Secondary polynomials: Difference between revisions

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<!-- To obtain a blank version of this page, type subst:chembox supplement inside of double curly braces, {{}}, and save the page -->
This page provides supplementary chemical data on [[trichloroethylene]]. <!-- replace with proper wikilink -->
 
== Material Safety Data Sheet == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet ([[Material safety data sheet|MSDS]]) for this chemical from a reliable source  such as [http://www2.siri.org/msds/index.php SIRI], and follow its directions. MSDS for trichloroethylene is available at [http://hazard.com/msds/mf/baker/baker/files/t4940.htm Mallinckrodt Baker].
 
== Structure and properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Structure and properties
|-
| [[Index of refraction]],<ref>''Lange's Handbook of Chemistry'', 10th ed. pp 1289-1376</ref>''n''<sub>D</sub>
| 1.4777 at 19.8°C <!-- Please omit if not applicable -->
|-
| [[Abbe number]]
|? <!-- Please omit if not applicable -->
|-
| [[Dielectric constant]],<ref>''CRC Handbook of Chemistry and Physics'', 44th ed. pp 2613-2620</ref> ε<sub>r</sub>
| 3.4 ε<sub>0</sub> at 16 °C <!-- Please omit if not applicable -->
|-
| [[Bond strength]]
| ? <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond length]]
| ? <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond angle]]
| ? <!-- Specify which angle, e.g. Cl-P-O. Please omit if not applicable -->
|-
| [[Magnetic susceptibility]]
| ? <!-- Please omit if not applicable -->
|-
| [[Surface tension]]<ref>{{Cite web|url=http://www.forwardtech.com/PrecisionCleaning/|title=Precision Cleaning|publisher=Forward Technology|accessdate=31 May 2007}}</ref>
| 28.7 dyn/cm
|-
| [[Viscosity]]<ref name="ca">{{Cite web|url=http://www.arb.ca.gov/db/solvents/solvent_pages/Halogens-HTML/112-trichloroethylene.htm| title=1,1,2-trichloroethylene|publisher=California Air Resources Board|accessdate=31 May 2007}}</ref>
| 0.53 mPa·s at 25°C
|-
|}
 
== Thermodynamic properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Phase behavior
|-
| [[Triple point]]<ref name="moldyn">{{Cite web|url=http://pubs.acs.org/subscribe/journals/langd5/suppinfo/la0607196/la0607196si20060316_012316.pdf?sessid=6006l3| title=Molecular Dynamics Simulation of Nanoparticle Self-Assembly at a Liquid/Liquid Surface|author=Mingxiang Lou, Oleg A. Mazyar, Mark W. Vaughn, William L. Hase, Lenore L. Dai|publisher=Texas Tech. University, Dept. of Chemical Engineering|accessdate=31 May 2007}} {{Dead link|date=October 2010|bot=H3llBot}}</ref>
| 188.4 K (–84.7 °C), ? Pa
|-
| [[Critical point (chemistry)|Critical point]]<ref name="moldyn"/>
| 571 K (298 °C), 5016 kPa
|-
| [[Standard enthalpy change of fusion|Std enthalpy change<br/>of fusion]], Δ<sub>fus</sub>''H''<sup><s>o</s></sup>
| 8.45 kJ/mol
|-
| [[Standard entropy change of fusion|Std entropy change<br/>of fusion]], Δ<sub>fus</sub>''S''<sup><s>o</s></sup>
| 44.8 J/(mol·K)
|-
| [[Standard enthalpy change of vaporization|Std enthalpy change<br/>of vaporization]], Δ<sub>vap</sub>''H''<sup><s>o</s></sup>
| 31.4 kJ/mol
|-
| [[Standard entropy change of vaporization|Std entropy change<br/>of vaporization]], Δ<sub>vap</sub>''S''<sup><s>o</s></sup>
| ? J/(mol·K)
|-
! {{chembox header}} | Solid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>solid</sub>
| ? kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>solid</sub>
| ? J/(mol K)
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| ? J/(mol K)
|-
! {{chembox header}} | Liquid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>liquid</sub>
| –53.1 kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>liquid</sub>
| ? J/(mol K)
|-
| [[Enthalpy of combustion]], Δ<sub>c</sub>''H''<sup><s>o</s></sup><sub>liquid</sub>
| –947.7 kJ/mol
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 120.1 J/(mol K)
|-
! {{chembox header}} | Gas properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>gas</sub>
| –19.1 kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>gas</sub>
| ? J/(mol K)
|-
| [[Heat capacity]],<ref name="cheric_p"/> ''c<sub>p</sub>''
| 80.7 J/(mol K) at 25°C
|-
|}
 
==Vapor pressure of liquid==
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| {{chembox header}} | '''P in mm Hg''' || 1 || 10 || 40 || 100 || 400 || 760
|-
| {{chembox header}} | '''T in °C''' || –43.8 || –12.4 || 11.9 || 31.4 || 67.0 || 86.7
|}
Table data obtained from ''CRC Handbook of Chemistry and Physics'' 44th ed.
 
[[Image:LogTrichloroethyleneVaporPressure.png|thumb|821px|left|'''log<sub>10</sub> of Trichloroethylene vapor pressure.''' Uses formula: <math>\scriptstyle \log_e P_{mmHg} =</math><math>\scriptstyle \log_e (\frac {760} {101.325}) - 3.586434\log_e(T+273.15) - \frac {5142.974} {T+273.15} + 39.83149 + 1.342324 \times 10^{-6} (T+273.15)^2</math> obtained from CHERIC<ref name="cheric_p">{{Cite web|url=http://www.cheric.org/research/kdb/hcprop/cmpsrch.php|title=Pure Component Properties|format=Queriable Database|accessdate=31 May 2007|publisher=Chemical Engineering Research Information Center}}</ref>]]{{Clear}}
 
==Distillation data==
{|
|- valign="top"
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3" | '''Vapor-liquid Equilibrium<br>for Trichlorethylene/[[Carbon tetrachloride]]'''<ref name="cheric_b">{{Cite web|url=http://www.cheric.org/research/kdb/hcvle/hcvle.php|title=Binary Vapor-Liquid Equilibrium Data|publisher=Chemical Engineering Research Information Center|format=Queriable database|accessdate=1 June 2007}}</ref><br>''P'' = 760 mmHg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole CCl<sub>4</sub>
|- {{chembox header}}
! liquid !! vapor
|-
| 86.0 || 6.0 || 7.5
|-
| 85.1 || 14.7 || 17.6
|-
| 84.4 || 20.2 || 25.0
|-
| 84.2 || 22.4 || 27.8
|-
| 83.5 || 27.4 || 34.4
|-
| 83.1 || 31.5 || 38.0
|-
| 82.5 || 37.6 || 44.5
|-
| 81.3 || 49.0 || 56.5
|-
| 81.0 || 52.5 || 58.9
|-
| 80.5 || 58.0 || 65.0
|-
| 80.0 || 62.7 || 70.0
|-
| 79.1 || 70.6 || 78.0
|-
| 78.5 || 76.7 || 82.9
|-
| 78.1 || 80.4 || 86.6
|-
| 77.3 || 91.8 || 95.0
|-
| 76.9 || 96.5 || 98.0
|-
|}
| &nbsp; &nbsp;
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3" | '''Vapor-liquid Equilibrium<br>for Trichlorethylene/[[Tetrachloroethylene]]'''<ref name="cheric_b"/><br>''P'' = 760 mmHg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole trichloroethylene
|- {{chembox header}}
! liquid !! vapor
|-
| 117.0 || 7.5 || 17.8
|-
| 115.7 || 10.0 || 22.8
|-
| 112.8 || 16.2 || 33.8
|-
| 110.5 || 21.7 || 42.0
|-
| 109.1 || 25.0 || 46.8
|-
| 106.9 || 30.8 || 53.7
|-
| 105.7 || 33.6 || 57.2
|-
| 103.4 || 39.4 || 62.7
|-
| 101.0 || 46.2 || 69.8
|-
| 100.0 || 49.3 || 71.8
|-
| 98.4 || 55.0 || 75.6
|-
| 96.3 || 61.4 || 80.0
|-
| 94.4 || 68.5 || 84.3
|-
| 93.4 || 72.3 || 87.2
|-
| 92.1 || 76.9 || 88.8
|-
| 89.5 || 87.5 || 95.0
|-
|}
| &nbsp; &nbsp;
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3" | '''Vapor-liquid Equilibrium<br>for Trichlorethylene/[[Isopropanol]]'''<ref name="cheric_b"/><br>''P'' = 100 kPa
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole trichloroethylene
|- {{chembox header}}
! liquid !! vapor
|-
| 81.7 || 0.0 || 0.0
|-
| 81.4 || 0.8 || 2.1
|-
| 80.4 || 3.2 || 8.0
|-
| 79.3 || 6.8 || 14.7
|-
| 78.3 || 10.6 || 20.9
|-
| 77.2 || 15.6 || 27.3
|-
| 76.3 || 21.8 || 33.7
|-
| 75.6 || 29.0 || 39.4
|-
| 75.2 || 35.7 || 43.7
|-
| 74.9 || 43.3 || 47.7
|-
| 74.8 || 50.9 || 50.8
|-
| 74.8 || 57.3 || 53.9
|-
| 75.0 || 63.2 || 56.2
|-
| 75.3 || 69.5 || 58.7
|-
| 75.7 || 75.2 || 61.1
|-
| 76.2 || 79.8 || 64.1
|-
| 77.4 || 86.2 || 68.8
|-
| 78.9 || 90.8 || 74.5
|-
| 80.5 || 94.1 || 80.1
|-
| 81.3 || 94.9 || 83.0
|-
| 82.5 || 96.7 || 87.1
|-
| 83.5 || 97.9 || 90.7
|-
| 84.2 || 98.5 || 92.9
|-
| 85.0 || 99.1 || 95.1
|-
| 86.4 || 100.0 || 100.0
|-
|}
|}
 
== Spectral data == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | [[UV/VIS spectroscopy|UV-Vis]]
|-
| [[Lambda-max|λ<sub>max</sub>]]
| ? [[Nanometre|nm]]
|-
| [[molar absorptivity|Extinction coefficient]], ε
| ?
|-
! {{chembox header}} | [[Infrared|IR]]
|-
| Major absorption bands
| ? [[Centimetre|cm]]<sup>&minus;1</sup>
|-
! {{chembox header}} | [[NMR Spectroscopy|NMR]]
|-
| [[Proton NMR]] <!-- Link to image of spectrum -->
| &nbsp;
|-
| [[Carbon-13 NMR]] <!-- Link to image of spectrum -->
| &nbsp;
|-
| Other NMR data <!-- Insert special data e.g. <sup>19</sup>F chem. shifts, omit if not used -->
| &nbsp;
|-
! {{chembox header}} | [[Mass Spectrometry|MS]]
|-
| Masses of <br>main fragments
| &nbsp; <!-- Give list of major fragments -->
|-
|}
 
==References==
{{Reflist}}
* {{Cite web|url=http://webbook.nist.gov/chemistry/|title=NIST Standard Reference Database}}
 
Except where noted otherwise, data relate to [[standard ambient temperature and pressure]].
 
[[wikipedia:Chemical infobox|Disclaimer]] applies.
{{Use dmy dates|date=September 2010}}
 
{{DEFAULTSORT:Trichloroethylene (Data Page)}}
[[Category:Chemical data pages]]

Latest revision as of 04:23, 17 March 2013

This page provides supplementary chemical data on trichloroethylene.

Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source such as SIRI, and follow its directions. MSDS for trichloroethylene is available at Mallinckrodt Baker.

Structure and properties

Structure and properties
Index of refraction,[1]nD 1.4777 at 19.8°C
Abbe number ?
Dielectric constant,[2] εr 3.4 ε0 at 16 °C
Bond strength ?
Bond length ?
Bond angle ?
Magnetic susceptibility ?
Surface tension[3] 28.7 dyn/cm
Viscosity[4] 0.53 mPa·s at 25°C

Thermodynamic properties

Phase behavior
Triple point[5] 188.4 K (–84.7 °C), ? Pa
Critical point[5] 571 K (298 °C), 5016 kPa
Std enthalpy change
of fusion, ΔfusHo 		8.45 kJ/mol
Std entropy change
of fusion, ΔfusSo 		44.8 J/(mol·K)
Std enthalpy change
of vaporization, ΔvapHo 		31.4 kJ/mol
Std entropy change
of vaporization, ΔvapSo 		? J/(mol·K)
Solid properties
Std enthalpy change
of formation, ΔfHosolid 		? kJ/mol
Standard molar entropy,
Sosolid 		? J/(mol K)
Heat capacity, cp ? J/(mol K)
Liquid properties
Std enthalpy change
of formation, ΔfHoliquid 		–53.1 kJ/mol
Standard molar entropy,
Soliquid 		? J/(mol K)
Enthalpy of combustion, ΔcHoliquid –947.7 kJ/mol
Heat capacity, cp 120.1 J/(mol K)
Gas properties
Std enthalpy change
of formation, ΔfHogas 		–19.1 kJ/mol
Standard molar entropy,
Sogas 		? J/(mol K)
Heat capacity,[6] cp 80.7 J/(mol K) at 25°C

Vapor pressure of liquid

P in mm Hg 1 10 40 100 400 760
T in °C –43.8 –12.4 11.9 31.4 67.0 86.7

Table data obtained from CRC Handbook of Chemistry and Physics 44th ed.

log10 of Trichloroethylene vapor pressure. Uses formula: obtained from CHERIC[6]

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Distillation data

Vapor-liquid Equilibrium
for Trichlorethylene/Carbon tetrachloride[7]
P = 760 mmHg
BP
Temp.
°C 		% by mole CCl4
liquid vapor
86.0 6.0 7.5
85.1 14.7 17.6
84.4 20.2 25.0
84.2 22.4 27.8
83.5 27.4 34.4
83.1 31.5 38.0
82.5 37.6 44.5
81.3 49.0 56.5
81.0 52.5 58.9
80.5 58.0 65.0
80.0 62.7 70.0
79.1 70.6 78.0
78.5 76.7 82.9
78.1 80.4 86.6
77.3 91.8 95.0
76.9 96.5 98.0
   
Vapor-liquid Equilibrium
for Trichlorethylene/Tetrachloroethylene[7]
P = 760 mmHg
BP
Temp.
°C 		% by mole trichloroethylene
liquid vapor
117.0 7.5 17.8
115.7 10.0 22.8
112.8 16.2 33.8
110.5 21.7 42.0
109.1 25.0 46.8
106.9 30.8 53.7
105.7 33.6 57.2
103.4 39.4 62.7
101.0 46.2 69.8
100.0 49.3 71.8
98.4 55.0 75.6
96.3 61.4 80.0
94.4 68.5 84.3
93.4 72.3 87.2
92.1 76.9 88.8
89.5 87.5 95.0
   
Vapor-liquid Equilibrium
for Trichlorethylene/Isopropanol[7]
P = 100 kPa
BP
Temp.
°C 		% by mole trichloroethylene
liquid vapor
81.7 0.0 0.0
81.4 0.8 2.1
80.4 3.2 8.0
79.3 6.8 14.7
78.3 10.6 20.9
77.2 15.6 27.3
76.3 21.8 33.7
75.6 29.0 39.4
75.2 35.7 43.7
74.9 43.3 47.7
74.8 50.9 50.8
74.8 57.3 53.9
75.0 63.2 56.2
75.3 69.5 58.7
75.7 75.2 61.1
76.2 79.8 64.1
77.4 86.2 68.8
78.9 90.8 74.5
80.5 94.1 80.1
81.3 94.9 83.0
82.5 96.7 87.1
83.5 97.9 90.7
84.2 98.5 92.9
85.0 99.1 95.1
86.4 100.0 100.0

Spectral data

UV-Vis
λmax ? nm
Extinction coefficient, ε ?
IR
Major absorption bands ? cm−1
NMR
Proton NMR  
Carbon-13 NMR  
Other NMR data  
MS
Masses of
main fragments 		 

References

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Except where noted otherwise, data relate to standard ambient temperature and pressure.

Disclaimer applies. 30 year-old Entertainer or Range Artist Wesley from Drumheller, really loves vehicle, property developers properties for sale in singapore singapore and horse racing. Finds inspiration by traveling to Works of Antoni Gaudí.

  1. ↑ Lange's Handbook of Chemistry, 10th ed. pp 1289-1376
  2. ↑ CRC Handbook of Chemistry and Physics, 44th ed. pp 2613-2620
  3. ↑ Template:Cite web
  4. ↑ Template:Cite web
  5. ↑ 5.0 5.1 Template:Cite web Template:Dead link
  6. ↑ 6.0 6.1 Template:Cite web
  7. ↑ 7.0 7.1 7.2 Template:Cite web
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