is continuous and open. In particular, ''Â''<sub>''n''</sub> can be regarded as the quotient topological space of Irr<sub>''n''</sub>(''A'') under unitary equivalence.
 
'''Remark'''.  The piecing together of the various ''Â''<sub>''n''</sub> can be quite complicated.
 
== Mackey Borel structure ==
 
''Â'' is a topological space and thus can also be regarded as a [[Borel set|Borel space]].  A famous conjecture of [[G. Mackey]] proposed that a ''separable'' locally compact group is of type I if and only if the Borel space is standard, i.e. is isomorphic (in the category of Borel spaces) to the underlying Borel space of a [[Polish space|complete separable metric space]].  Mackey called Borel spaces with this property '''smooth'''. This conjecture was proved by [[James Glimm]] for separable C*-algebras in the 1961 paper listed in the references below.
 
'''Definition'''.  A non-degenerate *-representation &pi; of a separable C*-algebra ''A'' is a '''factor representation''' if and only if the center of the von Neumann algebra generated by &pi;(''A'') is one-dimensional.  A C*-algebra ''A'' is of type I if and only if any separable factor representation of ''A'' is a finite or countable multiple of an irreducible one.
 
Examples of separable locally compact groups ''G'' such that C*(''G'') is of type I are [[connected space|connected]] (real) [[nilpotent]] [[Lie group]]s and connected real [[semi-simple]] Lie groups.  Thus the [[Heisenberg group]]s are all of type I. Compact and abelian groups are also of type I.
 
'''Theorem'''. If ''A'' is separable, ''Â'' is smooth if and only if ''A'' is of type I.
 
The result implies a far-reaching generalization of the structure of representations of separable type I C*-algebras and correspondingly of separable locally compact groups of type I.
 
== Algebraic primitive spectra  ==
 
Since a C*-algebra ''A'' is a [[ring (mathematics)|ring]], we can also consider the set of [[primitive ideal]]s of ''A'', where ''A'' is regarded algebraically.  For a ring an ideal is primitive if and only if it is the [[Annihilator (ring theory)|annihilator]] of a [[simple module]].  It turns out that for a C*-algebra ''A'', an ideal is algebraically primitive [[if and only if]] it is primitive in the sense defined above.
 
'''Theorem'''.  Let ''A'' be a C*-algebra.  Any algebraically irreducible representation of ''A'' on a complex vector space is algebraically equivalent to a topologically irreducible *-representation on a Hilbert space.  Topologically irreducible *-representations on a Hilbert space are algebraically isomorphic if and only if they are unitarily equivalent.
 
This is the Corollary of Theorem 2.9.5 of the Dixmier reference.
 
If ''G'' is a locally compact group, the topology on dual space of the [[group algebra|group C*-algebra]] C*(''G'') of ''G'' is called the '''Fell topology''', named after [[J. M. G. Fell]].
 
== References ==
* J.  Dixmier, ''Les C*-algèbres et leurs représentations'', Gauthier-Villars, 1969.
* J. Glimm, ''Type I C*-algebras'', Annals of Mathematics, vol 73, 1961.
* G. Mackey, ''The Theory of Group Representations'', The University of Chicago Press, 1955.
 
{{Functional Analysis}}
 
{{DEFAULTSORT:Spectrum of a C-algebra}}
[[Category:C*-algebras]]
[[Category:Spectral theory]]

Revision as of 00:51, 13 August 2014

In mathematics, the spectrum of a C*-algebra or dual of a C*-algebra A, denoted Â, is the set of unitary equivalence classes of irreducible *-representations of A. A *-representation π of A on a Hilbert space H is irreducible if, and only if, there is no closed subspace K different from H and {0} which is invariant under all operators π(x) with xA. We implicitly assume that irreducible representation means non-null irreducible representation, thus excluding trivial (i.e. identically 0) representations on one-dimensional spaces. As explained below, the spectrum  is also naturally a topological space; this generalizes the notion of the spectrum of a ring.

One of the most important applications of this concept is to provide a notion of dual object for any locally compact group. This dual object is suitable for formulating a Fourier transform and a Plancherel theorem for unimodular separable locally compact groups of type I and a decomposition theorem for arbitrary representations of separable locally compact groups of type I. The resulting duality theory for locally compact groups is however much weaker than the Tannaka–Krein duality theory for compact topological groups or Pontryagin duality for locally compact abelian groups, both of which are complete invariants. That the dual is not a complete invariant is easily seen as the dual of any finite dimensional full matrix algebra Mn(C) consists of a single point.

Primitive spectrum

The topology of  can be defined in several equivalent ways. We first define it in terms of the primitive spectrum .

The primitive spectrum of A is the set of primitive ideals Prim(A) of A, where a primitive ideal is the kernel of an irreducible *-representation. The set of primitive ideals is a topological space with the hull-kernel topology (or Jacobson topology). This is defined as follows: If X is a set of primitive ideals, its hull-kernel closure is

Hull-kernel closure is easily shown to be an idempotent operation, that is

and it can be shown to satisfy the Kuratowski closure axioms. As a consequence, it can be shown that there is a unique topology τ on Prim(A) such that the closure of a set X with respect to τ is identical to the hull-kernel closure of X.

Since unitarily equivalent representations have the same kernel, the map π Template:Mapsto ker(π) factors through a surjective map

We use the map k to define the topology on  as follows:

Definition. The open sets of  are inverse images k−1(U) of open subsets U of Prim(A). This is indeed a topology.

The hull-kernel topology is an analogue for non-commutative rings of the Zariski topology for commutative rings.

The topology on  induced from the hull-kernel topology has other characterizations in terms of states of A.

Examples

Commutative C*-algebras

3-dimensional commutative C*-algebra and its ideals. Each of 8 ideals corresponds to a closed subset of discrete 3-points space (or to an open complement). Primitive ideals correspond to closed singletons. See details at the image description page.

The spectrum of a commutative C*-algebra A coincides with the usual dual of A (not to be confused with the dual A' of the Banach space A). In particular, suppose X is a compact Hausdorff space. Then there is a natural homeomorphism

This mapping is defined by

I(x) is a closed maximal ideal in C(X) so is in fact primitive. For details of the proof, see the Dixmier reference. For a commutative C*-algebra,

The C*-algebra of bounded operators

Let H be a separable Hilbert space. L(H) has two norm-closed *-ideals: I0 = {0} and the ideal K = K(H) of compact operators. Thus as a set, Prim(L(H)) = {I0K}. Now

  • {K} is a closed subset of Prim(L(H)).
  • The closure of {I0} is Prim(L(H)).

Thus Prim(L(H)) is a non-Hausdorff space.

The spectrum of L(H) on the other hand is much larger. There are many inequivalent irreducible representations with kernel K(H) or with kernel {0}.

Finite dimensional C*-algebras

Suppose A is a finite dimensional C*-algebra. It is known A is isomorphic to a finite direct sum of full matrix algebras:

where min(A) are the minimal central projections of A. The spectrum of A is canonically isomorphic to min(A) with the discrete topology. For finite dimensional C*-algebras, we also have the isomorphism

Other characterizations of the spectrum

The hull-kernel topology is easy to describe abstractly, but in practice for C*-algebras associated to locally compact topological groups, other characterizations of the topology on the spectrum in terms of positive definite functions are desirable.

In fact, the topology on  is intimately connected with the concept of weak containment of representations as is shown by the following:

Theorem. Let S be subset of Â. Then the following are equivalent for an irreducile representation π

  1. The equivalence class of π in  is in the closure of S
  2. Every state associated to π, that is one of the form
with ||ξ||=1, is the weak limit of states associated to representations in S.

The second condition means exactly that π is weakly contained in S.

The GNS construction is a recipe for associating states of a C*-algebra A to representations of A. By one of the basic theorems associated to the GNS construction, a state f is pure if and only if the associated representation πf is irreducible. Moreover, the mapping κ: PureState(A) → Â defined by f Template:Mapsto πf is a surjective map.

From the previous theorem one can easily prove the following;

Theorem The mapping

given by the GNS construction is continuous and open.

The space Irrn(A)

There is yet another characterization of the topology on  which arises by considering the space of representations as a topological space with an appropriate pointwise convergence topology. More precisely, let n be a cardinal number and let Hn be the canonical Hilbert space of dimension n.

Irrn(A) is the space of irreducible *-representations of A on Hn with the point-weak topology. In terms of convergence of nets, this topology is defined by πi → π if and only if

It turns out that this topology on Irrn(A) is the same as the point-strong topology, i.e. πi → π if and only if

Theorem. Let Ân be the subset of  consisting of equivalence classes of representations whose underlying Hilbert space has dimension n. The canonical map Irrn(A) → Ân is continuous and open. In particular, Ân can be regarded as the quotient topological space of Irrn(A) under unitary equivalence.

Remark. The piecing together of the various Ân can be quite complicated.

Mackey Borel structure

 is a topological space and thus can also be regarded as a Borel space. A famous conjecture of G. Mackey proposed that a separable locally compact group is of type I if and only if the Borel space is standard, i.e. is isomorphic (in the category of Borel spaces) to the underlying Borel space of a complete separable metric space. Mackey called Borel spaces with this property smooth. This conjecture was proved by James Glimm for separable C*-algebras in the 1961 paper listed in the references below.

Definition. A non-degenerate *-representation π of a separable C*-algebra A is a factor representation if and only if the center of the von Neumann algebra generated by π(A) is one-dimensional. A C*-algebra A is of type I if and only if any separable factor representation of A is a finite or countable multiple of an irreducible one.

Examples of separable locally compact groups G such that C*(G) is of type I are connected (real) nilpotent Lie groups and connected real semi-simple Lie groups. Thus the Heisenberg groups are all of type I. Compact and abelian groups are also of type I.

Theorem. If A is separable, Â is smooth if and only if A is of type I.

The result implies a far-reaching generalization of the structure of representations of separable type I C*-algebras and correspondingly of separable locally compact groups of type I.

Algebraic primitive spectra

Since a C*-algebra A is a ring, we can also consider the set of primitive ideals of A, where A is regarded algebraically. For a ring an ideal is primitive if and only if it is the annihilator of a simple module. It turns out that for a C*-algebra A, an ideal is algebraically primitive if and only if it is primitive in the sense defined above.

Theorem. Let A be a C*-algebra. Any algebraically irreducible representation of A on a complex vector space is algebraically equivalent to a topologically irreducible *-representation on a Hilbert space. Topologically irreducible *-representations on a Hilbert space are algebraically isomorphic if and only if they are unitarily equivalent.

This is the Corollary of Theorem 2.9.5 of the Dixmier reference.

If G is a locally compact group, the topology on dual space of the group C*-algebra C*(G) of G is called the Fell topology, named after J. M. G. Fell.

References

  • J. Dixmier, Les C*-algèbres et leurs représentations, Gauthier-Villars, 1969.
  • J. Glimm, Type I C*-algebras, Annals of Mathematics, vol 73, 1961.
  • G. Mackey, The Theory of Group Representations, The University of Chicago Press, 1955.

Template:Functional Analysis